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Safety Data Sheet EN

LIAL 125 R

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LIAL 125 R
Chemical Name
Alcohols, C12-15-branched and linear

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119490230-48-0000

Identified Uses

raw material for surfactant production

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Alcohols, C12-15-branched and linear EC: 292-334-0 90604-40-3 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove from exposure, lie down. If breathing is irregular or stopped, administer artificial respiration. Monitor breathing, give oxygen if necessary. Consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Consult a physician. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, Dry powder, Foam, Carbon dioxide (CO2)

Unsuitable media

High volume water jet

Specific hazards

Dangerous gases or fumes may occur in case of fire.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

Use personal protective equipment. Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not let product enter drains. Do not flush into surface water. Avoid subsoil penetration. Do not allow material to contaminate ground water system.

Cleanup methods

Soak up with inert absorbent material

Materials: sand, silica gel, acid binder, universal binder, sawdust

—

Related Products

Similar products with comparable safety profiles

L

LIALET 125/5

CAS: 106232-83-1

T

TEROSON RB 1250 CR310ML

---

R

RADIA A125

---

O

OTTOSEAL S 125

---

L

LEYBONOL LVO 120

---

L

LEYBOLD - LEYBONOL LVO 120

---

T

TEROSON RB 1251-03

---

L

LUCONYL®NG YW 1256

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment.

Storage

Protect from frost, heat and sunlight.

Fire prevention

No special protective measures against fire required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide sufficient air exchange and/or exhaust in work rooms.

Hands

Material: Nitrile rubber/nitrile latex Break through time: >= 480 min Glove thickness: 0,35 mm Material: butyl-rubber Break through time: >= 480 min Glove thickness: 0,5 mm The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature). Unsuitable material: Natural rubber/natural latex

Eyes

Tightly fitting safety goggles

Respiratory

No personal respiratory protective equipment normally required. In inadequately ventilated areas, where workplace limits are exceeded, where unpleasant odours exist or where aerosols are in use, or smoke and mist occur, use self-contained breathing apparatus or breathing apparatus with a type A filter or appropriate combined filter (e.g. where aerosols are in use, or smoke and mist occur, A-P2 or ABEK-P2), in compliance with EN 141.

Skin/Body

Wear suitable protective equipment.

Environmental

Do not let product enter drains. Do not flush into surface water. Avoid subsoil penetration. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
---
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
liquid
Odor
characteristic
Odor Threshold
No valid method available.
Ph
Not applicable, Justification:, insoluble
Melting Point
---
Boiling Point
261 - 298 °C; 1.013 hPa; ASTM E 537-07
Flash Point
ca. 135 °C; 1,013 hPa; ASTM D 93
Freezing Point
ca. 6,1 °C; 1,013 hPa; ASTM D 97-08
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
< 0,005 hPa; 20 °C; NF T 20-048 ca. 0,009 hPa; 50 °C; NF T 20-048
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 0,837 g/cm3; 20 °C; 1,013 hPa; ASTM D 4052-96
Flammability
not applicable (liquid)
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
251 °C; 1,013 hPa; ASTM E 659
Decomposition Temperature
Stable under normal conditions.
Solubility
---
Partition Coefficient
log Pow: ca. 5,81; 25 °C; OECD Test Guideline 107
Solubility In Water
< 0,0013 g/l; 20 °C; 1,013 hPa; OECD Test Guideline 105
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
ca. 25,59 mPas; 20 °C; (calculated)
Kinematic Viscosity
ca. 30,57 mm2/s; 20 °C; ASTM D 445 ca. 13,78 mm2/s; 40 °C; ASTM D 445
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal ambient temperature and pressure.

Reactivity

Stable at normal ambient temperature and pressure.

Hazardous reactions

Hazardous decomposition products formed under fire conditions.

Avoid

Direct heating, dirt, chemical contamination, sunlight, UV or ionising radiation.

