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Safety Data Sheet EN

DUREZ 37130

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DUREZ 37130
Product Form
Mixture
Product Code
37130

Regulatory Identifiers

CAS Number
N/A
UFI Code
74P0-N0AM-A00T-JWR7

Identified Uses

Main use category: Industrial use; Industrial/Professional use spec: Industrial; Use of the substance/mixture: Coating; Function or use category: Intermediates

Uses advised against

No additional information available

Manufacturers & Suppliers

S

Sumitomo Bakelite Europe N.V.

manufacturer

Henry Fordlaan 80, BE– 3600 Genk, België

+32 89 320 300

Emergency Contacts

Emergency Contact

+32 89 320 300

Available 24 hours/day

Centre Anti-Poisons/Antigifcentrum

+32 70 245 245

National Poisons Information Centre

+353 1 809 2566

Healthcare professionals-24/7

National Poisons Information Centre

+353 1 809 2166

8am - 10pm, 7/7

Medicines & Poisons Info Office

+356 2545 6508

National Poisons Information Service (Birmingham Centre)

0344 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
STOT SE Cat. 3 H336
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
phenol, polymer with formaldehyde 9003-35-4 57 - 62% Yes
butan-1-ol; n-butanol EC: 200-751-6 71-36-3 21 - 27% Yes
xylene, mixture of isomers EC: 215-535-7 1330-20-7 4 - 9% Yes
phenol EC: 203-632-7 108-95-2 4% Yes
ethanol EC: 200-578-6 64-17-5 2 - 3% Yes
methanol EC: 200-659-6 67-56-1 2 - 3% Yes
formaldehyde EC: 200-001-8 50-00-0 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Call a POISON CENTER/doctor if you feel unwell.

Symptoms: May cause respiratory irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness.

Skin contact

Rinse skin with water/shower. Take off immediately all contaminated clothing. Call a physician immediately. Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse.

Symptoms: Burns. May cause an allergic skin reaction.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Immediately call a POISON CENTER/doctor.

Symptoms: Serious damage to eyes.

Ingestion

Rinse mouth. Do not induce vomiting. Call a physician immediately. Do NOT induce vomiting. Call a POISON CENTER/doctor if you feel unwell. Immediately call a POISON CENTER/doctor.

Symptoms: Burns. Swallowing a small quantity of this material will result in serious health hazard.

Immediate Medical Attention

Call a physician immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Dry powder. Foam. Carbon dioxide. Sand.

Unsuitable media

Do not use a heavy water stream.

Specific hazards

Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.

Instructions

Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire.

Firefighter Protection

Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Evacuate unnecessary personnel. Ventilate area.

Environmental

Avoid release to the environment.

Cleanup methods

Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage.

Materials: absorbent material, inert solids, such as clay or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Take all necessary technical measures to avoid or minimize the release of the product on the workplace. Limit quantities of product at the minimum necessary for handling and limit the number of exposed workers. Provide local exhaust or general room ventilation. Floors, walls and other surfaces in the hazard area must be cleaned regularly. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area.

Storage

Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Keep only in the original container in a cool, well ventilated place away from :

Hygiene

Separate working clothes from town clothes. Launder separately. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Wash hands, forearms and face thoroughly after handling.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Local exhaust ventilation should be provided. The need for local exhaust ventilation should be evaluated by a professional industrial hygienist. Local exhaust ventilation systems should be designed by a professional engineer.

Hands

Ansell Hynit nitrile gloves - safety cuff AE32-800 or equivalent. Chemical resistant PVC gloves (to European standard ISO 374-1 or equivalent)

Eyes

Protective goggles. Face shield. Safety glasses with side shields

Respiratory

On heating: gas mask with filter type A

Skin/Body

Wear suitable protective clothing. Materials for protective clothing: Excellent resistance: Butyl rubber. Viton. Good resistance: Nitrile rubber

Environmental

Avoid release to the environment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
brown.
Colour Intensity
---
Form
---
Odor
alcoholic.
Odor Threshold
Not available
Ph
6 – 9
Melting Point
Not applicable
Boiling Point
Not available
Flash Point
≈ 43 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not available
Vapor Density
---
Relative Density
Not available
Bulk Density
---
Density
Not available
Flammability
Not applicable,Flammable liquid and vapour.
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
Not available
Decomposition Temperature
Not available
Solubility
Soluble in organic solvents. Poorly soluble in water.
Partition Coefficient
Not available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
2000 – 4000 cP
Kinematic Viscosity
Not available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Flammable liquid and vapour.

