NextSDS Logo
Safety Data Sheet EN

Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur

CAS 64-19-7

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report.

Get Free Audit
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur
Product Code
100063
Chemical Name
Acetic acid

Regulatory Identifiers

CAS Number
64-19-7 Check regulations →
REACH No.
01-2119475328-30-XXXX

Identified Uses

Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

Hazard Statements

H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P210 Keep away from heat.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report

Free Audit
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Formula CHCOOH CHO (Hill) Molar mass 60,05 g/mol

Chemical Name CAS Number Concentration Hazardous
acetic acid EC: 200-580-7 64-19-7 100% Yes

Notes

Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Symptoms: bronchitis, Shortness of breath

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Symptoms: Irritation and corrosion

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.

Symptoms: Risk of corneal clouding. Risk of blindness!

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Symptoms: gastric spasms, Nausea, Vomiting

Immediate Medical Attention

Call in physician / Call a physician immediately / Immediately call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Collect, bind, and pump off spills. Take up with liquid-absorbent and neutralising material. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge. Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: KCL 898 Butoject®; splash contact: Glove material: butyl-rubber, Glove thickness: 0,7 mm, Break through time: > 480 min; Glove material: natural latex, Glove thickness: 0,6 mm, Break through time: > 30 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374.

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: filter E-(P2). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Flash Point
39 °C
Solidification Point
---
Form
liquid
Colour Intensity
---
Physical State
liquid
Metal Corrosion
May be corrosive to metals.
Density
1,05 g/cm3 at 20 °C
Solubility In Fat
---
Vapor Pressure
15,4 hPa at 20 °C
Solubility
---
Freezing Point
---
Cloud Point
---
Lower Explosive Limit
4 %(V)
Evaporation Rate
No information available.
Bulk Density
---
Softening Point
---
State Under Standard Conditions
---
Odor Threshold
0,2 - 100,1 ppm
Ph
2,5 at 50 g/l 20 °C
Crystallisation Point
---
Flammability
Not applicable
Kinematic Viscosity
1,17 mm2/s at 20 °C
Melting Point
17 °C
Auto Ignition Temperature
485 °C
Solubility In Water
602,9 g/l at 25 °C
Relative Evaporation Rate
---
Colour
colourless
Appearance
---
Upper Explosive Limit
19,9 %(V)
Physical State Data
liquid
Molecular Weight
---
Dynamic Viscosity
1,22 mPa.s at 20 °C
Vapor Density
---
Odor
stinging
Decomposition Temperature
Distillable in an undecomposed state at normal pressure.
Relative Density
No information available.
Partition Coefficient
log Pow: -0,17 (25 °C)
Properties Status
---
Voc Content
---
Explosive Limits
---
Boiling Point
116 - 118 °C at 1.013 hPa
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapour/air-mixtures are explosive at intense warming.

Hazardous reactions

Risk of explosion with: peroxi compounds, perchloric acid, fuming sulfuric acid, phosphorus halides, hydrogen peroxide, chromium(VI) oxide, potassium permanganate, Peroxides, Strong oxidizing agents. Risk of ignition or formation of inflammable gases or vapours with: Metals, Iron, Zinc, magnesium, Mild steel. Possible formation of: Hydrogen. Violent reactions possible with: strong alkalis, anhydrides, Aldehydes, alkali hydroxides, nonmetallic halides, ethanolamine, Acetaldehyde, Alcohols, halogen-halogen compounds, chlorosulfonic acid, chromosulfuric acid, Potassium hydroxide, Nitric acid

Avoid

Temperatures < 17 °C. Heating.

Incompatible

various metals

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2789
Shipping Name
ACETIC ACID, GLACIAL
Transport Class
8 (3)
Packing Group
II
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Dir 94/33/EC on the protection of young people at work.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The signal word is danger.

What is the physical form of Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colourless color. It has stinging odor.

What is Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?

Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.

What are the hazard statements for Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

This substance has 3 hazard statements:

  • H226: Flammable liquid and vapour.
  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The melting point is 17 °C and the boiling point is 116 - 118 °C at 1.013 hPa.