Decomposition

Hazardous decomposition products formed under fire conditions.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to fish Alcohols, C12-15-branched and linear: LL50 (96 h) Oncorhynchus mykiss (rainbow trout); semi-static test; OECD Test Guideline 203 In the range of water solubility not toxic under test conditions. (literature value) Toxicity to fish - Chronic toxicity Alcohols, C12-15-branched and linear: The study is not necessary. Justification: Data requirements are adequately met by data on the constituents. Toxicity to daphnia and other aquatic invertebrates Alcohols, C12-15-branched and linear: EL50 (48 h) Daphnia magna (Water flea): < 1 mg/l; semi-static test; OECD Test Guideline 202 (literature value) Toxicity to daphnia and other aquatic invertebrates - Chronic toxicity Alcohols, C12-15-branched and linear: The study is not necessary. Data requirements are adequately met by data on the constituents. Alcohols, C12-15-branched and linear: EC10 (21 d) Daphnia magna (Water flea): 0,013 mg/l; reproduction rate; semi-static test; OECD Test Guideline 211 (literature value) The data are derived from the evaluations or test results achieved with similar products (conclusion by analogy). Test substance: dodecan-1-ol Alcohols, C12-15-branched and linear: EC10 (21 d) Daphnia magna (Water flea): 0,0063 mg/l; reproduction rate; semi-static test; OECD Test Guideline 211 (literature value) The data are derived from the evaluations or test results achieved with similar products (conclusion by analogy). Test substance: 1-Tetradecanol Alcohols, C12-15-branched and linear: EC10 (21 d) Daphnia magna (Water flea): 0,012 mg/l; reproduction rate; semi-static test; OECD Test Guideline 211 (literature value) The data are derived from the evaluations or test results achieved with similar products (conclusion by analogy). Test substance: pentadecan-1-ol Toxicity to aquatic plants Alcohols, C12-15-branched and linear: EL50 (72 h) Raphidocelis subcapitata (freshwater green alga): > 0,01 - 0,1 mg/l; Growth rate; semi-static test; OECD Test Guideline 201; (literature value) Alcohols, C12-15-branched and linear: NOEL (72 h) Raphidocelis subcapitata (freshwater green alga): 0,003 mg/l; semi-static test; OECD Test Guideline 201; (literature value) M-Factors Alcohols, C12-15-branched and linear: M-Factor (Acute aquatic toxicity): 10 M-Factor (Chronic aquatic toxicity): 1 1 Toxicity to bacteria Alcohols, C12-15-branched and linear: The substance is not to be considered to be inhibitory to bacteria. Toxicity to soil dwelling organisms Alcohols, C12-15-branched and linear: Substance is a UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Plant toxicity Alcohols, C12-15-branched and linear: Substance is a UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Toxicity to terrestrial organisms Alcohols, C12-15-branched and linear: Studies on birds do not need to be conducted due to large mammalian dataset.

12.2 Persistence and degradability

Biodegradability Alcohols, C12-15-branched and linear: Readily biodegradable.; > 60 %; 30 d; aerobic; OECD Test Guideline 301D (literature value)

12.3 Bioaccumulative potential

### Bioaccumulation Alcohols, C12-15-branched and linear: Bioaccumulation is unlikely.

Bioaccumulation is unlikely for Alcohols, C12-15-branched and linear.

12.4 Mobility in soil

Distribution among environmental compartments Alcohols, C12-15-branched and linear: Adsorption/Soil; Koc: 5098 - 89883; OECD Test Guideline 121 (literature value) The product/preparation has not been tested. The product/preparation has been evaluated based on the single components. immobile strong adsorption to soil

12.5 Results of PBT and vPvB assessment

### Results of PBT assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. ### Results of PBT assessment Alcohols, C12-15-branched and linear: This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB). The substance is considered to be toxic to aquatic life, but is not persistent or bioaccumulating and therefore not classified as PBT.

The substance/mixture contains no components considered to be PBT or vPvB at levels of 0.1% or higher. Alcohols, C12-15-branched and linear are not classified as PBT or vPvB.

12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Additional ecological information Alcohols, C12-15-branched and linear: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

The substance is identified as very toxic to aquatic life with long lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Can be incinerated, when in compliance with local regulations.

Disposal

Can be incinerated, when in compliance with local regulations.

Waste Codes

Not assigned EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1-Dodecanol)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LIAL 125 R?

The signal word is warning.

What is the physical form of LIAL 125 R?

LIAL 125 R is a liquid with colourless color. It has characteristic odor.

What is LIAL 125 R used for?

raw material for surfactant production

What are the hazard statements for LIAL 125 R?

This substance has 1 hazard statement:

  • H410: Very toxic to aquatic life with long lasting effects.