Hazardous reactions

No dangerous reactions known under normal conditions of use. Not established.

Avoid

Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Sparks.

Incompatible

Strong acids. Strong bases.

Decomposition

Corrosive vapours.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general : Harmful to aquatic life with long lasting effects. Ecology - water : Harmful to aquatic life with long lasting effects. Hazardous to the aquatic environment, short–term : Not classified (acute) Hazardous to the aquatic environment, long–term : Harmful to aquatic life with long lasting effects. (chronic)

12.1. Toxicity

LC50 - Fish [1] 1376 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system, Fresh water, Experimental value, GLP) EC50 - Crustacea [1] 1328 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, GLP) ErC50 algae 225 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP)

12.1. Toxicity

LC50 - Fish [1] 2,6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oncorhynchus mykiss, Static renewal, Fresh water, Read-across, Lethal) ErC50 algae 4,4 mg/l (OECD 201: Alga, Growth Inhibition Test, 73 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP)

12.1. Toxicity

|LC50 - Fish [1]|8,9 mg/l (US EPA, 96 h, Oncorhynchus mykiss, Flow-through system, Fresh water,
Experimental value, Lethal)| |LC50 - Fish [2]|9,1 (9,1 – 12,2) mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss)| |EC50 - Crustacea [1]|18 (18 – 36) mg/l (48 h; Daphnia pulex; Static system)| |EC50 96h - Algae [1]|61 mg/l (US EPA, Pseudokirchneriella subcapitata, Static system, Fresh water,
Experimental value, Cell numbers)|

12.1. Toxicity

LC50 - Fish [1] 15300 mg/l (US EPA, 96 h, Pimephales promelas, Flow-through system, Fresh water, Experimental value, Lethal) EC50 72h - Algae [1] 275 mg/l (Equivalent or similar to OECD 201, Chlorella vulgaris, Static system, Fresh water, Experimental value, Growth rate)

12.1. Toxicity

|LC50 - Fish [1]|15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh
water, Experimental value, Lethal)| |EC50 - Crustacea [1]|18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, Locomotor effect)| |EC50 96h - Algae [1]|22000 mg/l (OECD 201: Alga, Growth Inhibition Test, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, Growth rate)|

12.1. Toxicity

|LC50 - Fish [2]|62 (62 – 109) mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); PURE SUBSTANCE)|

12.2. Persistence and degradability

DUREZ 37130 Persistence and degradability: May cause long-term adverse effects in the environment.

May cause long-term adverse effects in the environment.

12.2. Persistence and degradability

butan-1-ol; n-butanol (71-36-3) Persistence and degradability: Readily biodegradable in water. Biochemical oxygen demand (BOD): 1,1 – 1,92 g O₂/g substance Chemical oxygen demand (COD): 2,46 g O₂/g substance ThOD: 2,59 g O₂/g substance

12.2. Persistence and degradability

xylene, mixture of isomers (1330-20-7) Persistence and degradability: Biodegradable in the soil. Readily biodegradable in water.

The substance is biodegradable in soil and readily biodegradable in water.

Persistence and degradability

Readily biodegradable in water. Photolysis in water. Biodegradable in the soil. Inhibits biodegradation processes in the soil. Biochemical oxygen demand (BOD) 1,7 g O₂/g substance. Chemical oxygen demand (COD) 2,3 g O₂/g substance. ThOD 2,4 g O₂/g substance.

12.2. Persistence and degradability

Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0,8 – 0,967 g O₂/g substance Chemical oxygen demand (COD) 1,7 g O₂/g substance ThOD 2,1 g O₂/g substance

12.2. Persistence and degradability

Readily biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD): 0,6 – 1,12 g O₂/g substance Chemical oxygen demand (COD): 1,42 g O₂/g substance ThOD: 1,5 g O₂/g substance

12.2. Persistence and degradability

Biodegradability in soil: no data available. Does not contain any not readily biodegradable component(s).

12.3. Bioaccumulativepotential

Bioaccumulative potential: Not established.

