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Safety Data Sheet EN

Manganese(II) chloride tetrahydrate

CAS 13446-34-9
EC 231-869-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Manganese(II) chloride tetrahydrate
Product Code
T881
Chemical Name
Manganese(II) chloride tetrahydrate

Regulatory Identifiers

CAS Number
13446-34-9 Check regulations →
EC Number
231-869-6 Check regulations →
REACH No.
01-2119934899-15-xxxx

Identified Uses

Laboratory chemical Laboratory and analytical use

Uses advised against

Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). Food, drink and animal feedingstuffs.

Manufacturers & Suppliers

Carl Roth GmbH + Co. KG logo

Carl Roth GmbH + Co. KG

manufacturer

Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

Giftzentrale München

+49/(0)89 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H301 Toxic if swallowed
H318 Causes serious eye damage
H373 May cause damage to organs (brain) through prolonged or repeated exposure (if inhaled)

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray
P280 Wear protective gloves/eye protection/face protection
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical advice/attention

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Name of substance Manganese(II) chloride tetrahydrate Molecular formula MnCl₂ · 4H₂O Molar mass 197,9[g] /mol REACH Reg. No 01-2119934899-15-xxxx CAS No 13446-34-9 EC No 231-869-6

Chemical Name CAS Number Concentration Hazardous
Manganese(II) chloride tetrahydrate EC: 231-869-6 13446-34-9 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Skin contact

Rinse skin with water/shower.

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.

Symptoms: Risk of blindness, Risk of serious damage to eyes, Irritation

Ingestion

Rinse mouth immediately and drink plenty of water. Call a physician immediately.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical advice. Consult an ophthalmologist. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings! water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder

Unsuitable media

water jet

Specific hazards

Non-combustible.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Take up mechanically.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid dust formation. Clear contaminated areas thoroughly.

Storage

Store in a dry place. Store locked up.

Hygiene

When using do not eat or drink. Thorough skin-cleansing after handling the product.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: NBR (Nitrile rubber). Material thickness: >0,3 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P3 (filters at least 99,95 % of airborne particles, colour code: White). Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (DGUV-Rule 112/190).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
pink - light red
Colour Intensity
---
Form
crystalline
Odor
odourless
Odor Threshold
---
Ph
4 – 6 (in aqueous solution: 99[g] /l, 25 °C)
Melting Point
58 °C
Boiling Point
not determined
Flash Point
not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not determined
Vapor Density
---
Relative Density
---
Bulk Density
~800[kg] /m³
Density
2,01[g] /cm³ at 20 °C
Flammability
non-combustible
Upper Explosive Limit
not relevant (solid)
Lower Explosive Limit
not relevant (solid)
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
>106 °C
Solubility
---
Partition Coefficient
not relevant (inorganic)
Solubility In Water
1.980[g] /l at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
not relevant
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

This material is not reactive under normal ambient conditions.

Hazardous reactions

Violent reaction with: strong oxidiser, Strong acid, Danger of explosion: Alkali metal, Zinc

Avoid

Keep away from heat. Decompostion takes place from temperatures above: >106 °C.

Incompatible

Light metals, metal

Decomposition

Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3288
Shipping Name
TOXIC SOLID, INORGANIC, N.O.S.
Transport Class
6.1
Packing Group
III
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Manganese(II) chloride tetrahydrate?

The signal word is danger.

What is the physical form of Manganese(II) chloride tetrahydrate?

Manganese(II) chloride tetrahydrate is a solid with pink - light red color. It has odourless odor.

What is Manganese(II) chloride tetrahydrate used for?

Laboratory chemical Laboratory and analytical use

What are the hazard statements for Manganese(II) chloride tetrahydrate?

This substance has 3 hazard statements:

  • H301: Toxic if swallowed
  • H318: Causes serious eye damage
  • H373: May cause damage to organs (brain) through prolonged or repeated exposure (if inhaled)

What is the melting point of Manganese(II) chloride tetrahydrate?

The melting point is 58 °C and the boiling point is not determined.