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Safety Data Sheet EN

Sulphuric acid ROTIPURAN® 96 %, p.a., ISO

CAS 7664-93-9
EC 231-639-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sulphuric acid ROTIPURAN® 96 %, p.a., ISO
Product Code
4623
Chemical Name
Sulphuric acid

Regulatory Identifiers

CAS Number
7664-93-9 Check regulations →
EC Number
231-639-5 Check regulations →

Identified Uses

Laboratory chemical, Laboratory and analytical use

Uses advised against

Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe, Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Service City Hospital

844 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Sulphuric acid ROTIPURAN® 96 %, p.a., ISO

Chemical Name CAS Number Concentration Hazardous
Sulphuric acid EC: 231-639-5 7664-93-9 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Skin contact

Remove mechanically (e.g. dab away using wadding or cellulose material) then thoroughly wash the affected skin with a mild cleansing agent and water.

Symptoms: Corrosion

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye.

Symptoms: Risk of serious damage to eyes, Risk of blindness

Ingestion

Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).

Symptoms: Gastric perforation

Immediate Medical Attention

Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)

Unsuitable media

water jet

Specific hazards

Non-combustible.

Instructions

In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus. Wear full chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).

Materials: sand, diatomaceous earth, acid- or universal binding agents

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle and open container with care. Clear contaminated areas thoroughly.

Storage

Keep container tightly closed. Store in a dry place. Hygroscopic.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. FKM (fluoro rubber), material thickness: ≥0,4 mm, breakthrough times: >480 minutes (permeation: level 6). Splash protection: Butyl caoutchouc (butyl rubber), material thickness: 0,7 mm, breakthrough times: >120 minutes (permeation: level 4).

Eyes

Use safety goggle with side protection. Wear face protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sulphur dioxide or hydrogen chloride, colour code: Yellow). Type: B-P2 (combined filters for acidic gases and particles, colour code: Grey/White).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Form
---
Flash Point
not determined
Melting Point
-15 °C
Decomposition Temperature
338 °C
Flammability
non-combustible
Relative Evaporation Rate
---
Ph
<1 (20 °C)
State Under Standard Conditions
---
Upper Explosive Limit
not determined
Vapor Density
---
Molecular Weight
---
Solubility In Fat
---
Boiling Point
295 – 315 °C
Relative Density
---
Metal Corrosion
corrosive to metals
Explosive Limits
---
Colour Intensity
---
Lower Explosive Limit
not determined
Partition Coefficient
not relevant (inorganic)
Bulk Density
---
Kinematic Viscosity
14,62 mm²/s at 20 °C
Appearance
---
Density
1,84 g/cm³ at 20 °C
Freezing Point
-15 °C
Softening Point
---
Properties Status
---
Odor Threshold
---
Solubility
Water solubility (soluble)
Crystallisation Point
---
Voc Content
---
Solidification Point
---
Colour
colourless
Physical State
liquid
Solubility In Water
(soluble)
Evaporation Rate
---
Odor
odourless
Auto Ignition Temperature
not determined
Physical State Data
liquid
Cloud Point
---
Dynamic Viscosity
26,9 mPa s at 20 °C
Vapor Pressure
<0,01 hPa at 20 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

It's a reactive substance. Substance or mixture corrosive to metals.

Hazardous reactions

Violent reaction with: Aldehydes, Alkali (lye), Alkali metals, Ammonia (NH3), Bromates, Carbide, Chlorates, Alkaline earth metal, Halogenated hydrocarbons, Metals, Metal powder, Nitrate, Nitriles, Nitro compound, Organic substances, Perchlorates, Permanganates, Peroxides, Phosphorus, Phosphorus oxides (e.g. P2O5), Acids, Strong alkali, Water, Hydrogen peroxide

Avoid

Keep away from heat. Decomposition takes place from temperatures above: 338 °C.

Incompatible

different metals

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

This material and its container must be disposed of as hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1830
Shipping Name
SULPHURIC ACID
Transport Class
8
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sulphuric acid ROTIPURAN® 96 %, p.a., ISO?

The signal word is danger.

What is the physical form of Sulphuric acid ROTIPURAN® 96 %, p.a., ISO?

Sulphuric acid ROTIPURAN® 96 %, p.a., ISO is a liquid with colourless color. It has odourless odor.

What is the solubility of Sulphuric acid ROTIPURAN® 96 %, p.a., ISO?

Water solubility (soluble)

What is Sulphuric acid ROTIPURAN® 96 %, p.a., ISO used for?

Laboratory chemical, Laboratory and analytical use

What are the hazard statements for Sulphuric acid ROTIPURAN® 96 %, p.a., ISO?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals
  • H314: Causes severe skin burns and eye damage

What is the melting point of Sulphuric acid ROTIPURAN® 96 %, p.a., ISO?

The melting point is -15 °C and the boiling point is 295 – 315 °C.