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Safety Data Sheet EN

VEOVA™ Vinyl Ester Monomer 10

CAS 51000-52-3
EC 256-905-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
VEOVA™ Vinyl Ester Monomer 10
Product Code
K3112
Chemical Name
Vinyl ester

Regulatory Identifiers

CAS Number
51000-52-3 Check regulations →
EC Number
256-905-8 Check regulations →
REACH No.
01-2119429886-24-0000

Identified Uses

Industrial manufacturing including synthesis of the substance and blending, or use as an intermediate or monomer in reactions by the manufacturer or DU.

Manufacturers & Suppliers

H

Hexion Inc.

manufacturer

180 East Broad Street, Columbus, OH, 43215 USA

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type uvcb
Chemical Name CAS Number Concentration Hazardous
vinyl neodecanoate EC: 256-905-8 51000-52-3 100% Yes

Notes

See Section 16 for the full text of the H statements declared above. There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No known significant effects or critical hazards. No specific data.

Skin contact

Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards. No specific data.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Symptoms: No known significant effects or critical hazards. No specific data.

Ingestion

Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel.

Symptoms: No known significant effects or critical hazards. No specific data.

Immediate Medical Attention

Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO2, alcohol-resistant foam or water spray (fog).

Unsuitable media

Do not use water jet.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Wash spillages into an effluent treatment plant.

Materials: sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see section 8 of SDS). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10 of SDS) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Material: 730 Camatril Minimum break through time: 10 min Material: 898 Butoject Minimum break through time: 480 min Producer: This recommendation is valid only for our Product as delivered. If this product will be mixed with other substances you need to contact a supplier of CE approved protective gloves (e.g. KCL GmbH, D-36124 Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email: vertrieb@kcl.de).

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Cloud Point
---
Solidification Point
---
Ph
Not available (not measured)
Form
---
Melting Point
< -73,5 °C
Crystallisation Point
---
Partition Coefficient
4,9
Decomposition Temperature
Not available (not measured)
Relative Evaporation Rate
---
Vapor Pressure
38,6 Pa @ 20 °C
Freezing Point
< -73,5 °C
Metal Corrosion
---
Odor
Ester.
Evaporation Rate
Not available (not measured)
Properties Status
---
Physical State
Liquid
Density
---
Flammability
---
Relative Density
0,8793
Physical State Data
liquid
Solubility In Fat
---
Lower Explosive Limit
Not available
Bulk Density
---
Boiling Point
212 °C
Molecular Weight
---
Voc Content
---
Flash Point
> 94 °C
Colour Intensity
---
Colour
Colorless/Colourless
Dynamic Viscosity
Not available (not measured)
Solubility
Not available (not measured)
Upper Explosive Limit
Not available
Softening Point
---
Auto Ignition Temperature
267 - 279 °C
Solubility In Water
5,0 mg/l
Explosive Limits
---
State Under Standard Conditions
---
Appearance
Liquid, Colorless/Colourless
Kinematic Viscosity
2,11 mm2/s @ 20 °C, 1,65 mm2/s @ 40 °C
Odor Threshold
Not available (not measured)
Vapor Density
6,8 [Air = 1] (Estimated.)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Inhibitor: 4-methoxyphenol - The product is stable.

Reactivity

Stable under normal conditions.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

No specific data.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Neodecanoic acid, ethenyl ester)
Transport Class
9
Packing Group
III
ADR

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The substance(s) in this product has (have) been Registered, or are exempted from registration, according to Regulation (EC) No. 1907/2006 (REACH).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for VEOVA™ Vinyl Ester Monomer 10?

The signal word is warning.

What is the physical form of VEOVA™ Vinyl Ester Monomer 10?

VEOVA™ Vinyl Ester Monomer 10 is a liquid appearing as liquid, colorless/colourless with colorless/colourless color. It has ester. odor.

What is the solubility of VEOVA™ Vinyl Ester Monomer 10?

Not available (not measured)

What is VEOVA™ Vinyl Ester Monomer 10 used for?

Industrial manufacturing including synthesis of the substance and blending, or use as an intermediate or monomer in reactions by the manufacturer or DU.

What are the hazard statements for VEOVA™ Vinyl Ester Monomer 10?

This substance has 1 hazard statement:

  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of VEOVA™ Vinyl Ester Monomer 10?

The melting point is < -73,5 °C and the boiling point is 212 °C.