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Safety Data Sheet EN

Hydrochloric Acid, 31 – 36.7%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrochloric Acid, 31 – 36.7%

Regulatory Identifiers

CAS Number
N/A

Identified Uses

acid etching, steel pickling, oil and gas, ore and mineral, food processing, pharmaceutical, organic chemical synthesis

Manufacturers & Suppliers

A

ASHTA Chemicals Inc.

manufacturer

P.O. Box 858, Ashtabula Ohio 44005

(440) 997-5221

Emergency Contacts

CHEMTREC

(800) 424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P234 Keep only in original container.
P261 Avoid breathing dust/ fume/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water. Shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container with a resistant inner liner.
P405 Store locked up.
P406 Store in corrosive resistant stainless steel container with a resistant inner liner.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hydrochloric acid EC: 231-595-7 7647-01-0 31 - 36% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give humidified air. Give oxygen, but only by a certified physician. Consult a physician.

Skin contact

Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash off with soap and plenty of water. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Remove contact lenses if present and easy to do. Continue rinsing eyes during transport to medical facility.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth thoroughly with water. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Consult a physician.

Immediate Medical Attention

Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing agents compatible with acid and appropriate for the burning material.

Specific hazards

Releases flammable hydrogen gas when reacting with metals.

Instructions

Use standard firefighting procedures and consider the hazards of other involved materials.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing. In case of fire and/or explosion do not breathe fumes.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Follow preplanned emergency procedures. Using full protective equipment, apply appropriate emergency device or other securement technology to stop the leak if possible.

Small spill

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: neutralize the residue with a dilute solution of sodium carbonate.

Large spill

Corrosive liquid. Stop leak if without risk. Do not touch spilled material. Use water spray curtain to knock down vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that vapor is not present at a concentration level above TLV.

Environmental

Avoid discharge into drains, water courses or onto the ground.

Cleanup methods

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Neutralize the residue with a dilute solution of sodium carbonate.

Materials: inert dry material, dilute solution of sodium carbonate

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear appropriate personal protective equipment. Do not get in eyes, on skin, on clothing. Do not breathe mist or vapor. Observe good industrial hygiene practices. Do not empty into drains. Use caution when combining with water; DO NOT add water to acid, ALWAYS add acid to water while stirring to prevent release of heat, steam and fumes.

Storage

Store in a well-ventilated place. Store away from incompatible materials. Store closed containers in a clean, cool, open or well ventilated area. Keep out of sun.

Hygiene

Observe good industrial hygiene practices.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Partition Coefficient
No data available
Bulk Density
8.75 lbs/gal (32% HCl solution) 9.83 lbs/gal (36.5% HCl solution)
Solubility
---
Solidification Point
---
Ph
<1 (in aqueous solution)
Upper Explosive Limit
Not combustible
Flash Point
Not applicable
Flammability
Not combustible
Kinematic Viscosity
---
Molecular Weight
36.46
Explosive Limits
---
Form
---
Colour Intensity
---
Appearance
Colorless to light yellow liquid
Freezing Point
-30°C (-22°F)
Solubility In Water
100%
Relative Density
1.16 (32% HCl solution) 1.19 (36.5% HCl solution)
Softening Point
---
Odor
Pungent (irritating/strong)
Melting Point
-30°C (-22°F)
Colour
---
Density
---
Metal Corrosion
---
Vapor Density
1.267 at 20 °C
Physical State Data
liquid
Decomposition Temperature
No data available
Auto Ignition Temperature
Not applicable
Boiling Point
>100°C (>212°F)
Relative Evaporation Rate
---
Properties Status
---
State Under Standard Conditions
---
Dynamic Viscosity
---
Odor Threshold
0.3ppm (can cause olfactory fatigue)
Solubility In Fat
---
Crystallisation Point
---
Vapor Pressure
84 mm Hg @ 20°C
Lower Explosive Limit
Not combustible
Physical State
liquid
Voc Content
---
Evaporation Rate
No data available
Cloud Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hydrochloric acid is stable under normal conditions and pressures.

Hazardous reactions

Hazardous polymerization WILL NOT occur.

Avoid

Incompatible materials, metals, excess heat, bases.

Incompatible

Bases, amines, metals, permanganates, (e.g. potassium permanganate), fluorine, metal acetylides, hexalithium disilicide.

Decomposition

Hydrogen chloride, chlorine, hydrogen gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1789
Shipping Name
Hydrochloric Acid
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrochloric Acid, 31 – 36.7%?

The signal word is danger.

What is the physical form of Hydrochloric Acid, 31 – 36.7%?

Hydrochloric Acid, 31 – 36.7% is a liquid appearing as colorless to light yellow liquid . It has pungent (irritating/strong) odor.

What is Hydrochloric Acid, 31 – 36.7% used for?

acid etching, steel pickling, oil and gas, ore and mineral, food processing, pharmaceutical, organic chemical synthesis

What are the hazard statements for Hydrochloric Acid, 31 – 36.7%?

This substance has 4 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of Hydrochloric Acid, 31 – 36.7%?

The melting point is -30°C (-22°F) and the boiling point is >100°C (>212°F).