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Safety Data Sheet EN

ELVANOL® 51-05 polyvinyl alcohol

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ELVANOL® 51-05 polyvinyl alcohol
Product Code
130000021504

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

D

DuPont

manufacturer

1007 Market Street, Wilmington, DE 19898

1-800-441-7515

Emergency Contacts

Medical Emergency

1-800-441-3637

Medical Emergency

1-302-774-1139

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H261 May form explosive dust-air mixture.
H301 Methanol : Toxic if swallowed. Causes damage to the kidneys/ liver/ eyes/ brain/ digestive system/ central nervous system if swallowed. Impairment of vision, Blindness.
H318 Methyl acetate : Corrosive, may cause permanent eye injury if not promptly treated. Severe eye irritation
H319 Methanol : May cause eye irritation. May cause: Tearing, redness, or discomfort.
H335 Processing temperatures that exceed those described in Section 10 (Conditions to Avoid), may evolve fumes irritating the eyes, nose and throat.
H335 Exposure may result in reddening, tears and itching of the eyes and soreness in the nose and throat, together with coughing.
H372 Methyl acetate : Abdominal pain Nausea, Vomiting, Weakness, narcosis.
H373 Adverse effects from repeated exposure may include: Respiratory irritation Central nervous system effects cardiovascular system effects altered blood chemistry Liver effects Kidney effects
H373 Methyl acetate : Central nervous system Respiratory system Cardio-vascular system Blood Mucous membranes Liver Kidney
H373 Methanol : Central nervous system Eyes
Resin particles, like other inert materials, are mechanically irritating to eyes.
Experience shows no unusual dermatitis hazard from routine handling.
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a carcinogen.

Precautionary Statements

Avoid breathing dust or solution spray.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Vinyl alcohol copolymer 25213-24-5 90% No
Process Aids --- 3% No
Methyl acetate 79-20-9 1% No
Methanol 67-56-1 1% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.

Skin contact

Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before reuse.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes.

Ingestion

Call a physician.

Immediate Medical Attention

Call a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2)

Specific hazards

Under severe dusting conditions, this material may form explosive mixtures in air.

Instructions

Wear self-contained breathing apparatus and protective suit. The solid polymer can only be burned with difficulty.

Firefighter Protection

Wear self-contained breathing apparatus and protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not discharge to streams, ponds, lakes or sewers.

Cleanup methods

Shovel or sweep up.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Minimize the generation and accumulation of dust. Can accumulate high static electric charge during handling. Grounding and elimination of the static charge is recommended.

Storage

Keep containers dry and tightly closed to avoid moisture absorption and contamination.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

In the event that the polymer is heated above 200°C (392°F), local ventilation should be used to avoid exposure to fumes. See Bulletin "Proper Use of Local Exhaust Ventilation During Processing of Plastics". Good general ventilation should be provided to keep dust concentrations below the exposure limits.

Eyes

Wear tightly fitting chemical splash goggles and face shield when possibility exists for eye and face contact due to spattering or splashing of molten material.

Respiratory

Where there is potential for airborne exposures in excess of applicable limits, wear NIOSH approved respiratory protection. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or there are any other circumstances where air purifying respirators may not provide adequate protection.

Skin/Body

If there is a potential for contact with hot/molten material wear heat resistant clothing and footwear.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Partition Coefficient
---
Crystallisation Point
---
Auto Ignition Temperature
---
Odor Threshold
---
Upper Explosive Limit
---
Dynamic Viscosity
---
Flammability
---
Physical State
solid
Cloud Point
---
Density
---
Relative Evaporation Rate
---
Bulk Density
---
Vapor Density
---
Appearance
---
Softening Point
---
Ph
---
Relative Density
> 1
Vapor Pressure
---
Physical State Data
solid
Metal Corrosion
---
Melting Point
200 °C (392 °F)
Molecular Weight
---
Explosive Limits
---
Evaporation Rate
---
Freezing Point
---
State Under Standard Conditions
---
Colour
clear or pigmented
Solubility
---
Solidification Point
---
Kinematic Viscosity
---
Boiling Point
---
Colour Intensity
---
Odor
mild
Decomposition Temperature
---
Properties Status
---
Solubility In Water
partly soluble
Voc Content
---
Solubility In Fat
---
Form
dry, free flowing granules, powder
Flash Point
---
Lower Explosive Limit
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal temperatures and storage conditions.

Avoid

Temperature 200 °C (392 °F)

Incompatible

None reasonably foreseeable.

Decomposition

Carbon monoxide, Hydrocarbons, Organic acids, Alcohols, Aldehydes, Disodium oxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ELVANOL® 51-05 polyvinyl alcohol?

The signal word is danger.

What is the physical form of ELVANOL® 51-05 polyvinyl alcohol?

ELVANOL® 51-05 polyvinyl alcohol is a solid with clear or pigmented color. It has mild odor.

What are the hazard statements for ELVANOL® 51-05 polyvinyl alcohol?

This substance has 13 hazard statements:

  • H261: May form explosive dust-air mixture.
  • H301: Methanol : Toxic if swallowed. Causes damage to the kidneys/ liver/ eyes/ brain/ digestive system/ central nervous system if swallowed. Impairment of vision, Blindness.
  • H318: Methyl acetate : Corrosive, may cause permanent eye injury if not promptly treated. Severe eye irritation
  • H319: Methanol : May cause eye irritation. May cause: Tearing, redness, or discomfort.
  • H335: Processing temperatures that exceed those described in Section 10 (Conditions to Avoid), may evolve fumes irritating the eyes, nose and throat.
  • H335: Exposure may result in reddening, tears and itching of the eyes and soreness in the nose and throat, together with coughing.
  • H372: Methyl acetate : Abdominal pain Nausea, Vomiting, Weakness, narcosis.
  • H373: Adverse effects from repeated exposure may include: Respiratory irritation Central nervous system effects cardiovascular system effects altered blood chemistry Liver effects Kidney effects
  • H373: Methyl acetate : Central nervous system Respiratory system Cardio-vascular system Blood Mucous membranes Liver Kidney
  • H373: Methanol : Central nervous system Eyes
  • Resin particles, like other inert materials, are mechanically irritating to eyes.
  • Experience shows no unusual dermatitis hazard from routine handling.
  • None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a carcinogen.

What is the melting point of ELVANOL® 51-05 polyvinyl alcohol?

The melting point is 200 °C (392 °F) .