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Safety Data Sheet EN

884/L 24557 herkula ultraprint spezial ceruse bl

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
884/L 24557 herkula ultraprint spezial ceruse bl
Product Code
884/L 24557
Synonyms
ceruse bl.

Regulatory Identifiers

CAS Number
N/A

Identified Uses

colour / ink for use in industrial installations or professional treatment only

Uses advised against

Consumer use

Manufacturers & Suppliers

h

herkula

manufacturer

FARBWERKE HERKULA SA-AG logo

FARBWERKE HERKULA SA-AG

manufacturer

Industriezone I, Friedensstrasse 21, 4780 St.Vith, BELGIUM

+32 (0) 80 22 87 63

http://www.herkula.com

Emergency Contacts

GBK Dangerous Goods Consulting LTD

+49 (0) 61 32 84 463

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P280 Wear protective gloves and eye/face protection.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
hexamethylene diacrylate EC: 235-921-9 13048-33-4 10 - 30% Yes
Dipentaerythritol Pentaacrylate EC: 800-838-4 1384855-91-7 10 - 30% Yes
Bisphenol-A Epoxy Diacrylate EC: 500-130-2 55818-57-0 1 - 10% Yes
2-Hydroxy-2-methylpropiophenone EC: 231-272-0 7473-98-5 1 - 10% Yes
Ethoxylated Trimethylopropane Triacrylate EC: 500-066-5 28961-43-5 1 - 10% Yes
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate EC: 256-032-2 42978-66-5 1 - 10% Yes
Ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate EC: 282-810-6 84434-11-7 0.1 - 1% Yes
Tripropylenglycol, Esters with acrylic acid, reaction products with diethylamine EC: 601-101-8 111497-86-9 0.1 - 1% Yes

Full text of classification: see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial respiration.

Skin contact

Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. Conditions to avoid: UV-radiation/sunlight

Symptoms: Causes mild skin irritation.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately.

Ingestion

If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting.

Immediate Medical Attention

Seek medical advice immediately (for eye contact and ingestion). In all cases of doubt, or when symptoms persist, seek medical advice.

Medical Treatment

First Aid, decontamination, treatment of symptoms.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, carbon dioxide, Powder, spray mist, (water)

Unsuitable media

strong water jet

Specific hazards

Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.

Instructions

Cool closed containers that are near the source of the fire.

Firefighter Protection

Provide a conveniently located respiratory protective device.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.

Environmental

Do not allow to enter into surface water or drains.

Cleanup methods

Clean using cleansing agents. Do not use solvents.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used. Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations.

Storage

Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. Keep only in the original container.

Hygiene

When using do not eat, drink or smoke.

Fire prevention

Keep away from heat sources, sparks and open flames.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.

Hands

For prolonged or repeated handling the following glove material must be used: Tested protective gloves must be worn. Thickness of the glove material > 0,4 mm ; Breakthrough time: > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles EN ISO 374

Eyes

Wear closely fitting protective glasses in case of splashes.

Respiratory

If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Use only respiratory protection equipment with CE-symbol including four digit test number.

Skin/Body

Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.

Environmental

Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Vapor Density
not applicable
Flash Point
> 100 °C
Explosive Limits
---
Partition Coefficient
see section 12
Solubility In Fat
---
Melting Point
not applicable
Bulk Density
---
Colour Intensity
---
Form
---
Solubility In Water
---
Odor Threshold
not applicable
Softening Point
---
Solidification Point
---
Vapor Pressure
not applicable
Properties Status
---
Solubility
---
Boiling Point
not applicable
Lower Explosive Limit
not applicable
Appearance
---
Physical State Data
liquid
Voc Content
---
Decomposition Temperature
not applicable
Ph
not applicable
Crystallisation Point
---
Freezing Point
not applicable
Cloud Point
---
Relative Evaporation Rate
---
Relative Density
---
State Under Standard Conditions
---
Kinematic Viscosity
50 s 6 mm (Method: DIN 53211)
Physical State
Liquid
Flammability
---
Density
1,10 g/cm³
Upper Explosive Limit
not applicable
Auto Ignition Temperature
not applicable
Metal Corrosion
---
Evaporation Rate
not applicable
Odor
characteristic
Colour
refer to label
Dynamic Viscosity
---
Molecular Weight
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable when applying the recommended regulations for storage and handling.

Reactivity

No information available.

Hazardous reactions

Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.

Avoid

Heat, strong ultraviolet radiation.

Incompatible

not applicable

Decomposition

Hazardous decomposition byproducts may form with exposure to high temperatures.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Based on available data, the classification criteria are not met. ### Long-term Ecotoxicity Harmful to aquatic life with long lasting effects.

12.2. Persistence and degradability

Toxicological data are not available.

12.3. Bioaccumulative potential

Toxicological data are not available. ### Bioconcentration factor (BCF) Toxicological data are not available.

12.4. Mobility in soil

Toxicological data are not available.

12.5. Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Other adverse effects

No information available.

No information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste disposal according to directive 2008/98/EC, covering waste and dangerous waste.

Disposal

Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way.

Waste Codes

080111* Waste paint and varnish containing organic solvents or other dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
not applicable
Transport Class
not applicable
Packing Group
not applicable
ADR

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IMDG

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

IATA

Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed

An intended Annex Ib describing CSA for mixtures has been removed from the REACH Regulation because of lack of scientific basis.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 884/L 24557 herkula ultraprint spezial ceruse bl known by?

884/L 24557 herkula ultraprint spezial ceruse bl is also known as: ceruse bl.

What is the hazard signal word for 884/L 24557 herkula ultraprint spezial ceruse bl?

The signal word is warning.

What is the physical form of 884/L 24557 herkula ultraprint spezial ceruse bl?

884/L 24557 herkula ultraprint spezial ceruse bl is a liquid with refer to label color. It has characteristic odor.

What is 884/L 24557 herkula ultraprint spezial ceruse bl used for?

colour / ink for use in industrial installations or professional treatment only

What are the hazard statements for 884/L 24557 herkula ultraprint spezial ceruse bl?

This substance has 4 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of 884/L 24557 herkula ultraprint spezial ceruse bl?

The melting point is not applicable and the boiling point is not applicable.