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Safety Data Sheet EN

Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur

CAS 64-18-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur
Product Code
1.00264
Chemical Name
Formic acid

Regulatory Identifiers

CAS Number
64-18-6 Check regulations →
REACH No.
01-2119491174-37-XXXX

Identified Uses

Reagent for analysis, Chemical production

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Formic acid EC: 200-579-1 64-18-6 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most). Call a physician immediately.

Symptoms: Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Cover drains. Collect, bind, and pump off spills. Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorised persons. Protected from light.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material : Chloroprene, Break through time : 480 min, Glove thickness : 0,65 mm, Protective index : Full contact, Manufacturer : KCL 720 Camapren®. Material : Latex gloves, Break through time : 60 min, Glove thickness : 0,6 mm, Protective index : Splash contact, Manufacturer : Lapren® (KCL 706 / Aldrich Z677558, Size M). Remarks : This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type : Filter E-(P3). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid (20 °C, 1.013 hPa)
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
stinging
Odor Threshold
0,02 ppm
Ph
2,2 (20 °C)
Melting Point
8,5 °C
Boiling Point
100,80 °C (1.013 hPa)
Flash Point
47 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
171 hPa (50 °C)
Vapor Density
---
Relative Density
1,22 (20 °C)
Bulk Density
---
Density
1,22 g/cm³ (20 °C)
Flammability
---
Upper Explosive Limit
38 % (V)
Lower Explosive Limit
18 % (V)
Explosive Limits
---
Auto Ignition Temperature
540 °C
Decomposition Temperature
350 °C
Solubility
---
Partition Coefficient
log Pow: -2,1 (23 °C)
Solubility In Water
miscible in all proportions, (experimental)
Solubility In Fat
---
Molecular Weight
46,03 g/mol
Voc Content
---
Metal Corrosion
3,7 mm/a
Dynamic Viscosity
1,8 mPa.s (20 °C)
Kinematic Viscosity
1,47 mm²/s (20 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapour/air-mixtures are explosive at intense warming.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Aluminium. Risk of explosion with: organic nitro compounds, sodium hypochlorite, hydrogen peroxide, furfuryl alcohol. Generates dangerous gases or fumes in contact with: alkalines, Strong oxidizing agents, sulfuric acid, nonmetallic oxides, metal catalysts, Oxides of phosphorus, Nitric acid, nitrates. Exothermic reaction with: alkaline earth hydroxides, alkali hydroxides, bases, Amines.

Avoid

Heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1779
Shipping Name
FORMIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur?

The signal word is danger.

What is the physical form of Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur?

Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur is a liquid (20 °c, 1.013 hpa) with colourless color. It has stinging odor.

What is Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur used for?

Reagent for analysis, Chemical production

What are the hazard statements for Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur?

This substance has 4 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.

What is the melting point of Formic acid 98-100% for analysis EMSURE® ACS,Reag. Ph Eur?

The melting point is 8,5 °C and the boiling point is 100,80 °C (1.013 hPa).