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Safety Data Sheet EN

ROKAnol® IT9

CAS 69011-36-5
EC Polymer

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ROKAnol® IT9
Chemical Name
Alcohols, C13, branched, ethoxylated
Synonyms
CAS: 9043-30-5 Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-, branched; Branched tridecylalcohol, ethoxylated; Poly(oxy-1,2-ethanediyl), alpha-tridecyl-omega -hydroxy-, branched; Polyoxyethylene tridecyl (branched) alcohol

Regulatory Identifiers

CAS Number
69011-36-5 Check regulations →
EC Number
Polymer Check regulations →
REACH No.
Exempt from REACH: Polymer.

Identified Uses

Base for detergent formulations. Textile industry Industrial use as intermediate.

Uses advised against

Not determined.

Manufacturers & Suppliers

PCC Exol SA logo

PCC Exol SA

Sienkiewicza 4, 56-120 Brzeg Dolny, Poland

+48 71 794 2127

www.pcc-exol.eu

Emergency Contacts

PCC Exol SA

+48 71 794 2555

24h/day

PCC Exol SA

+48 71 794 2441

24h/day

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H318 Causes serious eye damage.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear eye or face protection.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
P501 Dispose of contents/container to hazardous or special waste collection point.
IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Alcohols, C13, branched, ethoxylated 69011-36-5 99% Yes

Occupational exposure limits, if available, are listed in Section 8.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

Skin contact

Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Adverse symptoms may include the following: pain or irritation redness blistering may occur

Eye contact

Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.

Symptoms: Adverse symptoms may include the following: pain watering redness

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Adverse symptoms may include the following: stomach pains

Immediate Medical Attention

Get medical attention immediately. Call a poison center or physician. Chemical burns must be treated promptly by a physician. If unconscious, place in recovery position and get medical attention immediately. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use alcohol-resistant foam to extinguish.

Unsuitable media

Never direct a water jet into the container in order to prevent any splashing of the product, which could cause the fire to spread.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Do not absorb in sawdust or other combustible material.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Cleanup methods

If water-soluble, dilute with water and mop up. If water-insoluble, absorb with an inert dry material. For large spills, wash into an effluent treatment plant or contain and collect with non-combustible, absorbent material.

Materials: water, inert dry material, non-combustible absorbent material (e.g., sand, earth, vermiculite or diatomaceous earth)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Do not store above the following temperature: 40°C (104°F). Store in accordance with local regulations. Shelf life: 24 months from the date of manufacture. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. In case of a long-term direct exposure: nitrile rubber/nitrile latex > 0.4mm thick, of minimum time of penetration 480 min should be used. In case of a short-term direct exposure: nitrile rubber / nitrile latex > 0.2mm thick, of minimum time of penetration 30 min should be used.

Eyes

If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Cloud Point
---
Solidification Point
---
Ph
5 to 7
Relative Density
Lack of data.
Solubility
cold water: Soluble; hot water: Soluble; methanol: Easily soluble
Explosive Limits
---
Partition Coefficient
Lack of data.
Boiling Point
Lack of data.
Flash Point
>180°C (>356°F)
Physical State Data
liquid
Density
1,01 g/cm³
Form
Liquid
Kinematic Viscosity
Lack of data.
Auto Ignition Temperature
Lack of data.
Flammability
Lack of data.
Vapor Density
Lack of data.
Odor Threshold
---
State Under Standard Conditions
---
Bulk Density
---
Physical State
Liquid.
Decomposition Temperature
>200°C
Upper Explosive Limit
Lack of data.
Freezing Point
10°C
Molecular Weight
---
Appearance
---
Softening Point
---
Solubility In Water
Lack of data.
Colour
Colorless to light yellow.
Solubility In Fat
---
Relative Evaporation Rate
---
Voc Content
---
Properties Status
---
Crystallisation Point
---
Vapor Pressure
Lack of data.
Lower Explosive Limit
Lack of data.
Dynamic Viscosity
Lack of data.
Evaporation Rate
---
Melting Point
10°C
Odor
Characteristic.
Metal Corrosion
---
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Shelf life: 24 months from the date of manufacture.

Reactivity

oxidizing agents

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

Oxidizing agent.

Decomposition

Carbon dioxide. Carbon monoxide.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not regulated.
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is ROKAnol® IT9 known by?

ROKAnol® IT9 is also known as: CAS: 9043-30-5 Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-, branched; Branched tridecylalcohol, ethoxylated; Poly(oxy-1,2-ethanediyl), alpha-tridecyl-omega -hydroxy-, branched; Polyoxyethylene tridecyl (branched) alcohol

What is the hazard signal word for ROKAnol® IT9?

The signal word is danger.

What is the physical form of ROKAnol® IT9?

ROKAnol® IT9 is a liquid. with colorless to light yellow. color. It has characteristic. odor.

What is the solubility of ROKAnol® IT9?

cold water: Soluble; hot water: Soluble; methanol: Easily soluble

What is ROKAnol® IT9 used for?

Base for detergent formulations. Textile industry Industrial use as intermediate.

What are the hazard statements for ROKAnol® IT9?

This substance has 2 hazard statements:

  • H302: Harmful if swallowed.
  • H318: Causes serious eye damage.

What is the melting point of ROKAnol® IT9?

The melting point is 10°C and the boiling point is Lack of data..

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