Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur
- Product Code
- 100063
- Chemical Name
- Acetic acid
Regulatory Identifiers
- CAS Number
- 64-19-7 Check regulations →
- REACH No.
- 01-2119475328-30-XXXX
Identified Uses
Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.
Manufacturers & Suppliers
Merck KGaA
manufacturer
64271 Darmstadt, Germany
+49 6151 72-0
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS05
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
Formula CHCOOH CHO (Hill) Molar mass 60,05 g/mol
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| acetic acid EC: 200-580-7 | 64-19-7 | 100% | Yes |
Notes
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
First Aid Measures
Emergency procedures for chemical exposure incidents
After inhalation: fresh air. Call in physician.
Symptoms: bronchitis, Shortness of breath
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Symptoms: Irritation and corrosion
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Symptoms: Risk of corneal clouding. Risk of blindness!
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
Symptoms: gastric spasms, Nausea, Vomiting
Immediate Medical Attention
Call in physician / Call a physician immediately / Immediately call in ophthalmologist.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Carbon dioxide (CO2), Foam, Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Remove container from danger zone and cool with water.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not let product enter drains. Risk of explosion.
Collect, bind, and pump off spills. Take up with liquid-absorbent and neutralising material. Clean up affected area.
Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)
Related Products
Similar products with comparable safety profiles
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Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Observe label precautions.
Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature see product label.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge. Keep away from heat and sources of ignition.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.
full contact: KCL 898 Butoject®; splash contact: Glove material: butyl-rubber, Glove thickness: 0,7 mm, Break through time: > 480 min; Glove material: natural latex, Glove thickness: 0,6 mm, Break through time: > 30 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374.
Tightly fitting safety goggles
required when vapours/aerosols are generated. Recommended Filter type: filter E-(P2). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
Flame retardant antistatic protective clothing.
Do not let product enter drains. Risk of explosion.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is chemically stable under standard ambient conditions (room temperature).
Vapour/air-mixtures are explosive at intense warming.
Risk of explosion with: peroxi compounds, perchloric acid, fuming sulfuric acid, phosphorus halides, hydrogen peroxide, chromium(VI) oxide, potassium permanganate, Peroxides, Strong oxidizing agents. Risk of ignition or formation of inflammable gases or vapours with: Metals, Iron, Zinc, magnesium, Mild steel. Possible formation of: Hydrogen. Violent reactions possible with: strong alkalis, anhydrides, Aldehydes, alkali hydroxides, nonmetallic halides, ethanolamine, Acetaldehyde, Alcohols, halogen-halogen compounds, chlorosulfonic acid, chromosulfuric acid, Potassium hydroxide, Nitric acid
Temperatures < 17 °C. Heating.
various metals
in the event of fire: See section 5.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 2789
- Shipping Name
- ACETIC ACID, GLACIAL
- Transport Class
- 8 (3)
- Packing Group
- II
yes
yes
no
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Take note of Dir 94/33/EC on the protection of young people at work.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
The signal word is danger.
What is the physical form of Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colourless color. It has stinging odor.
What is Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?
Reagent for analysis, Chemical production In compliance with the conditions described in the annex to this safety data sheet.
What are the hazard statements for Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
This substance has 3 hazard statements:
- H226: Flammable liquid and vapour.
- H290: May be corrosive to metals.
- H314: Causes severe skin burns and eye damage.
What is the melting point of Acetic acid (glacial) 100% anhydrous for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
The melting point is 17 °C and the boiling point is 116 - 118 °C at 1.013 hPa.