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Safety Data Sheet EN

Fluorosulfonic acid

CAS 7789-21-1
EC 232-149-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Fluorosulfonic acid
Product Code
236535
Chemical Name
Fluosulfuric acid

Regulatory Identifiers

CAS Number
7789-21-1 Check regulations →
EC Number
232-149-4 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Fluosulfuric acid

Chemical Name CAS Number Concentration Hazardous
Fluosulfuric acid EC: 232-149-4 7789-21-1 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. First treatment with calcium gluconate paste.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Medical Treatment

Skin exposures can be treated with a 2.5% calcium gluconate gel repeated until burning ceases. More serious skin exposures may require subcutaneous calcium gluconate except for digital areas unless the physician is experienced in this technique, due to the potential for tissue injury from increased pressure. Absorption can readily occur through the subungual areas and should be considered when undergoing decontamination. Prevention of absorption of the fluoride ion in cases of ingestion can be obtained by giving milk, chewable calcium carbonate tablets or Milk of Magnesia to conscious victims.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.4 mm Break through time: 120 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Ph
No data available
Bulk Density
---
Density
---
State Under Standard Conditions
---
Relative Evaporation Rate
---
Kinematic Viscosity
---
Solubility In Fat
---
Solubility In Water
No data available
Flammability
No data available
Voc Content
---
Solidification Point
---
Cloud Point
---
Flash Point
Not applicable
Colour Intensity
---
Upper Explosive Limit
---
Physical State Data
liquid
Odor
No data available
Decomposition Temperature
No data available
Odor Threshold
No data available
Relative Density
1.726 g/cm3 at 25 ℃ (77 ºF)
Metal Corrosion
---
Boiling Point
165.5 ℃ (329.9 ºF)
Melting Point
-87.3 ℃ (-125.1 ºF)
Form
---
Explosive Limits
---
Physical State
liquid
Properties Status
---
Auto Ignition Temperature
No data available
Appearance
clear, liquid
Partition Coefficient
No data available
Molecular Weight
---
Colour
colourless
Lower Explosive Limit
---
Dynamic Viscosity
No data available
Softening Point
---
Vapor Density
3.45 - (Air = 1.0)
Evaporation Rate
No data available
Solubility
No data available
Vapor Pressure
3.3 hPa (2.5 mmHg) at 25 ℃ (77 ºF)
Freezing Point
---
Crystallisation Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1777
Shipping Name
Fluorosulphonic acid
Transport Class
8
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Fluorosulfonic acid?

The signal word is danger.

What is the physical form of Fluorosulfonic acid?

Fluorosulfonic acid is a liquid appearing as clear, liquid with colourless color. It has no data available odor.

What is the solubility of Fluorosulfonic acid?

No data available

What is Fluorosulfonic acid used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Fluorosulfonic acid?

This substance has 3 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Fluorosulfonic acid?

The melting point is -87.3 ℃ (-125.1 ºF) and the boiling point is 165.5 ℃ (329.9 ºF).

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