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Safety Data Sheet EN

Hydrochloric Acid, 37% w/w

CAS 7647-01-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrochloric Acid, 37% w/w
Product Form
Substance
Product Code
LC14950
Chemical Name
Hydrochloric Acid, 37% w/w
Synonyms
Hydrochloric acid / hydrochloric acid, conc=37%, aqueous solution

Regulatory Identifiers

CAS Number
7647-01-0 Check regulations →

Identified Uses

Laboratory chemical

Manufacturers & Suppliers

LabChem Inc logo

LabChem Inc

manufacturer

Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court, Zelienople, PA 16063 - USA

412-826-5230

http://www.labchem.com

Emergency Contacts

CHEMTREC

1-800-424-9300

CHEMTREC

011-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
Aquatic Acute Cat. 3 H402

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H335 May cause respiratory irritation
H402 Harmful to aquatic life

Precautionary Statements

P260 Do not breathe mist, spray, vapours
P264 Wash exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P273 Avoid release to the environment
P280 Wear eye protection, face protection, protective clothing, protective gloves
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P363 Wash contaminated clothing before reuse
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to Comply with applicable regulations

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Substance type : Multi-constituent. Name : Hydrochloric Acid, 37% w/w

Chemical Name CAS Number Concentration Hazardous
Water 7732-18-5 63% No
Hydrogen Chloride 7647-01-0 37% Yes

Notes

Full text of H-phrases: see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Respiratory difficulties. Possible laryngeal spasm/oedema. Corrosion of the upper respiratory tract.

Skin contact

Wash immediately with PE-glycol 400. Wash immediately with lots of water (15 minutes)/shower. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital.

Symptoms: Caustic burns/corrosion of the skin.

Eye contact

Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist.

Symptoms: Corrosion of the eye tissue. Permanent eye damage.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Do not give chemical antidote. Ingestion of large quantities: immediately to hospital.

Symptoms: Burns to the gastric/intestinal mucosa. Blood in vomit. Possible esophageal perforation. Shock.

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. Take victim to an ophthalmologist. Immediately consult a doctor/medical service. Ingestion of large quantities: immediately to hospital.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

EXTINGUISHING MEDIA FOR SURROUNDING FIRES: All extinguishing media allowed.

Unsuitable media

No unsuitable extinguishing media known.

Specific hazards

Fire hazard: DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Reactions involving a fire hazard: see "Reactivity Hazard". Explosion hazard: INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".

Instructions

Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Firefighter Protection

Heat/fire exposure: compressed air/oxygen apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. No naked flames. In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation. Large spills/in confined spaces: consider evacuation. Wash contaminated clothes. Stop leak if safe to do so. Ventilate area.

Large spill

Large spills/in confined spaces: consider evacuation.

Environmental

Prevent soil and water pollution. Prevent spreading in sewers.

Cleanup methods

Liquid spill: neutralize with soda (sodium carbonate). Neutralized substance: take up in absorbent material. Scoop absorbed substance into closing containers. Damaged/cooled tanks must be emptied. Carefully collect the spill/leftovers. Take collected spill to manufacturer/competent authority. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling.

Materials: absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep away from naked flames/heat. Observe strict hygiene. Keep container tightly closed. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.

Storage

2 - 25 °C

Hygiene

Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.

Fire prevention

Keep away from naked flames/heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

Hands

Gloves.

Eyes

Face shield.

Respiratory

Gas mask with filter type B. Gas mask with filter type E. High vapour/gas concentration: self-contained respirator.

Skin/Body

Materials for protective clothing: GIVE GOOD RESISTANCE: natural rubber. nitrile rubber. Corrosion-proof clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Irritating/pungent odour.
Odor Threshold
No data available
Ph
< 1
Melting Point
No data available
Boiling Point
No data available
Flash Point
Not applicable
Freezing Point
-30 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
No data available
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
---
Relative Density
1.2
Bulk Density
---
Density
1190 kg/m³
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No data available
Solubility
Soluble in water. Water: Complete
Partition Coefficient
0.25 (QSAR)
Solubility In Water
Complete
Solubility In Fat
---
Molecular Weight
36.46 g/mol
Voc Content
Not applicable
Metal Corrosion
---
Dynamic Viscosity
0.0023 Pa.s (15 °C)
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No data available.

