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Safety Data Sheet EN

Fluorosilicic acid solution

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Fluorosilicic acid solution
Product Code
372757

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

distributor

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H311
Skin Corr. Cat. 1 H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Formula : H 2 F 6 Si Molecular weight : 144,09 g/mol

Chemical Name CAS Number Concentration Hazardous
hexafluorosilicic acid EC: 241-034-8 16961-83-4 20 - 30% Yes
Hydrofluoric acid EC: 231-634-8 7664-39-3 0.1 - 1% Yes

A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, or the annual tonnage does not require a registration.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Hydrogen fluoride, silicon oxides. Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Collect, bind, and pump off spills. Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® HF, Merck Art. No. 101591). Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® HF, Merck Art. No. 101591)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
clear, liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
light yellow
Colour Intensity
---
Form
---
Odor
pungent
Odor Threshold
---
Ph
1,0 - 1,2 at 10 g/l
Melting Point
ca.-4 - 5 °C
Boiling Point
221 - 222,5 °C
Flash Point
No data available
Freezing Point
ca.-4 - 5 C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
32 hPa at 25 °C
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
1,22 g/cm³ at 25 °C
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No data available
Solubility
completely solubleat 20 C soluble
Partition Coefficient
No data available
Solubility In Water
completely soluble at 20 °C soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Violent reactions possible with: The generally known reaction partners of water.

Avoid

no information available

Incompatible

Strong oxidizing agents, Metals, Alkalis, Strong acids, Stoneware, glass

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

No data available

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1778
Shipping Name
FLUOROSILICIC ACID
Transport Class
8
Packing Group
II
ADR

No data available

IMDG

No data available

IATA

No data available

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Fluorosilicic acid solution?

The signal word is danger.

What is the physical form of Fluorosilicic acid solution?

Fluorosilicic acid solution is a clear, liquid with light yellow color. It has pungent odor.

What is the solubility of Fluorosilicic acid solution?

completely solubleat 20 C soluble

What is Fluorosilicic acid solution used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Fluorosilicic acid solution?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H311: Toxic in contact with skin.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Fluorosilicic acid solution?

The melting point is ca.-4 - 5 °C and the boiling point is 221 - 222,5 °C.