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Safety Data Sheet EN

2-Methyl-2-butene

CAS 513-35-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2-Methyl-2-butene
Product Code
66050
Chemical Name
2-Methyl-2-butene

Regulatory Identifiers

CAS Number
513-35-9 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science N.V.

distributor

Haarlerbergweg 21 A, 1101 CH AMSTERDAM, NETHERLANDS

+31 078 620-5411

Emergency Contacts

CHEMTREC

+(31)-858880596

Alarmnummer

112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1 H224
Acute Tox. Cat. 4 H302
Muta. Cat. 2 H341
STOT SE Cat. 3 H336
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H224 Extremely flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P273 Avoid release to the environment.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P331 Do NOT induce vomiting.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substance

Synonyms: -Isoamylene, Amylene

Chemical Name CAS Number Concentration Hazardous
2-methyl-2-butene EC: 208-156-3 513-35-9 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

Keep airways free. Call a physician immediately.

Symptoms: caution if victim vomits. Risk of aspiration! Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention

No data available

Medical Treatment

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Hygiene

Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
No data available
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
No data available
Melting Point
-134 C
Boiling Point
35 - 38 C at 1.013 hPa
Flash Point
-20 C
Freezing Point
-134 C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
6.621,5 hPa at 25 C
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
0,66 g/cm3 at 20 C
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
log Pow: 2,67 at 25 C - Bioaccumulation is not expected., (External MSDS)
Solubility In Water
0,193 g/l at 25 C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0,203 mPa.s at 25 C
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to fish semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 4,99 mg/l - 96 h (OECD Test Guideline 203) Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 3,84 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 13,2 mg/l - 96 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata (green algae) - 7,22 mg/l - 96 h (OECD Test Guideline 201)

12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 28 d Result: 7 % - Not readily biodegradable. (OECD Test Guideline 301D)

The substance is not readily biodegradable.

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2460
Shipping Name
2-METHYL-2-BUTENE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 2-Methyl-2-butene?

The signal word is danger.

What is the physical form of 2-Methyl-2-butene?

2-Methyl-2-butene is a liquid with no data available color. It has no data available odor.

What is 2-Methyl-2-butene used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for 2-Methyl-2-butene?

This substance has 6 hazard statements:

  • H224: Extremely flammable liquid and vapor.
  • H302: Harmful if swallowed.
  • H304: May be fatal if swallowed and enters airways.
  • H336: May cause drowsiness or dizziness.
  • H341: Suspected of causing genetic defects.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of 2-Methyl-2-butene?

The melting point is -134 C and the boiling point is 35 - 38 C at 1.013 hPa.