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Safety Data Sheet EN

AIR WICK AUTOMATIC SPRAY - FRESH WATERS

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
AIR WICK AUTOMATIC SPRAY - FRESH WATERS

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Air care products Consumer uses

Manufacturers & Suppliers

Reckitt Benckiser LLC. logo

Reckitt Benckiser LLC.

distributor

Morris Corporate Center IV, 399 Interpace Parkway (P.O. Box 225), Parsippany, New Jersey 07054-0225

+1 973 404 2600

http://www.rbnainfo.com

Reckitt Benckiser (Canada) Inc. logo

Reckitt Benckiser (Canada) Inc.

distributor

1680 Tech Avenue, Unit #2, Mississauga, Ontario L4W 5S9, CANADA

+1 905 283 7000

http://www.rbnainfo.com

Emergency Contacts

Emergency Contact

1-800-338-6167

CHEMTREC

1-800-424-9300

CHEMTREC

703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1
Press. Gas

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

Hazard Statements

H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P403 Store in a well-ventilated place.
P410 Protect from sunlight.
P412 Do not expose to temperatures exceeding 50 °C/122 °F.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
butane 106-97-8 30 - 60% No
Distillates (petroleum), hydrotreated light 64742-47-8 30 - 60% No
propane 74-98-6 10 - 30% No
1,1-difluoroethane 75-37-6 10 - 30% No
Isobutane 75-28-5 1 - 5% No
Isopropyl myristate 110-27-0 1 - 5% No
d-Limonene 5989-27-5 0.1 - 1% No

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: respiratory tract irritation coughing

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: irritation redness

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards.

Immediate Medical Attention

If unconscious, place in recovery position and get medical attention immediately.

Medical Treatment

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Stop leak if without risk. Move containers from spill area. Approach release from upwind.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Storage

Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid. [Aerosol.]
Physical State Data
aerosol
State Under Standard Conditions
---
Appearance
Colorless.
Colour
Colorless.
Colour Intensity
---
Form
Spray
Odor
Not available.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
<34°C (<93.2°F)
Flash Point
Closed cup: <0°C (<32°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
0.732 to 0.752
Bulk Density
---
Density
0.732 to 0.752 g/cm³
Flammability
---
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Not available.
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame).

Incompatible

No specific data.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Product/ingredient name | Result | Species | Exposure --- | d-Limonene | Acute EC50 421 μg/l Fresh water Acute EC50 688 μg/l Fresh water | Daphnia - Daphnia magna Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) | 48 hours 96 hours Conclusion/Summary : Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

Persistence and degradability

Not available.

Bioaccumulative potential

Product/ingredient name | LogP_{ow} | BCF | Potential ---

12.3 Bioaccumulative potential

Product/ingredient name: butane, LogP_ow: 2.89, BCF: -, Potential: low

12.3 Bioaccumulative potential

Product/ingredient name: propane, LogP_ow: 1.09, BCF: -, Potential: low

12.3 Bioaccumulative potential

1,1-difluoroethane | 1.13 | - | low

12.1 Toxicity

No data available

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

Product/ingredient name: Isobutane, LogP_ow: 2.8, BCF: -, Potential: low

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine disrupting properties

No data available

12.7 Other adverse effects

No data available

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Isopropyl myristate | 7.71 | - | high

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

Bioaccumulative potential

d-Limonene | 4.38 | - | high

Mobility in soil

Soil/water partition coefficient (Koc) : Not available.

Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1950
Shipping Name
Aerosols
Transport Class
2.1
IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for AIR WICK AUTOMATIC SPRAY - FRESH WATERS?

The signal word is danger.

What is the physical form of AIR WICK AUTOMATIC SPRAY - FRESH WATERS?

AIR WICK AUTOMATIC SPRAY - FRESH WATERS is a liquid. [aerosol.] appearing as colorless. with colorless. color. It has not available. odor.

What is the solubility of AIR WICK AUTOMATIC SPRAY - FRESH WATERS?

Not available.

What is AIR WICK AUTOMATIC SPRAY - FRESH WATERS used for?

Air care products Consumer uses

What are the hazard statements for AIR WICK AUTOMATIC SPRAY - FRESH WATERS?

This substance has 2 hazard statements:

  • H222: Extremely flammable aerosol.
  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of AIR WICK AUTOMATIC SPRAY - FRESH WATERS?

The melting point is Not available. and the boiling point is <34°C (<93.2°F).