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Safety Data Sheet EN

Frigutec® SiNO3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Frigutec® SiNO3

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Heat transfer fluid

Uses advised against

No further relevant information available.

Manufacturers & Suppliers

H

HVL GmbH

manufacturer

79410 Badenweiler Germany

+49-7632-823480

Emergency Contacts

Vergiftungs-Informations-Zentrale Freiburg

+49 (0) 761 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.

Precautionary Statements

P260 Do not breathe dusts or mists.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P405 Store locked up.
P406 Store in a corrosion resistant container / container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethanediol EC: 203-473-3 107-21-1 15 - 25% Yes
disodium silicate pentahydrate EC: 229-912-9 10213-79-3 15 - 20% Yes
Sodium nitrate EC: 231-554-3 7631-99-4 10 - 15% Yes
[3-(2,3-epoxypropoxy)propyl]trimethoxysilane EC: 219-784-2 2530-83-8 3 - 5% Yes

For the wording of the listed hazard phrases refer to section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation.

Skin contact

Immediately rinse with water. Call a doctor immediately.

Eye contact

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a doctor immediately.

Ingestion

Rinse out mouth and then drink plenty of water. Do NOT induce vomiting. Call for a doctor immediately.

Immediate Medical Attention

No further relevant information available.

Medical Treatment

No further relevant information available.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire extinguishing methods suitable to surrounding conditions.

Unsuitable media

Water with full jet

Specific hazards

Formation of toxic gases is possible during heating or in case of fire.

Instructions

Cool endangered receptacles with water spray.

Firefighter Protection

Wear self-contained respiratory protective device.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Wear protective clothing.

Environmental

Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water.

Cleanup methods

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralising agent. Dispose of the material collected according to regulations.

Materials: liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.

Storage

Store in cool, dry conditions in well sealed receptacles.

Fire prevention

No special measures required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No further data; see section 7.

Hands

Protective gloves Only use chemical-protective gloves with CE-labelling of category III. DIN EN 374 The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves: - Butyl rubber (0.7 mm) - Nitrile rubber (0.4 mm) The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material ≥ 30 min The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eyes

Tightly sealed goggles

Respiratory

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Skin/Body

Protective work clothing

Environmental

No further relevant information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Decomposition Temperature
Not determined.
Relative Evaporation Rate
---
Density
Not determined.
Colour Intensity
---
Boiling Point
Not determined.
Kinematic Viscosity
Not determined.
Melting Point
Not determined.
Physical State
Liquid
Partition Coefficient
107-21-1 Ethanediol: -1,36 log Pow; 2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane: 0,5 log Pow (20°C, pH 7, QSAR)
Explosive Limits
---
Lower Explosive Limit
Not applicable.
Bulk Density
---
Voc Content
---
Flash Point
111 °C
Vapor Pressure
Not determined.
Solubility In Water
Fully miscible.
Molecular Weight
Not applicable.
State Under Standard Conditions
---
Solubility In Fat
---
Vapor Density
Not determined.
Flammability
Contact with combustible material may cause fire.
Odor
Characteristic
Appearance
---
Softening Point
---
Odor Threshold
Not determined.
Properties Status
---
Metal Corrosion
May be corrosive to metals.
Auto Ignition Temperature
398 °C
Ph
Not determined.
Cloud Point
---
Dynamic Viscosity
Not determined.
Solubility
water: Fully miscible.
Crystallisation Point
---
Solidification Point
---
Upper Explosive Limit
Not applicable.
Relative Density
Not determined.
Form
Liquid
Physical State Data
liquid
Colour
According to product specification
Freezing Point
Not determined.
Evaporation Rate
Not determined.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used and stored according to specifications.

Reactivity

No further relevant information available.

Hazardous reactions

No dangerous reactions known.

Avoid

No further relevant information available.

Incompatible

No further relevant information available.

Decomposition

No dangerous decomposition products known.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1760
Shipping Name
CORROSIVE LIQUID, N.O.S. (DISODIUM TRIOXOSILICATE)
Transport Class
8 Corrosive substances.
Packing Group
II
ADR

Warning: Corrosive substances.

IMDG

Warning: Corrosive substances.

IATA

Warning: Corrosive substances.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Frigutec® SiNO3?

The signal word is danger.

What is the physical form of Frigutec® SiNO3?

Frigutec® SiNO3 is a liquid with according to product specification color. It has characteristic odor.

What is the solubility of Frigutec® SiNO3?

water: Fully miscible.

What is Frigutec® SiNO3 used for?

Heat transfer fluid

What are the hazard statements for Frigutec® SiNO3?

This substance has 4 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.
  • H373: May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.

What is the melting point of Frigutec® SiNO3?

The melting point is Not determined. and the boiling point is Not determined..

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