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Safety Data Sheet EN

4-Vinyl-1-cyclohexene, stabilized

CAS 100-40-3
EC 202-848-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4-Vinyl-1-cyclohexene, stabilized
Product Code
140880000; 140880050; 140885000
Chemical Name
4-Vinyl-1-cyclohexene
Synonyms
Butadine dimer; Cyclohexene, 4-ethenyl-; Cyclohexenylethylene

Regulatory Identifiers

CAS Number
100-40-3 Check regulations →
EC Number
202-848-9 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

manufacturer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Number US

001-201-796-7100

Emergency Number Europe

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Asp. Tox. Cat. 1 H304
Skin Irrit. Cat. 2 H315
Carc. Cat. 2 H351
Repr. Cat. 2 H361
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P308 + P313 IF exposed or concerned: Get medical advice/attention
P331 Do NOT induce vomiting

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
4-Vinylcyclohexene EC: 202-848-9 100-40-3 99% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.

Symptoms: Difficulty in breathing, headache, dizziness, tiredness, nausea and vomiting (from inhalation of high vapor concentrations).

Skin contact

Get medical attention. Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician or poison control center immediately. If vomiting occurs naturally, have victim lean forward.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available.

Specific hazards

Flammable. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air.

Instructions

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment. Avoid release to the environment.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Refrigerator/flammables. Keep under nitrogen.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Nitrile rubber, Neoprene, Natural rubber, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
---
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
No data available
Ph
---
Melting Point
-101 °C / -149.8 °F
Boiling Point
126 - 127 °C / 258.8 - 260.6 °F
Flash Point
16 °C / 60.8 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
15 mbar @ 20 °C
Vapor Density
3.76
Relative Density
---
Bulk Density
Not applicable
Density
0.832
Flammability
Highly flammable
Upper Explosive Limit
9.1
Lower Explosive Limit
0.6
Explosive Limits
---
Auto Ignition Temperature
280 °C / 536 °F
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
---
Solubility In Water
0.05 g/L (20°C)
Solubility In Fat
---
Molecular Weight
108.18
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.7 mPa s at 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Excess heat. Incompatible products. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents. Alcohols. Amines.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1993
Shipping Name
Flammable liquid, n.o.s.
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 4-Vinyl-1-cyclohexene, stabilized known by?

4-Vinyl-1-cyclohexene, stabilized is also known as: Butadine dimer; Cyclohexene, 4-ethenyl-; Cyclohexenylethylene

What is the hazard signal word for 4-Vinyl-1-cyclohexene, stabilized?

The signal word is danger.

What is the physical form of 4-Vinyl-1-cyclohexene, stabilized?

4-Vinyl-1-cyclohexene, stabilized is a liquid appearing as clear . It has odorless odor.

What is 4-Vinyl-1-cyclohexene, stabilized used for?

Laboratory chemicals.

What are the hazard statements for 4-Vinyl-1-cyclohexene, stabilized?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H304: May be fatal if swallowed and enters airways
  • H315: Causes skin irritation
  • H351: Suspected of causing cancer
  • H361: Suspected of damaging fertility or the unborn child
  • H412: Harmful to aquatic life with long lasting effects

What is the melting point of 4-Vinyl-1-cyclohexene, stabilized?

The melting point is -101 °C / -149.8 °F and the boiling point is 126 - 127 °C / 258.8 - 260.6 °F.