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Safety Data Sheet EN

Acetophenone

CAS 98-86-2
EC 202-708-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Acetophenone
Product Code
1621
Chemical Name
Acetophenone

Regulatory Identifiers

CAS Number
98-86-2 Check regulations →
EC Number
202-708-7 Check regulations →
REACH No.
01-2119533169-37-0004

Identified Uses

Raw material for industrial use. Raw material for plastics Laboratory chemicals Use as an intermediate Other registered uses: See exposure scenario attached

Uses advised against

No further relevant information available.

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.
H319 Causes serious eye irritation.

Precautionary Statements

P280 Wear eye protection / face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Acetophenone EC: 202-708-7 98-86-2 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air; consult doctor in case of complaints. If breathing has stopped, perform artificial respiration. In case of unconsciousness place patient stably in side position for transportation. Call a doctor immediately.

Symptoms: Irritation of respiratory tract.

Skin contact

Immediately flush affected area with plenty of water. Immediately remove any clothing soiled by the product.

Symptoms: irritation, swelling or redness

Eye contact

Irrigate eyes with copious amounts of water for at least 10-15 min, holding eyelids apart to ensure thorough rinsing. Call a doctor immediately.

Symptoms: irritation, blurred vision or swelling

Ingestion

Administer medicinal carbon. Do not induce vomit. Wash the mouth with clean water. Call a doctor and/or carry immediately to first aid.

Symptoms: Nausea, vomiting.

Immediate Medical Attention

Call a doctor immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, water spray, foam, dry chemicals, carbon dioxide.

Unsuitable media

No information available

Specific hazards

The product, when involved in a fire, burns with a sooty flame and release fumes made up of water, carbon dioxide, carbon monoxide (when starved of oxygen) and other combustion products. The gases / vapors are heavier than air and may flow at ground level.

Instructions

Cool endangered receptacles with spray water.

Firefighter Protection

Wear suitable protective clothing (helmet, protective clothings, goggles, fire resistant gloves, boots) and protect respiratory organs (self contained breathing apparatus).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Avoid contact with the eyes and skin.

Environmental

Do not allow product to reach sewage system or any water course. Stop leak if safe to do so.

Cleanup methods

Send for recovery or disposal in suitable receptacles.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

The usual precautionary measures are to be adhered to when handling chemicals. Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). Prevent formation of aerosols. Do not inhale gases / fumes / aerosols.

Storage

Keep the product in ventilated and fresh storage areas. Do not store in the open under direct sunlight. Store in dry conditions. Keep container tightly sealed.

Hygiene

Comply with personal hygiene measures and use the personal protective equipment (see chapter 8). Do not smoke, eat or drink in the workplace. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin.

Fire prevention

Avoid naked flames. Remove ignition sources. Avoid sparks. Do not smoke. Take precautionary measures against static discharges. Earth all equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Work rooms must be provided with adequate ventilation and exhaust equipment to collect dust and gas/vapours that may be evolved during the conversion. Ensure that washing facilities are available at the work place.

Hands

Protective gloves. The following materials may provide suitable chemical protection: - Butyl rubber (Recommended thickness of the material: ≥ 0.35 mm; Permeation time: > 480 min) - Fluorocarbon rubber (Recommended thickness of the material: ≥ 0.30 mm; Permeation time: > 480 min). The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Not suitable are gloves made of the following materials: - Natural rubber, NR - Nitrile rubber, NBR - PVC gloves - PVA gloves

Eyes

In case of possible or foreseeable exposure to vapours or aerosol (and anyway in case of simultaneous use of respiratory protective equipment), it is preferable to wear a EN 136 certified full face mask for a better eye/face protection.

