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Safety Data Sheet EN

Benzene-d₆

CAS 1076-43-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Benzene-d₆
Product Code
151815

Regulatory Identifiers

CAS Number
1076-43-3 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

distributor

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Muta. Cat. 1B H340
Carc. Cat. 1A H350
STOT RE Cat. 1 H372
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H372 Causes damage to organs (Blood) through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P331 Do NOT induce vomiting.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
(2H6)benzene EC: 214-061-8 1076-43-3 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: caution if victim vomits. Keep airways free. Call a physician immediately.

Symptoms: Risk of aspiration! Pulmonary failure possible after aspiration of vomit.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Not combustible, Pay attention to flashback, Vapors are heavier than air and may spread along floors, Forms explosive mixtures with air at ambient temperatures, Ambient fire may liberate hazardous vapours.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Handle and store under inert gas. hygroscopic

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Viton®, Minimum layer thickness: 0,7 mm, Break through time: 480 min, Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,4 mm, Break through time: 10 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter A-(P3). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
No data available
Melting Point
6,8 °C
Boiling Point
79,1 °C
Flash Point
-11 °C
Freezing Point
6,8 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
99,5 hPa at 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,95 g/cm³ at 25 °C
Flammability
---
Upper Explosive Limit
8 % (V)
Lower Explosive Limit
1,3 % (V)
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

Exothermic reaction with: halogens, Halogenated hydrocarbon, in the presence of: Light metals, halogen-halogen compounds, Nitric acid, Boranes, Ozone, peroxi compounds, perchlorates, permanganic acid, perchloryl fluoride, Strong oxidizing agents, Chlorine, fluorides, uranium hexafluoride. Risk of explosion with: Oxygen, liquid. Risk of ignition or formation of inflammable gases or vapours with: chromium(VI) oxide, Fluorine, nitryl compounds, Oxygen, oxyhalogenic compounds. Violent reactions possible with: mineral acids, sulfur.

Avoid

Warming.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1114
Shipping Name
BENZENE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Benzene-d₆?

The signal word is danger.

What is the physical form of Benzene-d₆?

Benzene-d₆ is a liquid with colorless color. It has no data available odor.

What is Benzene-d₆ used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Benzene-d₆?

This substance has 8 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H372: Causes damage to organs (Blood) through prolonged or repeated exposure.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Benzene-d₆?

The melting point is 6,8 °C and the boiling point is 79,1 °C.