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Safety Data Sheet EN

Methanethiol

CAS 74-93-1
EC 200-822-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methanethiol
Product Code
295515
Chemical Name
methylmercaptaan
Synonyms
Mercaptan C1 Methyl mercaptan

Regulatory Identifiers

CAS Number
74-93-1 Check regulations →
EC Number
200-822-1 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Gases under pressure H280
Acute Tox. Cat. 3 H331

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS06 - Acute toxicity

GHS06

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H331 Toxic if inhaled.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P271 Use only outdoors or in a well-ventilated area.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
methylmercaptaan EC: 200-822-1 74-93-1 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Splash contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 30 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State Data
gas
Molecular Weight
---
Form
Liquefied gas
Kinematic Viscosity
No data available
Colour Intensity
---
Explosive Limits
---
Ph
No data available
Properties Status
---
Odor Threshold
No data available
Boiling Point
6 °℃ (43 ºF) - lit.
Bulk Density
---
Vapor Density
1.93
Freezing Point
---
Appearance
Form: Liquefied gas, Colour: colourless
Flash Point
-18 ℃ (0 ºF) - closed cup
Relative Density
No data available
Physical State
Liquefied gas
Cloud Point
---
Crystallisation Point
---
Dynamic Viscosity
No data available
Density
---
Odor
No data available
Lower Explosive Limit
3.91 %(V)
Relative Evaporation Rate
---
Solidification Point
---
Evaporation Rate
No data available
Voc Content
---
Solubility In Water
No data available
Colour
colourless
State Under Standard Conditions
---
Melting Point
- 123 ℃ (-189 ºF) - lit.
Solubility
---
Partition Coefficient
No data available
Decomposition Temperature
No data available
Softening Point
---
Vapor Pressure
2,048 hPa (1,536 mmHg) at 20 °℃ (68 ºF)
Auto Ignition Temperature
No data available
Metal Corrosion
---
Flammability
No data available
Upper Explosive Limit
21.8 %(V
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1064
Shipping Name
Methyl mercaptan
Transport Class
2.3 (2.1)
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methanethiol known by?

Methanethiol is also known as: Mercaptan C1 Methyl mercaptan

What is the hazard signal word for Methanethiol?

The signal word is danger.

What is the physical form of Methanethiol?

Methanethiol is a liquefied gas appearing as form: liquefied gas, colour: colourless with colourless color. It has no data available odor.

What is Methanethiol used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Methanethiol?

This substance has 3 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.
  • H331: Toxic if inhaled.

What is the melting point of Methanethiol?

The melting point is - 123 ℃ (-189 ºF) - lit. and the boiling point is 6 °℃ (43 ºF) - lit..

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