Not established.

12.3. Bioaccumulativepotential

Partition coefficient n-octanol/water (Log Pow) 1 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 25 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

12.3. Bioaccumulativepotential

xylene, mixture of isomers (1330-20-7) BCF - Fish [1] 7,2 – 26 (56 day(s), Oncorhynchus mykiss, Flow-through system, Fresh water, Read-across) Partition coefficient n-octanol/water (Log Pow) 3,2 (Read-across, 20 °C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Low potential for bioaccumulation (BCF < 500).

12.3. Bioaccumulativepotential

|**phenol (108-95-2)**|| |BCF - Fish [1]|18 (OECD 305: Bioconcentration: Flow-Through Fish Test, 3 h, Danio rerio, Flow-through
system, Fresh water, Experimental value, Fresh weight)| |Partition coefficient n-octanol/water (Log Pow)|1,5 (Experimental value, Equivalent or similar to OECD 117, 30 °C)| |Bioaccumulative potential|Low potential for bioaccumulation (BCF < 500).|

Low potential for bioaccumulation (BCF < 500).

12.3. Bioaccumulativepotential

ethanol (64-17-5) Partition coefficient n-octanol/water (Log Pow) -0,35 (Experimental value, Equivalent or similar to OECD 107, 24 °C) Bioaccumulative potential Not bioaccumulative.

12.3. Bioaccumulativepotential

BCF - Fish [1] 1 – 4,5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value) Partition coefficient n-octanol/water (Log Pow) -0,77 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Low potential for bioaccumulation (BCF < 500).

12.3. Bioaccumulativepotential

Bioaccumulative potential: Does not contain bioaccumulative component(s).

12.4. Mobility in soil

butan-1-ol; n-butanol (71-36-3): Surface tension 69,9 mN/m (20 °C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions), Organic Carbon Normalized Adsorption Coefficient (Log Koc) 0,54 (log Koc, SRC PCKOCWIN v2.0, Calculated value), Ecology - soil Highly mobile in soil. May be harmful to plant growth, blooming and fruit formation. xylene, mixture of isomers (1330-20-7): Surface tension 28,01 – 29,76 mN/m (25 °C), Organic Carbon Normalized Adsorption Coefficient (Log Koc) 2,7 (log Koc, Equivalent or similar to OECD 121, Read-across), Ecology - soil Low potential for adsorption in soil. May be harmful to plant growth, blooming and fruit formation. phenol (108-95-2): Surface tension 71,3 mN/m (20 °C, 0.118 %), Organic Carbon Normalized Adsorption Coefficient (Log Koc) 1,2 – 1,9 (log Koc, Calculated value). ethanol (64-17-5): Surface tension 22,31 mN/m (20 °C, 100 %), Organic Carbon Normalized Adsorption Coefficient (Log Koc) 0,2 (log Koc, Experimental value). methanol (67-56-1): Surface tension No data available in the literature, Organic Carbon Normalized Adsorption Coefficient (Log Koc) -0,89 – -0,21 (log Koc, Calculated value), Ecology - soil Highly mobile in soil. formaldehyde (50-00-0): Ecology - soil Contains component(s) with potential for mobility in the soil.

12.5. Results of PBT and vPvB assessment

butan-1-ol; n-butanol (71-36-3) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII xylene, mixture of isomers (1330-20-7) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII phenol (108-95-2) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII ethanol (64-17-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII methanol (67-56-1) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

All listed components do not meet the PBT or vPvB criteria of REACH regulation, annex XIII.

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

Additional information : Avoid release to the environment.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1866
Shipping Name
RESIN SOLUTION (contains 1-butanol)
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DUREZ 37130?

The signal word is danger.

What is the physical form of DUREZ 37130?

DUREZ 37130 is a liquid with brown. color. It has alcoholic. odor.

What is the solubility of DUREZ 37130?

Soluble in organic solvents. Poorly soluble in water.

What is DUREZ 37130 used for?

Main use category: Industrial use; Industrial/Professional use spec: Industrial; Use of the substance/mixture: Coating; Function or use category: Intermediates

What are the hazard statements for DUREZ 37130?

This substance has 9 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of DUREZ 37130?

The melting point is Not applicable and the boiling point is Not available.