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Safety Data Sheet EN

DUREZ 34071

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DUREZ 34071
Product Form
Mixture
Product Code
34071
Chemical Name
Phenol, polymer with formaldehyde

Regulatory Identifiers

CAS Number
N/A
UFI Code
KEF0-50GN-F007-Y996

Identified Uses

Industrial use, Industrial, coatings, Intermediates

Uses advised against

No additional information available

Manufacturers & Suppliers

S

Sumitomo Bakelite Europe N.V.

manufacturer

Henry Fordlaan 80, BE– 3600 Genk, België

+32 89 320 300

Emergency Contacts

Emergency Contact

+32 89 320 300

24 hours/day

Centre Anti-Poisons/Antigifcentrum

+32 70 245 245

National Poisons Information Centre

+353 1 809 2566

24/7

National Poisons Information Centre

+353 1 809 2166

8am - 10pm, 7/7

Medicines & Poisons Info Office

+356 2545 6508

National Poisons Information Service (Birmingham Centre)

0344 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer (if inhaled).
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Phenol, polymer with formaldehyde 9003-35-4 76 - 79% No
butan-1-ol; n-butanol EC: 200-751-6 71-36-3 12 - 20% Yes
phenol EC: 203-632-7 108-95-2 3 - 6% Yes
ethanol EC: 200-578-6 64-17-5 1 - 4% Yes
formaldehyde EC: 200-001-8 50-00-0 0.2 - 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

When symptoms occur: go into open air and ventilate suspected area. If experiencing respiratory symptoms: Call a poison center or a doctor. Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.

Symptoms: Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. May cause an allergic skin reaction.

Skin contact

Wash immediately with lots of water (15 minutes)/shower. Soap may be used. Remove clothing while washing. Take victim to a doctor if irritation persists. Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse.

Symptoms: irritation, rash

Eye contact

Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

Symptoms: irritation

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Ingestion of large quantities: immediately to hospital. Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER/doctor if you feel unwell. Immediately call a POISON CENTER/doctor.

Symptoms: Risk of aspiration pneumonia. Swallowing a small quantity of this material will result in serious health hazard.

Immediate Medical Attention

Immediately call a POISON CENTER/doctor.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. ABC powder. Carbon dioxide. Preferably: alcohol resistant foam. AFFF foam. Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable media

No information available. Do not use a heavy water stream.

Specific hazards

DIRECT FIRE HAZARD: Flammable. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD: May be ignited by sparks. Reactions involving a fire hazard: see "Reactivity Hazard". Flammable liquid and vapour. DIRECT EXPLOSION HAZARD: Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD: May be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard". May form flammable/explosive vapour-air mixture.

Instructions

Take account of environmentally hazardous firefighting water. Cool tanks/drums with water spray/remove them into safety. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment.

Firefighter Protection

Heat/fire exposure: compressed air/oxygen apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Local exhaust ventilation should be provided. Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. Evacuate unnecessary personnel.

Large spill

Large spills/in enclosed spaces: compressed air apparatus.

Environmental

Substance must not be discharged into the sewer. Prevent soil and water pollution.

Cleanup methods

This material and its container must be disposed of in a safe way, and as per local legislation. Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite, kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess of water. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

Materials: sand, earth, vermiculite, kieselguhr, powdered limestone, clay, diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle empty containers with care because residual vapours are flammable. Observe normal hygiene standards. Do not eat, drink or smoke when using this product. Use spark-/explosionproof appliances and lighting system. Use earthed equipment. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood.

Storage

Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed.

Hygiene

Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace.

Fire prevention

Use spark-/explosionproof appliances and lighting system. Use earthed equipment. Keep away from naked flames/heat. Keep away from ignition sources/sparks. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Local exhaust ventilation should be provided. The need for local exhaust ventilation should be evaluated by a professional industrial hygienist. Local exhaust ventilation systems should be designed by a professional engineer.

Hands

Ansell Hynit nitrile gloves - safety cuff AE32-800 or equivalent. Chemical resistant PVC gloves (to European standard ISO 374-1 or equivalent)

Eyes

Safety glasses with side shields

Respiratory

On heating: gas mask with filter type A

Skin/Body

Wear suitable protective clothing. Materials for protective clothing: Excellent resistance: Butyl rubber. Viton. Good resistance: Nitrile rubber

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
brown.
Colour Intensity
---
Form
---
Odor
Alcohol odour.
Odor Threshold
Not available
Ph
6 – 9
Melting Point
Not available
Boiling Point
Not available
Flash Point
~ 43 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not available
Vapor Density
---
Relative Density
Not available
Bulk Density
---
Density
Not available
Flammability
Flammable liquid and vapour.
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
Not available
Decomposition Temperature
Not available
Solubility
Soluble in acetone. Soluble in ethanol. Soluble in organic solvents. Insoluble in water.
Partition Coefficient
Not available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
200 – 300 cP
Kinematic Viscosity
1500 - 2000
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Reacts violently with (strong) oxidizers. Violent exothermic reaction with (some) acids. Violent to explosive reaction with (some) halogens.

Hazardous reactions

May form flammable/explosive vapour-air mixture.

Avoid

Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

Incompatible

(strong) oxidizers, (some) acids, (some) halogens

Decomposition

irritating and toxic gases, oxides of carbon, Corrosive vapours

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general: According to literature: no environmental hazard. For more data: see separate components. Ecology - water: Harmful to aquatic life with long lasting effects. Hazardous to the aquatic environment, short–term (acute): Not classified. Hazardous to the aquatic environment, long–term (chronic): Harmful to aquatic life with long lasting effects.

