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Safety Data Sheet EN

2-Hydroxyethyl methacrylate

CAS 868-77-9
EC 212-782-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2-Hydroxyethyl methacrylate
Product Code
477028
Chemical Name
丙烯酸酯单体 2-Hydroxyethyl methacrylate
Synonyms
hema,GMA

Regulatory Identifiers

CAS Number
868-77-9 Check regulations →
EC Number
212-782-2 Check regulations →
REACH No.
01-2119490169-29

Identified Uses

Laboratory chemicals, Synthesis of substances

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipient’s responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

global supplier

3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements

P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-hydroxyethyl methacrylate EC: 212-782-2 868-77-9 100% Yes
N/A --- 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Specific hazards

Carbon oxides Combustible.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

No data available

Cleanup methods

No data available

Materials: No data available

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: Chloroprene Minimum layer thickness: 0.65 mm Break through time: 480 min Material tested:KCL 720 Camapren®. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves. Splash contact Material: Latex gloves Minimum layer thickness: 0.6 mm Break through time: 10 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves.

Respiratory

Recommended Filter type: Filter A-(P2). Required when vapours/aerosols are generated. Recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Colour Intensity
---
Explosive Limits
---
Relative Density
No data available
Lower Explosive Limit
No data available
Solubility In Water
100 g/l at 20 °C (68 °F)
Relative Evaporation Rate
---
Decomposition Temperature
No data available
Physical State
liquid
Voc Content
---
Solubility
---
Flash Point
106 °C (223 °F)
Auto Ignition Temperature
375 °C (707 °F)
Bulk Density
---
Ph
No data available
Form
clear, liquid
Appearance
clear, liquid
Properties Status
---
Dynamic Viscosity
---
Upper Explosive Limit
No data available
Vapor Pressure
0.08 hPa at 20 °C (68 °F)
Solidification Point
---
State Under Standard Conditions
---
Melting Point
-12 °C (10 °F)
Solubility In Fat
---
Vapor Density
No data available
Evaporation Rate
No data available
Partition Coefficient
log Pow: 0.42 at 25 °C (77 °F)
Odor
ester-like
Kinematic Viscosity
6.36 mm2/s at 20 °C (68 °F) - 3.42 mm2/s at 40 °C (104 °F)
Flammability
No data available
Odor Threshold
No data available
Metal Corrosion
---
Density
1.073 g/mL at 25 °C (77 °F)
Boiling Point
67 °C 153 °F
Colour
colorless
Cloud Point
---
Physical State Data
liquid
Freezing Point
---
Crystallisation Point
---
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No data available

Reactivity

No data available

Hazardous reactions

Violent reactions possible with: Amines peroxi compounds polymerisation initiators

Avoid

Exposure to moisture. Heat. Light.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 2-Hydroxyethyl methacrylate known by?

2-Hydroxyethyl methacrylate is also known as: hema,GMA

What is the hazard signal word for 2-Hydroxyethyl methacrylate?

The signal word is warning.

What is the physical form of 2-Hydroxyethyl methacrylate?

2-Hydroxyethyl methacrylate is a liquid appearing as clear, liquid with colorless color. It has ester-like odor.

What is 2-Hydroxyethyl methacrylate used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for 2-Hydroxyethyl methacrylate?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.

What is the melting point of 2-Hydroxyethyl methacrylate?

The melting point is -12 °C (10 °F) and the boiling point is 67 °C 153 °F.

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