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Safety Data Sheet EN

DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK
Product Form
AEROSOL

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Consumer use; Solvent borne coating for interior use.

Manufacturers & Suppliers

ICI Paints AkzoNobel logo

ICI Paints AkzoNobel

manufacturer

Wexham Road, Slough, Berkshire, SL2 5DS, U.K.

+44 (0) 333 222 71 71

www.hammerite.co.uk

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1 H222
Skin Irrit. Cat. 2 H315
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H222 Extremely flammable aerosol.
H229 Pressurized container: may burst if heated.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing dust or mist.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F.
P501 Dispose of contents and container in accordance with all local, regional, national or international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixture
Chemical Name CAS Number Concentration Hazardous
gaz de ptrole liqufis EC: 270-704-2 68476-85-7 25 - 50% Yes
hydrocarbon, C9-C11, n- alkane, iso-alkane, cyclic, <2% of aromatics EC: 918-481-9 64742-48-9 12% Yes
n-butyl acetate substance with a Community workplace exposure limit EC: 204-658-1 123-86-4 7.3% Yes
Hydrocarbons, C6, isoalkanes, <5% n-hexane EC: 931-254-9 --- 5% Yes
Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n- hexane EC: 926-605-8 --- 5% Yes
Hydrocarbons, C6-C7, n- alkanes, isoalkanes, cyclics, <5% n-hexane EC: 921-024-6 --- 5% Yes
Hydrocarbons, C7, n- alkanes, isoalkanes, cyclics EC: 927-510-4 --- 5% Yes
Cyclohexane stof waarvoor binnen de Gemeenschap een blootstellingsgrens op de werkvloer geldt EC: 203-806-2 110-82-7 5% Yes
nhexaan EC: 203-777-6 110-54-3 1% Yes
Reaction mass of ethylbenzene and xylene EC: 905-588-0 --- 0.3% Yes

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Adverse symptoms may include the following: irritation redness

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: Adverse symptoms may include the following: pain or irritation watering redness

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Ingestion may cause nausea, diarrhea and vomiting.

Immediate Medical Attention

Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Medical Treatment

No specific treatment.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time >480 minutes according to EN374) is recommended. Recommended gloves: Viton or Nitrile, thickness 0.38 mm. When only brief contact is expected, a glove with protection class of 2 or higher (breakthrough time >30 minutes according to EN374) is recommended. Recommended gloves: Nitrile, thickness 0.12 mm. Gloves should be replaced regularly and if there is any sign of damage to the glove material. The performance or effectiveness of the glove may be reduced by physical/ chemical damage and poor maintenance. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included in the user's risk assessment.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or better. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Voc Content
---
Explosive Limits
---
Properties Status
---
Bulk Density
---
Relative Density
0.681
Density
---
Metal Corrosion
---
Solubility In Water
Not soluble [OECD (TG 105)]
Form
---
Vapor Pressure
Petroleum gases, liquefied: 3097.22 mm Hg (412.9 kPa) at 20°C; cyclohexane: 93.01 mm Hg (12.4 kPa) at 20°C; n-butyl acetate: 11.25 mm Hg (1.5 kPa) at 20°C
Dynamic Viscosity
---
Crystallisation Point
---
Evaporation Rate
---
Lower Explosive Limit
1.3%
Colour
Gray.
Flammability
Not available.
Upper Explosive Limit
8.4%
Softening Point
---
Auto Ignition Temperature
Not available.
Solubility
---
Freezing Point
Not available.
Odor
Characteristic.
Flash Point
Closed cup: - 18 (-0.4F) [Pensky-Martens]
Cloud Point
---
Decomposition Temperature
Not available.
Vapor Density
Not available.
Solubility In Fat
---
Ph
Not applicable. [DIN EN 1262]
Kinematic Viscosity
Kinematic (room temperature): 29 mm2/s [DIN EN ISO 3219] Kinematic (40): 29 mm2/s [DIN EN ISO 3219]
Relative Evaporation Rate
---
Appearance
---
Solidification Point
---
Physical State
Liquid.
Molecular Weight
---
State Under Standard Conditions
---
Colour Intensity
---
Odor Threshold
Not available.
Physical State Data
liquid
Melting Point
Not available.
Boiling Point
34 (93.2F)
Partition Coefficient
Not applicable.
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1950
Shipping Name
AEROSOLS
ADR

The environmentally hazardous substance mark is not required when transported in sizes of 5 L or 5 kg.

IMDG

The marine pollutant mark is not required when transported in sizes of 5 L or 5 kg.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK?

The signal word is danger.

What is the physical form of DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK?

DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK is a liquid. with gray. color. It has characteristic. odor.

What is DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK used for?

Consumer use; Solvent borne coating for interior use.

What are the hazard statements for DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK?

This substance has 5 hazard statements:

  • H222: Extremely flammable aerosol.
  • H229: Pressurized container: may burst if heated.
  • H315: Causes skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of DIRECT TO RUST METAL PAINT SMOOTH AEROSOL BLACK?

The melting point is Not available. and the boiling point is 34 (93.2F).

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