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Safety Data Sheet EN

NEODOL 25

CAS 90604-40-3
EC 292-334-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
NEODOL 25
Product Code
V2451, V2493, V2745

Regulatory Identifiers

CAS Number
90604-40-3 Check regulations →
EC Number
292-334-0 Check regulations →
REACH No.
01-2119490230-48-0002

Identified Uses

Use in detergent manufacture. Please refer to section 16 and/or the annexes for the registered uses under REACH.

Uses advised against

This product must not be used in applications other than the above without first seeking the advice of the supplier.

Manufacturers & Suppliers

S

Shell Chemicals Europe B.V.

manufacturer

PO Box 2334, 3000 CH Rotterdam, Netherlands

+31 (0)10 441 5137 / +31 (0)10 441 5191

Emergency Contacts

Emergency Contact

+44 (0) 1235 239 670

24 hours per day, 7 days per week

Numéro ORFILA (INRS)

+33 (0)1 45 42 59 59

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Alcohols, C12-15-branched and linear EC: 292-334-0 90604-40-3 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice.

Symptoms: Possible respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat, coughing, and/or difficulty breathing.

Skin contact

Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention.

Symptoms: Skin irritation signs and symptoms may include a burning sensation, redness, or swelling.

Eye contact

Flush eye with copious quantities of water. Remove contact lenses, if present and easy to do. Continue rinsing. If persistent irritation occurs, obtain medical attention.

Symptoms: Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision.

Ingestion

In general no treatment is necessary unless large quantities are swallowed, however, get medical advice.

Symptoms: Ingestion may result in nausea, vomiting and/or diarrhoea.

Immediate Medical Attention

Call a doctor or poison control center for guidance.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol-resistant foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable media

Do not use water in a jet.

Specific hazards

Carbon monoxide may be evolved if incomplete combustion occurs. Will float and can be reignited on surface water. The vapour is heavier than air, spreads along the ground and distant ignition is possible.

Instructions

Standard procedure for chemical fires. Clear fire area of all non-emergency personnel. Keep adjacent containers cool by spraying with water.

Firefighter Protection

Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with spilled or released material. Immediately remove all contaminated clothing. Stay upwind and keep out of low areas. Be ready for fire or possible exposure.

Small spill

For small liquid spills (< 1 drum), transfer by mechanical means to a labeled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Large spill

For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Environmental

Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers. Use appropriate containment to avoid environmental contamination.

Cleanup methods

Transfer by mechanical means, allow residues to evaporate or soak up with an appropriate absorbent material.

Materials: appropriate absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing of or direct contact with material. Only use in well ventilated areas. Wash thoroughly after handling. Avoid contact with skin, eyes and clothing. Do not empty into drains. Keep containers closed when not in use. Do not use compressed air for filling discharge or handling.

Storage

Bulk storage tanks should be diked (bunded). Vapours from tanks should not be released to atmosphere. Breathing losses during storage should be controlled by a suitable vapour treatment system. Nitrogen blanket recommended for large tanks (capacity 100 m3 or higher). Insulation (lagging) will minimize heat loss in areas of low ambient temperature. Tanks should be fitted with heating coils in areas where ambient conditions can result in handling temperatures below the freezing point/pour point of the product.

Hygiene

Wash hands before eating, drinking, smoking and using the toilet. Launder contaminated clothing before re-use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Eye washes and showers for emergency use.

Hands

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. When prolonged or frequent repeated contact occurs. Nitrile rubber gloves. Incidental contact/Splash protection: PVC or neoprene rubber gloves. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

Eyes

If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Approved to EU Standard EN166.

Respiratory

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for the combination of organic gases and vapours and particles meeting EN14387 and EN143 [Filter type A/P for use against certain organic gases and vapours with a boiling point >65°C (149°F) and for use against particles].

Skin/Body

Skin protection is not ordinarily required beyond standard work clothes. It is good practice to wear chemical resistant gloves. Protective clothing approved to EU Standard EN14605.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Boiling Point
260 - 290 °C
Dynamic Viscosity
50 mPa.s (22 °C); 12 mPa.s (40 °C)
Kinematic Viscosity
14 mm2/s (40 °C)
Crystallisation Point
---
Metal Corrosion
---
Lower Explosive Limit
Data not available
Auto Ignition Temperature
Data not available
Solubility In Water
ca. 5 mg/l (25 °C)
Flammability
Not applicable
Physical State
Liquid.
Form
---
Colour
Water white
Upper Explosive Limit
Data not available
Solubility In Fat
---
Odor Threshold
Data not available
Physical State Data
liquid
Freezing Point
---
Relative Density
0,834 (25 °C)
Vapor Density
---
Odor
mild
Vapor Pressure
< 0,01 hPa (25 °C)
State Under Standard Conditions
---
Relative Evaporation Rate
---
Melting Point
Data not available
Decomposition Temperature
Data not available
Cloud Point
---
Explosive Limits
---
Colour Intensity
---
Ph
Data not available
Density
0,834 g/cm3 (25 °C); 0,822 g/cm3 (40 °C)
Softening Point
---
Evaporation Rate
Data not available
Molecular Weight
203 - 210 g/mol
Flash Point
149 °C
Bulk Density
---
Partition Coefficient
log Pow: 5,9 - 6,66
Voc Content
---
Properties Status
---
Appearance
---
Solubility
---
Solidification Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable. Stable under normal conditions.

Reactivity

Stable at normal ambient temperature and pressure. May oxidise in the presence of air.

Hazardous reactions

None known.

Avoid

Extremes of temperature and direct sunlight.

Incompatible

Copper, Copper alloys, Strong oxidising agents, Aluminum

Decomposition

None expected under normal use conditions.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations.

Disposal

Dispose in accordance with prevailing regulations, preferably to a recognized collector or contractor. The competence of the collector or contractor should be established beforehand.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (C12-C15 ALCOHOL)
Transport Class
9
Packing Group
III
ADR

Special Precautions: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IMDG

Special Precautions: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IATA

Special Precautions: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed

Labour code: Exposure forbidden to certain works/products to: Young people at least 15 years old and under 18 years old (art. D4153-17); Pregnant or breast-feeding women (art. D4152-10, D4152-11). Social security code - Article L.461-6, Appendix A, no. 601-15. Labour code - Intensified medical supervision: Articles R.4624-18 and R.4624-19, decree 2012-135 of 30.01.2012.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for NEODOL 25?

The signal word is warning.

What is the physical form of NEODOL 25?

NEODOL 25 is a liquid. with water white color. It has mild odor.

What is NEODOL 25 used for?

Use in detergent manufacture. Please refer to section 16 and/or the annexes for the registered uses under REACH.

What are the hazard statements for NEODOL 25?

This substance has 2 hazard statements:

  • H400: Very toxic to aquatic life.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of NEODOL 25?

The melting point is Data not available and the boiling point is 260 - 290 °C.