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Safety Data Sheet EN

Sulfuric acid 98% for analysis EMSURE®

CAS 7664-93-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sulfuric acid 98% for analysis EMSURE®
Product Code
1.12080
Chemical Name
Sulfuric acid

Regulatory Identifiers

CAS Number
7664-93-9 Check regulations →

Identified Uses

Reagent for analysis, Chemical production

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient's responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

manufacturer

3050 SPRUCE ST, ST. LOUIS MO 63103, UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P234 Keep only in original container.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
sulphuric acid EC: 231-639-5 7664-93-9 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Sulfur oxides. Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material. Dispose of properly. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

No metal containers. Tightly closed. Recommended storage temperature see product label.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Change contaminated clothing and immerse in water. Preventive skin protection. Wash hands and face after working with substance.

Hands

Full contact: Material: Viton®, Minimum layer thickness: 0.7 mm, Break through time: 480 min, Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). Splash contact: Material: butyl-rubber, Minimum layer thickness: 0.7 mm, Break through time: 120 min, Material tested: Butoject® (KCL 898).

Eyes

Tightly fitting safety goggles. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Recommended Filter type: Filter type P2. Required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid, colorless
Colour
colorless
Colour Intensity
---
Form
liquid
Odor
odorless
Odor Threshold
Not applicable
Ph
1.2 at 5 g/l
Melting Point
10.31 °C (50.56 °F)
Boiling Point
290 °C 554 °F at 1,013 hPa
Flash Point
No data available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
1.33 hPa at 145.8 °C (294.4 °F)
Vapor Density
3.39 - (Air = 1.0)
Relative Density
No data available
Bulk Density
Not applicable
Density
1.80 - 1.84 g/cm3
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
soluble
Partition Coefficient
Not applicable for inorganic substances
Solubility In Water
soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

A risk of explosion and/or of toxic gas formation exists with the following substances: Water, Alkali metals, alkali compounds, Ammonia, Aldehydes, acetonitrile, Alkaline earth metals, alkalines, Acids, alkaline earth compounds, Metals, metal alloys, Oxides of phosphorus, phosphorus, hydrides, halogen-halogen compounds, oxyhalogenic compounds, permanganates, nitrates, carbides, combustible substances, organic solvent, acetylidene, Nitriles, organic nitro compounds, anilines, Peroxides, picrates, nitrides, lithium silicide, iron(III) compounds, bromates, chlorates, Amines, perchlorates, hydrogen peroxide

Avoid

no information available

Incompatible

animal/vegetable tissues Contact with metals liberates hydrogen gas.

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1830
Shipping Name
Sulfuric acid
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sulfuric acid 98% for analysis EMSURE®?

The signal word is danger.

What is the physical form of Sulfuric acid 98% for analysis EMSURE®?

Sulfuric acid 98% for analysis EMSURE® is a liquid appearing as liquid, colorless with colorless color. It has odorless odor.

What is the solubility of Sulfuric acid 98% for analysis EMSURE®?

soluble

What is Sulfuric acid 98% for analysis EMSURE® used for?

Reagent for analysis, Chemical production

What are the hazard statements for Sulfuric acid 98% for analysis EMSURE®?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Sulfuric acid 98% for analysis EMSURE®?

The melting point is 10.31 °C (50.56 °F) and the boiling point is 290 °C 554 °F at 1,013 hPa.