Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP
- Product Code
- 137000
Regulatory Identifiers
- CAS Number
- 64-19-7 Check regulations →
- REACH No.
- 01-2119475328-30-XXXX
Identified Uses
Pharmaceutical production In compliance with the conditions described in the annex to this safety data sheet.
Manufacturers & Suppliers
Merck KGaA
manufacturer
64271 Darmstadt, Germany
+49 6151 72-0
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS05
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
acetic acid
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| acetic acid EC: 200-580-7 | 64-19-7 | 80 - 100% | Yes |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Notes
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
First Aid Measures
Emergency procedures for chemical exposure incidents
fresh air. Call in physician.
Symptoms: Cough, Shortness of breath, Pneumonia
Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Symptoms: Irritation and corrosion
rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Symptoms: Risk of corneal clouding. Risk of blindness!
make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
Symptoms: Irritation and corrosion, Nausea, Vomiting, bronchitis, gastric spasms, Shortness of breath, shock, Circulatory collapse, Pneumonia
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Foam, Carbon dioxide (CO2), Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Remove container from danger zone and cool with water.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not let product enter drains. Risk of explosion.
Take up with liquid-absorbent and neutralising material. Dispose of properly. Clean up affected area.
Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)
Related Products
Similar products with comparable safety profiles
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---
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Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Observe label precautions.
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Keep away from open flames, hot surfaces and sources of ignition.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.
full contact: Glove material: butyl-rubber Glove thickness: 0,7 mm Break through time: 480 min splash contact: Glove material: natural latex Glove thickness: 0,6 mm Break through time: 30 min The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 898 Butoject (full contact), KCL 706 Lapren (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Tightly fitting safety goggles
required when vapours/aerosols are generated. Recommended Filter type: filter E-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Flame retardant antistatic protective clothing.
Do not let product enter drains. Risk of explosion.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The data for this section has not been processed yet.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
Bioaccumulation is not expected.
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
The substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
12.6 Other adverse effects
The substance may cause harmful effects due to pH shift and is caustic even in diluted form. Discharge into the environment should be avoided.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
The data for this section has not been processed yet.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN 2789
- Shipping Name
- ACETIC ACID, GLACIAL
- Transport Class
- 8
- Packing Group
- II
Regulatory Information
Chemical regulations, safety assessments, and compliance status
EU regulations: Major Accident Hazard SEVESO III, Occupational restrictions, Ozone layer, POPs, SVHC.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP?
The signal word is danger.
What is the physical form of Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP?
Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP is a liquid with colourless color. It has stinging odor.
What is Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP used for?
Pharmaceutical production In compliance with the conditions described in the annex to this safety data sheet.
What are the hazard statements for Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP?
This substance has 2 hazard statements:
- H226: Flammable liquid and vapour.
- H314: Causes severe skin burns and eye damage.
What is the melting point of Acetic acid (glacial) 100% EMPROVE® EXPERT Ph Eur,BP,JP,USP?
The melting point is 17 C and the boiling point is 116 - 118 C at 1.013 hPa.