Respiratory

Wear a EN 136 certified full face mask equipped with a EN 14387 certified gas filter of type A (Colour code: brown) In case filter respirators are not suitable (e.g.: high concentration of particles or aerosol, oxygen concentrations below 17% volume, unknown concentrations of vapours and/or gases or concentrations above the usage limits for filter devices as specified by the manufacturer, presence of other vapours and gases in the air, etc.) use EN 14594 certified continuous flow compressed air line breathing apparatus or EN 14593-1 certified compressed air line breathing apparatus with demand valve or EN 145 certified self-contained closed-circuit breathing apparatus or EN 137 certified self-contained open-circuit compressed air breathing apparatus.

Skin/Body

If release of liquid chemicals is possible or foreseeable, wear a EN 14605 certified protective suit against liquid chemicals with liquid-tight connections. Chemical-resistant boots (conforming EN 20345 & 13832).

Environmental

Take all the technical precautions necessary to prevent the diffusion of the product in the environment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Aromatic
Odor Threshold
---
Ph
Not determined.
Melting Point
20.04 °C
Boiling Point
202.11 °C
Flash Point
105 °C (Closed cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0.45 hPa at 25 °C
Vapor Density
4.15
Relative Density
1.03 g/cm³ at 20 °C
Bulk Density
---
Density
---
Flammability
Based on physical-chemical property this test is not required
Upper Explosive Limit
Not determined.
Lower Explosive Limit
1.1 Vol %
Explosive Limits
---
Auto Ignition Temperature
535 °C
Decomposition Temperature
Not determined.
Solubility
---
Partition Coefficient
1.65 log POW at 20 °C
Solubility In Water
6.2 g/l at 25 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.681 mPas at 25 °C
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable in the normal storage conditions.

Reactivity

The substance / mixture does not present additional hazards related to reactivity compared to those reported in the following subtitles

Hazardous reactions

Reacts with strong oxidising agents.

Avoid

Temperatures above 82°C

Incompatible

Reducing chemical agents. Avoid the contact with oxidising substances. Alkalis

Decomposition

Carbon monoxide and carbon dioxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic toxicity: Based on available data, classification criteria are not met. | EC50/96h | 162 mg/l (Fish - Pimephales promelas) | | --- | --- | | EL50/72h | 86.4 mg/l (Pseudokirchneriella subcapitata) | | EL50/48h | 528 mg/l (Daphnia) | | LC50 /96h | 162 mg/l (Fish - Pimephales promelas) | | NOEL- 48h | 24.8 mg/l (Pseudokirchneriella subcapitata) |

Based on available data, classification criteria are not met.

12.2 Persistence and degradability

Readily biodegradable

The substance is readily biodegradable.

12.3 Bioaccumulative potential

Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected. BCF: 0.47

Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected.

12.4 Mobility in soil

Low potential for absorption Koc: 9-95

12.5 Results of PBT and vPvB assessment

PBT: The substance/mixture doesn't meet the PBT Annex XIII criteria of REACH Regulation vPvB: The substance/mixture doesn't meet the vPvB Annex XIII criteria of REACH Regulation

The substance/mixture does not meet the PBT or vPvB criteria as defined in Annex XIII of the REACH Regulation.

12.6 Endocrine disrupting properties

The substance is not identified as having endocrine disrupting properties.

The substance is not identified as having endocrine disrupting properties.

12.7 Other adverse effects

Not known to be hazardous to water. No further relevant information available.

Not known to be hazardous to water.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Residues should be disposed of as required by national and local regulations.

Disposal

Must not be disposed together with household garbage.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

National implementations of European Community Directives listed below

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Acetophenone?

The signal word is warning.

What is the physical form of Acetophenone?

Acetophenone is a liquid with colourless color. It has aromatic odor.

What is Acetophenone used for?

Raw material for industrial use. Raw material for plastics Laboratory chemicals Use as an intermediate Other registered uses: See exposure scenario attached

What are the hazard statements for Acetophenone?

This substance has 2 hazard statements:

  • H302: Harmful if swallowed.
  • H319: Causes serious eye irritation.

What is the melting point of Acetophenone?

The melting point is 20.04 °C and the boiling point is 202.11 °C.