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Safety Data Sheet EN

WACKER® Vinylacetat Monomer stab.

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
WACKER® Vinylacetat Monomer stab.

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial. Industrial monomer to be polymerized or reacted.

Uses advised against

All other areas of application to be agreed with the Application Engineering/ Technical Marketing Department of the manufacturer.

Manufacturers & Suppliers

W

Wacker Chemie AG

manufacturer

Hanns-Seidel-Platz 4, D 81737 München

+49 89 6279-0

Emergency Contacts

NRCC

+86-532-83 88 90 90

National Response Center

+49 621 60-43333

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aquatic Chronic Cat. 3
Acute Tox. Cat. 5
Aquatic Acute Cat. 3
Flam. Liq. Cat. 2
Acute Tox. Cat. 4
Carc. Cat. 2
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P281 Use personal protective equipment as required.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P370 + P378 In case of fire: Use water spray, extinguishing powder, foam or carbon dioxide for extinction.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to waste disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Vinyl acetate EC: 203-545-4 108-05-4 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air.

Skin contact

Wash with plenty of water or water and soap. In the event of a visible skin change or other complaints, seek medical advice (show label or SDS where possible).

Eye contact

Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation.

Ingestion

Give several small portions of water to drink. Do not induce vomiting.

Immediate Medical Attention

Further toxicology information in section 11 must be observed.

Medical Treatment

Further toxicology information in section 11 must be observed.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water spray, extinguishing powder, foam, carbon dioxide.

Unsuitable media

water jet.

Specific hazards

At low oxygen level: carbon monoxide.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unprotected persons away. Avoid inhaling mists and vapours. Avoid contact with eyes and skin.

Small spill

Absorb with a liquid binding material such as diatomaceous earth

Large spill

Contain larger amounts and pump up into suitable containers.

Environmental

Prevent material from entering sewers or surface waters.

Cleanup methods

Absorb with a liquid binding material, pump up into suitable containers.

Materials: diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure adequate ventilation. Do not mix with alkalis, strong acids, oxidizing agents.

Storage

Keep container tightly closed. Store in a dry and cool place.

Fire prevention

Cool endangered containers with water. Extinguish flames only when no further combustible mixtures can be formed.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Observe regulations for protection against explosion.

Hands

rubber gloves, protective gloves coated with neoprene . Gloves designed to protect against spray and splashes only. Wear gloves for short periods only < 10 mins.

Eyes

protective goggles .

Respiratory

gas mask filter A . In case of long or strong exposure: positive pressure self contained breathing apparatus .

Skin/Body

protective clothing .

Environmental

Prevent material from entering surface waters and soil.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
liquid
Odor
pleasant
Odor Threshold
1 mg/m
Ph
not applicable
Melting Point
-100 - -93 C
Boiling Point
72 - 73 C at 1013 hPa (DIN 51751)
Flash Point
-7 C (ISO 13736)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
426 hPa at 50 C; 120 hPa at 20 C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,932 g/cm at 20 C (DIN 51757)
Flammability
---
Upper Explosive Limit
13,4 Vol-%
Lower Explosive Limit
2,6 Vol-%
Explosive Limits
---
Auto Ignition Temperature
385 C (DIN 51794)
Decomposition Temperature
No decomposition when used according to regulations.
Solubility
totally miscible with common organic solvents
Partition Coefficient
0,73 at 20 C (Log p OW )
Solubility In Water
23 g/l at 20 C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0,43 mPa.s at 20 C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Reactivity

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.

Hazardous reactions

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.

Avoid

Ensure adequate stabilisation. Possibility of spontaneous polymerization of unstabilized product by ambient temperature.

Incompatible

alkalis, amines, oxidizing agents, strong acids.

Decomposition

If stored and handled properly: none known. By hydrolysis: Acetaldehyde.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product details: | Result/Effect | Species/Test system | Source | | --- | --- | --- | | EC50: 12,6 mg/l | static Daphnia magna (48 h) | ECHA OECD 202 | | NOEC: 4,77 mg/l | static Daphnia magna (48 h) | ECHA OECD 202 | | EC50 (growth rate): 12,7 mg/l | Pseudokirchneriella subcapitata (72 h) | ECHA OECD 201 | | NOEC (growth rate): 5,96 mg/l | Pseudokirchneriella subcapitata (72 h) | ECHA OECD 201 | | EC3: 6 mg/l | Pseudomonas putida (16 h) | ECHA | | NOEC (early life stage test): 0,16 mg/l | dynamic minnow (Pimephales promelas) (34 d) | ECHA OECD 210 |

12.2 Persistence and degradability

Product details: Biodegradation: | Result | Test system/Method | Source | | --- | --- | --- | | 82 - 98 % / 14 d | no data available | ECHA OECD 301C |

12.3 Bioaccumulative potential

Assessment: Bioaccumulation is not expected to occur. Product details: | Result/Effect | Species/Test system | Source | | --- | --- | --- | | Bioconcentration factor (BCF): <= 100 | no data available | no data available |

Bioaccumulation is not expected to occur.

12.4 Mobility in soil

Assessment: The partition coefficient soil/water (logKoc) indicates a very high mobility in soil. Product details: adsorption - desorption: | Result | Test system/Method | Source | | --- | --- | --- | | log K_{OC}: 0,86 | Estimation of the adsorption coefficient (Koc) on soil and on sewage sludge using high performance liquid chromatography (HPLC) | test report OECD 121 |

The partition coefficient soil/water (logKoc) indicates a very high mobility in soil.

12.5 Other adverse effects

none known

none known

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1301
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

National and local regulations must be observed.

Chemical Safety Assessment Not performed

For information on labelling please refer to section 2 of this document.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for WACKER® Vinylacetat Monomer stab.?

The signal word is danger.

What is the physical form of WACKER® Vinylacetat Monomer stab.?

WACKER® Vinylacetat Monomer stab. is a liquid with colourless color. It has pleasant odor.

What is the solubility of WACKER® Vinylacetat Monomer stab.?

totally miscible with common organic solvents

What is WACKER® Vinylacetat Monomer stab. used for?

Industrial. Industrial monomer to be polymerized or reacted.

What are the hazard statements for WACKER® Vinylacetat Monomer stab.?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of WACKER® Vinylacetat Monomer stab.?

The melting point is -100 - -93 C and the boiling point is 72 - 73 C at 1013 hPa (DIN 51751).