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Safety Data Sheet EN

Ziram

CAS 137-30-4
EC 205-288-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ziram
Product Code
45708
Chemical Name
Ziram

Regulatory Identifiers

CAS Number
137-30-4 Check regulations →
EC Number
205-288-3 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

manufacturer

3050 Spruce Street ST. LOUIS MO 63103 UNITED STATES

+1 314 771-5765

Emergency Contacts

Emergency Contact

(314) 776-6555

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 2 H330
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs (/$/*_ORG_REP_ORAL/$/) through prolonged or repeated exposure if swallowed.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P284 Wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P314 Get medical advice/ attention if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
Ziram EC: 205-288-3 137-30-4 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Partition Coefficient
log Pow: 1.65 at 20 ℃ (68 ºF)
Ph
No data available
Odor Threshold
No data available
Flammability
The product is not flammable.
Physical State Data
solid
Flash Point
No data available
Vapor Pressure
No data available
Properties Status
---
Metal Corrosion
---
Boiling Point
No data available
Solubility In Water
slightly soluble
Cloud Point
---
Relative Evaporation Rate
---
Bulk Density
---
Solubility
Acetone 2.3 g/l at 20 ℃ (68 °F) Methanol 0.11 g/l at 20 ℃ (68 ºF)
Solubility In Fat
---
Softening Point
---
Form
powder
Solidification Point
---
Relative Density
No data available
Freezing Point
---
Colour
white
Evaporation Rate
No data available
Appearance
Form: powder Colour: white
State Under Standard Conditions
---
Crystallisation Point
---
Kinematic Viscosity
---
Dynamic Viscosity
---
Physical State
powder
Lower Explosive Limit
No data available
Voc Content
---
Auto Ignition Temperature
not auto-flammable
Decomposition Temperature
No data available
Upper Explosive Limit
No data available
Molecular Weight
---
Colour Intensity
---
Explosive Limits
---
Vapor Density
No data available
Melting Point
251 - 252.5 ℃ (484 - 486.5 °F)
Odor
No data available
Density
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2811
Shipping Name
Toxic solid, organic, n.o.s. (Ziram)
Transport Class
6.1
Packing Group
II
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Ziram?

The signal word is danger.

What is the physical form of Ziram?

Ziram is a powder appearing as form: powder colour: white with white color. It has no data available odor.

What is the solubility of Ziram?

Acetone 2.3 g/l at 20 ℃ (68 °F) Methanol 0.11 g/l at 20 ℃ (68 ºF)

What is Ziram used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Ziram?

This substance has 7 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H330: Fatal if inhaled.
  • H335: May cause respiratory irritation.
  • H373: May cause damage to organs (/$/*_ORG_REP_ORAL/$/) through prolonged or repeated exposure if swallowed.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Ziram?

The melting point is 251 - 252.5 ℃ (484 - 486.5 °F) and the boiling point is No data available.

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