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Safety Data Sheet EN

ROKAnol® LK3

CAS 68439-50-9
EC Polymer

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ROKAnol® LK3
Chemical Name
Alcohols, C12-14, ethoxylated
Synonyms
Linear (C12 and C14) alkyl alcohols, ethoxylated; Linear C12- and C14-alkyl alcohols, ethoxylated; C12-14 Alcohols ethoxylated; C12-14

Regulatory Identifiers

CAS Number
68439-50-9 Check regulations →
EC Number
Polymer Check regulations →
REACH No.
Exempt from REACH: Polymer.

Identified Uses

Base for detergent formulations.

Uses advised against

Not determined.

Manufacturers & Suppliers

PCC Exol SA logo

PCC Exol SA

Sienkiewicza 4, 56-120 Brzeg Dolny, Poland

+48 71 794 2127

www.pcc-exol.eu

Emergency Contacts

Supplier

+48 71 794 2555

24h/day

Supplier

+48 71 794 2441

24h/day

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice or attention.
P391 Collect spillage.
P501 Dispose of contents/container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Alcohols, C12-14, ethoxylated 68439-50-9 99% Yes

Occupational exposure limits, if available, are listed in Section 8.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: pain or irritation, watering, redness

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediate Medical Attention

Get medical attention. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).

Unsuitable media

Never direct a water jet into the container in order to prevent any splashing of the product, which could cause the fire to spread.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst. This material is very toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. No action shall be taken involving any personal risk or without suitable training.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Put on appropriate personal protective equipment (see Section 8).

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Do not absorb in sawdust or other combustible material.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Contain and collect spillage with non-combustible, absorbent material. Wash spillages into an effluent treatment plant.

Materials: inert dry material; non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Do not store above the following temperature: 40°C (104°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. In case of a long-term direct exposure, : nitrile rubber /nitrile latex > 0,4 mm thick, of minimum time of penetration 480 min should be used. In case of a short-term direct exposure: nitrile rubber / nitrile latex > 0,2 mm thick, of minimum time of penetration 30 min should be used.

Eyes

If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Properties Status
---
Dynamic Viscosity
---
Vapor Pressure
Lack of data.
Cloud Point
---
Explosive Limits
---
Bulk Density
---
Physical State
Liquid. [or Paste.]
Kinematic Viscosity
---
Molecular Weight
---
Freezing Point
5°C (approx.)
Evaporation Rate
---
Voc Content
---
Physical State Data
liquid
Partition Coefficient
Not applicable.
Relative Evaporation Rate
---
Odor Threshold
---
Crystallisation Point
---
Appearance
---
Flash Point
Open cup: >160°C (>320°F)
Odor
Characteristic. [Slight]
State Under Standard Conditions
---
Melting Point
5°C (approx.)
Colour
Lack of data.
Relative Density
Lack of data.
Density
0,93 (approx.) g/cm³ [25°C (77°F)]
Auto Ignition Temperature
Lack of data.
Softening Point
---
Form
---
Decomposition Temperature
Lack of data.
Ph
4,6 to 7,4 [Conc. (% w/w): 1%]
Vapor Density
Lack of data.
Flammability
Lack of data.
Boiling Point
Lack of data.
Lower Explosive Limit
Lack of data.
Upper Explosive Limit
Lack of data.
Colour Intensity
---
Metal Corrosion
---
Solubility
cold water: Very slightly soluble; hot water: Soluble; methanol: Soluble
Solidification Point
---
Solubility In Fat
---
Solubility In Water
0,01 to 0,04 g/l
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

Reacts with strong oxidizers

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid temperature above 40 °C

Incompatible

Strong oxidizing materials

Decomposition

Carbon dioxide. Carbon monoxide.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alcohols, C12-C14, ethoxylated)
Transport Class
9
Packing Group
III
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is ROKAnol® LK3 known by?

ROKAnol® LK3 is also known as: Linear (C12 and C14) alkyl alcohols, ethoxylated; Linear C12- and C14-alkyl alcohols, ethoxylated; C12-14 Alcohols ethoxylated; C12-14

What is the hazard signal word for ROKAnol® LK3?

The signal word is warning.

What is the physical form of ROKAnol® LK3?

ROKAnol® LK3 is a liquid. [or paste.] with lack of data. color. It has characteristic. [slight] odor.

What is the solubility of ROKAnol® LK3?

cold water: Very slightly soluble; hot water: Soluble; methanol: Soluble

What is ROKAnol® LK3 used for?

Base for detergent formulations.

What are the hazard statements for ROKAnol® LK3?

This substance has 2 hazard statements:

  • H319: Causes serious eye irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of ROKAnol® LK3?

The melting point is 5°C (approx.) and the boiling point is Lack of data..

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