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Safety Data Sheet EN

Zineb

CAS 12122-67-7
EC 235-180-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Zineb
Product Code
45707
Chemical Name
zineb (ISO) zinc ethylenebis(dithiocarbamate) (polymeric) 006-078-00-2

Regulatory Identifiers

CAS Number
12122-67-7 Check regulations →
EC Number
235-180-1 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
zineb (ISO) zinc ethylenebis(dithiocarbamate) (polymeric) 006-078-00-2 EC: 235-180-1 12122-67-7 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Consult a physician.

Eye contact

Flush eyes with water as a precaution.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
---
Physical State Data
---
State Under Standard Conditions
---
Appearance
Form: crystalline Colour: yellow
Colour
yellow
Colour Intensity
---
Form
crystalline
Odor
---
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
---
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0.001 hPa (< 0.001 mmHg) at 20 ℃ (68 ºF)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
157 ℃ (315 °F) -
Solubility
---
Partition Coefficient
---
Solubility In Water
insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3077
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zineb)
Transport Class
9
Packing Group
III
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Zineb?

The signal word is warning.

What is Zineb used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Zineb?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

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