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Safety Data Sheet EN

Sodium Hydrogensulphide 27-50%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sodium Hydrogensulphide 27-50%

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Pulp (paper) Chemical intermediate Tanning agents Impregnation and treatment spray for leather Reducing agent/ Deoxidiser

Manufacturers & Suppliers

Q

QUADRIMEX CHEMICAL

manufacturer

772, Chemin du Mitan 84300 Cavaillon - FRANCE

04 90 78 70 50

Emergency Contacts

London / National Poisons Information Service

(44) 71.635.91.91

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS09 - Environmental hazard

GHS09

Hazard Statements

H290 May be corrosive to metals.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dusts or mists.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P405 Store locked up.
P406 Store in a corrosion resistant container / container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixtures

Mixture of substances listed below with nonhazardous additions.

Chemical Name CAS Number Concentration Hazardous
Sulfhydrate de sodium EC: 240-778-0 16721-80-5 27 - 50% Yes

For the wording of the listed hazard phrases refer to section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of unconsciousness place patient stably in side position for transportation.

Skin contact

If skin irritation continues, consult a doctor. Immediately wash with water and soap and rinse thoroughly.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Do not induce vomiting; call for medical help immediately. Drink plenty of water and provide fresh air. Call for a doctor immediately.

Immediate Medical Attention

Consult a doctor after eye contact. Call for medical help immediately after swallowing.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eyes

Tightly sealed goggles

Respiratory

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Skin/Body

Use protective suit.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
---
Flash Point
Not applicable.
Form
Fluid
Voc Content
0.00 %
Physical State Data
liquid
Cloud Point
---
Dynamic Viscosity
5.5 mPas
Solubility In Fat
---
Solubility In Water
Fully miscible.
Odor
Like rotten eggs (mercaptans)
Evaporation Rate
Not determined.
Crystallisation Point
---
Ph
11.2
Partition Coefficient
---
Explosive Limits
---
Freezing Point
---
Lower Explosive Limit
---
Colour Intensity
---
Upper Explosive Limit
---
Density
1.22 g/cm
Appearance
---
Metal Corrosion
---
Bulk Density
---
Solidification Point
---
Colour
Yellow
Vapor Density
Not determined.
Flammability
Not applicable.
Solubility
---
Molecular Weight
---
Kinematic Viscosity
Not determined.
Relative Evaporation Rate
---
Physical State
Fluid
Melting Point
---
Boiling Point
110 C
State Under Standard Conditions
---
Properties Status
---
Auto Ignition Temperature
Product is not selfigniting.
Odor Threshold
Not determined.
Vapor Pressure
Not determined.
Softening Point
---
Decomposition Temperature
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2922
Shipping Name
CORROSIVE LIQUID, TOXIC, N.O.S. (SODIUM HYDROSULPHIDE, HYDRATED)
Transport Class
8 Corrosive substances.
Packing Group
II
ADR

Warning: Corrosive substances.

IMDG

Warning: Corrosive substances.

IATA

Warning: Corrosive substances.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sodium Hydrogensulphide 27-50%?

The signal word is danger.

What is the physical form of Sodium Hydrogensulphide 27-50%?

Sodium Hydrogensulphide 27-50% is a fluid with yellow color. It has like rotten eggs (mercaptans) odor.

What is Sodium Hydrogensulphide 27-50% used for?

Pulp (paper) Chemical intermediate Tanning agents Impregnation and treatment spray for leather Reducing agent/ Deoxidiser

What are the hazard statements for Sodium Hydrogensulphide 27-50%?

This substance has 4 hazard statements:

  • H290: May be corrosive to metals.
  • H301: Toxic if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H400: Very toxic to aquatic life.

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