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Benzene

DANGER Liquid SDS/MSDS
Chemical Identity

Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Benzene
Product Code
814652

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Feedstock
Uses Advised Against
All others

Overview

Benzene is a colorless substance commonly used feedstock.

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Organize and access your chemical safety data with ease.

Safety Classification

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (DANGER)

Hazard Classifications

Flam. Liq. Category 2 H225
Asp. Tox. Category 1 H304
Skin Irrit. Category 2 H315
Eye Irrit. Category 2 H319
STOT SE Category 3 H336
Muta. Category 1B H340
Carc. Category 1A H350
STOT RE Category 1 H372

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H225: Highly flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H340: May cause genetic defects
  • H350: May cause cancer
  • H372: Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements

  • P202: Do not handle until all safety precautions have been read and understood
  • P243: Take precautionary measures against static discharge
  • P280: Wear protective gloves / protective clothing / eye protection / face protection
  • P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
  • P303+P361+P353: IF ON SKIN: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
  • P331: Do NOT induce vomiting.
Supply Chain

Manufacturers & Suppliers

Authorized suppliers, manufacturers, and distribution network information

Phillips 66 Ltd, Humber Refinery company logo - Safety Data Sheet supplier organization

Phillips 66 Ltd, Humber Refinery

manufacturer

South Killingholme, North Lincolnshire DN40 3DW

GB

+44 (0)1469 571571

Emergency

24/7 Emergency Response

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

Emergency Contact

+44 (0)1469 555348

GB

24 Hours

Composition

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

substance

General Composition

All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
iso-alkaanen, cyclisch (<0,1% benzeen CAS 71-43-2)
EC: 200-753-7
71-43-2 99.9% Hazardous
First Aid

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

Inhalation Exposure

First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. Seek immediate medical attention.

Symptoms:

breathing difficulties

Skin Contact

Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse. First aid is not normally required. However, it is good practice to wash any chemical from the skin.

Symptoms:

irritation or redness

Eye Contact

For direct contact, remove contact lenses if present and easy to do. Immediately hold eyelids apart and flush the affected eye(s) with clean water for at least 20 minutes. Seek immediate medical attention.

Ingestion/Swallowing

Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek medical attention.

Symptoms:

drowsy or unconscious and vomiting

Immediate Medical Attention Required

Seek immediate medical attention for eye contact, breathing difficulties, or ingestion. Seek medical attention if skin surface is damaged or if irritation or redness develops.

Medical Treatment

Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents (e.g., in enclosed spaces or with deliberate abuse). The use of other drugs with less arrhythmogenic potential should be considered. If sympathomimetic drugs are administered, observe for the development of cardiac arrhythmias.

Alternatives

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Section 9

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

Physical State
Liquid
Critical Property
Physical State Data
liquid
State Under Standard Conditions
Not available
Appearance
Colorless
Colour
Colorless
Colour Intensity
Not available
Form
Liquid
Odor
Aromatic
Odor Threshold
N/D
Ph
Not available
Melting Point
5.5 C
Critical Property
Boiling Point
80 C
Critical Property
Flash Point
-11 C; (ASTM D93)
Critical Property
Freezing Point
5.5 C
Softening Point
Not available
Solidification Point
Not available
Cloud Point
Not available
Crystallisation Point
Not available
Relative Evaporation Rate
Not available
Evaporation Rate
N/D
Vapor Pressure
10 kPa @20C
Vapor Density
Not available
Relative Density
0.882-0.885 @ 15C
Bulk Density
Not available
Density
Not available
Flammability
Highly Flammable
Upper Explosive Limit
8.0
Lower Explosive Limit
1.2
Explosive Limits
Not available
Auto Ignition Temperature
550 C
Decomposition Temperature
N/D
Solubility
Solubility in water: Negligible @20C
Partition Coefficient
N/D
Solubility In Water
Negligible @20C
Solubility In Fat
Not available
Molecular Weight
Not available
Voc Content
Not available
Metal Corrosion
Not available
Dynamic Viscosity
Not available
Kinematic Viscosity
Not available
Properties Status
Not available
Section 8

Exposure Controls & Personal Protective Equipment

Occupational exposure limits, engineering controls, and required safety equipment

Engineering Controls

If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required.

Hand Protection

The use of gloves impervious to the specific material handled that comply with EN 374 is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products.

Eye Protection

The use of eye protection (such as splash goggles) that meets or exceeds EN 166 is recommended when there is potential liquid contact to the eye. Depending on conditions of use, a face shield may be necessary.

Respiratory Protection

Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type A, organic gases and vapour filters (as specified by the manufacturer) may be used. A respiratory protection program that follows recommendations for the selection, use, care and maintenance of respiratory protective devices in EN 529:2005 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygen deficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health.

Skin/Body Protection

Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Suggested protective materials: Viton (fluoroelastomers)

Environmental Exposure Controls

Refer to Sections 6, 7, 12 and 13.

Section 14

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

UN Number

UN1114

Proper Shipping Name

BENZENE

Transport Hazard Class

3

Packing Group

II

FAQ

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Benzene?

The signal word for this substance is "danger".

What is the physical form of Benzene?

Benzene is a liquid appearing as colorless with colorless color. It has aromatic odor.

What is the solubility of Benzene?

Solubility in water: Negligible @20C

What is Benzene used for?

Feedstock

What are the hazard statements for Benzene?

This substance has 7 hazard statements: H225: Highly flammable liquid and vapor. H304: May be fatal if swallowed and enters airways H315: Causes skin irritation H319: Causes serious eye irritation H340: May cause genetic defects H350: May cause cancer H372: Causes damage to organs through prolonged or repeated exposure.

What is the melting point of Benzene?

The melting point is 5.5 C and the boiling point is 80 C.