Reactivity

Decomposes on exposure to temperature rise: release of (highly) toxic gases/vapours (chlorine). On exposure to air: release of corrosive mist. Reacts violently with (some) bases. Reacts exothermically with many compounds. Reacts with (strong) oxidizers: release of (highly) toxic gases/vapours (chlorine). Reacts with (some) metals: release of highly flammable gases/vapours (hydrogen).

Hazardous reactions

Reacts violently with (some) bases: release of heat.

Avoid

Incompatible materials.

Incompatible

Strong bases. metals. cyanides. silver nitrate.

Decomposition

Hydrogen chloride.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - water : Mild water pollutant (surface water). Ground water pollutant. Maximum concentration in drinking water: 250 mg/l (chloride) (Directive 98/83/EC). Slightly harmful to fishes. Toxic to plankton. pH shift. Insufficient data available on ecotoxicity.

12.1. Toxicity

| Hydrochloric Acid, 37% w/w (7647-01-0) | | | --- | --- | | LC50 fishes 1 | 282 mg/l (96 h; Gambusia affinis; Pure substance) | | EC50 Daphnia 1 | < 56 mg/l (72 h; Daphnia magna; Pure substance) | | LC50 fish 2 | 862 mg/l (Leuciscus idus; Pure substance) | | TLM fish 1 | 282 ppm (96 h; Gambusia affinis; Pure substance) |

12.2. Persistence and degradability

12.2. Persistence and degradability

Biodegradability: not applicable. No (test)data on mobility of the components of the mixture available. Biochemical oxygen demand (BOD): Not applicable. Chemical oxygen demand (COD): Not applicable. ThOD: Not applicable. BOD (% of ThOD): Not applicable.

Biodegradability is not applicable. No data available for mobility. BOD, COD, and ThOD are not applicable.

12.3. Bioaccumulative potential

Log Pow: 0.25 (QSAR) Bioaccumulative potential: Low potential for bioaccumulation (Log Kow < 4).

Low potential for bioaccumulation (Log Kow < 4).

12.4. Mobility in soil

May be harmful to plant growth, blooming and fruit formation.

12.5. Other adverse effects

No additional information available

No additional information available

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle by distillation. Dehydrate/make insoluble. Immobilize the toxic or harmful components. Remove to an authorized dump (Class I). Treat using the best available techniques before discharge into drains or the aquatic environment.

Disposal

Remove waste in accordance with local and/or national regulations.

Waste Codes

KGA category 01 LWCA national code
Directive 2008/98/EC Hazardous waste EU
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1789
Shipping Name
Hydrochloric acid
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Hydrochloric Acid, 37% w/w known by?

Hydrochloric Acid, 37% w/w is also known as: Hydrochloric acid / hydrochloric acid, conc=37%, aqueous solution

What is the hazard signal word for Hydrochloric Acid, 37% w/w?

The signal word is danger.

What is the physical form of Hydrochloric Acid, 37% w/w?

Hydrochloric Acid, 37% w/w is a liquid appearing as liquid. with colourless. color. It has irritating/pungent odour. odor.

What is the solubility of Hydrochloric Acid, 37% w/w?

Soluble in water. Water: Complete

What is Hydrochloric Acid, 37% w/w used for?

Laboratory chemical

What are the hazard statements for Hydrochloric Acid, 37% w/w?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed
  • H314: Causes severe skin burns and eye damage
  • H335: May cause respiratory irritation
  • H402: Harmful to aquatic life

What is the melting point of Hydrochloric Acid, 37% w/w?

The melting point is No data available and the boiling point is No data available.