The substance is classified as harmful to aquatic life with long-lasting effects, though it is not classified for acute aquatic toxicity.

12.1. Toxicity

LC50 - Fish [1] 1376 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system, Fresh water, Experimental value, GLP) EC50 - Crustacea [1] 1328 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, GLP) ErC50 algae 225 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP)

12.1. Toxicity

|formaldehyde (50-00-0)|| LC50 - Fish [2]|62 (62 – 109) mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); PURE SUBSTANCE)|

12.1. Toxicity

LC50 - Fish [1] 8,9 mg/l (US EPA, 96 h, Oncorhynchus mykiss, Flow-through system, Fresh water, Experimental value, Lethal) LC50 - Fish [2] 9,1 (9,1 – 12,2) mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 - Crustacea [1] 18 (18 – 36) mg/l (48 h; Daphnia pulex; Static system) EC50 96h - Algae [1] 61 mg/l (US EPA, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, Cell numbers)

12.1. Toxicity

|**ethanol (64-17-5)**|| |LC50 - Fish [1]|15300 mg/l (US EPA, 96 h, Pimephales promelas, Flow-through system, Fresh water,
Experimental value, Lethal)| |EC50 72h - Algae [1]|275 mg/l (Equivalent or similar to OECD 201, Chlorella vulgaris, Static system, Fresh
water, Experimental value, Growth rate)|

12.2. Persistence and degradability

DUREZ 34071 Persistence and degradability: May cause long-term adverse effects in the environment.

May cause long-term adverse effects in the environment.

12.2. Persistence and degradability

butan-1-ol; n-butanol (71-36-3) Persistence and degradability: Readily biodegradable in water. Biochemical oxygen demand (BOD): 1,1 – 1,92 g O₂/g substance Chemical oxygen demand (COD): 2,46 g O₂/g substance ThOD: 2,59 g O₂/g substance

12.2. Persistence and degradability

Biodegradability in soil: no data available. Does not contain any not readily biodegradable component(s).

12.2. Persistence and degradability

Readily biodegradable in water. Photolysis in water. Biodegradable in the soil. Inhibits biodegradation processes in the soil. Biochemical oxygen demand (BOD): 1,7 g O₂/g substance Chemical oxygen demand (COD): 2,3 g O₂/g substance ThOD: 2,4 g O₂/g substance

12.2. Persistence and degradability

Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0,8 – 0,967 g O₂/g substance Chemical oxygen demand (COD) 1,7 g O₂/g substance ThOD 2,1 g O₂/g substance

12.3. Bioaccumulative potential

DUREZ 34071 Bioaccumulative potential: Not established.

Not established.

12.3. Bioaccumulative potential

Partition coefficient n-octanol/water (Log Pow) 1 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

12.3. Bioaccumulative potential

formaldehyde (50-00-0) Bioaccumulative potential: Does not contain bioaccumulative component(s).

Does not contain bioaccumulative component(s).

12.3. Bioaccumulative potential

|**phenol (108-95-2)**|| |BCF - Fish [1]|18 (OECD 305: Bioconcentration: Flow-Through Fish Test, 3 h, Danio rerio, Flow-through
system, Fresh water, Experimental value, Fresh weight)| |Partition coefficient n-octanol/water (Log Pow)|1,5 (Experimental value, Equivalent or similar to OECD 117, 30 °C)| |Bioaccumulative potential|Low potential for bioaccumulation (BCF < 500).|

Low potential for bioaccumulation (BCF < 500).

12.3. Bioaccumulative potential

|**ethanol (64-17-5)**|| |Partition coefficient n-octanol/water (Log Pow)|-0,35 (Experimental value, Equivalent or similar to OECD 107, 24 °C)| |Bioaccumulative potential|Not bioaccumulative.|

Not bioaccumulative.

12.4. Mobility in soil

butan-1-ol; n-butanol (71-36-3) Surface tension: 69,9 mN/m (20 °C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0,54 (log Koc, SRC PCKOCWIN v2.0, Calculated value) Ecology - soil: Highly mobile in soil. May be harmful to plant growth, blooming and fruit formation. formaldehyde (50-00-0) Ecology - soil: Contains component(s) with potential for mobility in the soil. phenol (108-95-2) Surface tension: 71,3 mN/m (20 °C, 0.118 %) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 1,2 – 1,9 (log Koc, Calculated value) ethanol (64-17-5) Surface tension: 22,31 mN/m (20 °C, 100 %) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0,2 (log Koc, Experimental value)

12.5. Results of PBT and vPvB assessment

Component: butan-1-ol; n-butanol (71-36-3) - This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII; This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII. phenol (108-95-2) - This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII; This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII. ethanol (64-17-5) - This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII; This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII.

All listed components (butan-1-ol, phenol, and ethanol) do not meet the PBT or vPvB criteria of REACH regulation, annex XIII.

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

Additional information : Avoid release to the environment.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1866
Shipping Name
RESIN SOLUTION (contains n-butanol)
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DUREZ 34071?

The signal word is danger.

What is the physical form of DUREZ 34071?

DUREZ 34071 is a liquid appearing as liquid. with brown. color. It has alcohol odour. odor.

What is the solubility of DUREZ 34071?

Soluble in acetone. Soluble in ethanol. Soluble in organic solvents. Insoluble in water.

What is DUREZ 34071 used for?

Industrial use, Industrial, coatings, Intermediates

What are the hazard statements for DUREZ 34071?

This substance has 7 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer (if inhaled).
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of DUREZ 34071?

The melting point is Not available and the boiling point is Not available.