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Safety Data Sheet EN

Manganese(II) chloride tetrahydrate

CAS 13446-34-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Manganese(II) chloride tetrahydrate
Product Code
63535

Regulatory Identifiers

CAS Number
13446-34-9 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

manufacturer

3050 SPRUCE ST, ST. LOUIS MO 63103, UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373
Aquatic Acute Cat. 3 H402

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H301 Toxic if swallowed.
H318 Causes serious eye damage.
H373 May cause damage to organs (Brain) through prolonged or repeated exposure.
H402 Harmful to aquatic life.

Precautionary Statements

P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Manganese dichloride tetrahydrate EC: 231-869-6 13446-34-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

Immediate Medical Attention

Immediately call in ophthalmologist. Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Hydrogen chloride gas, Manganese/manganese oxides. Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Clean up affected area.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0.11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter type P3. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
flakes
Colour
---
Colour Intensity
---
Form
flakes
Odor
odorless
Odor Threshold
Not applicable
Ph
3.5 - 6 at 50 g/l at 25 °C (77 °F)
Melting Point
58 °C (136 °F)
Boiling Point
1,190 °C 2,174 °F at 1,013 hPa - (anhydrous substance)
Flash Point
does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
No data available
Relative Density
2.5421.5 °C - Regulation (EC) No. 440/2008, Annex, A.3
Bulk Density
---
Density
2.01 g/cm³ at 20 °C (68 °F)
Flammability
The product is not flammable. - Flammability (solids)
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
106 - 198 °C (223 - 388 °F) - Elimination of water of crystallization
Solubility
---
Partition Coefficient
Not applicable for inorganic substances
Solubility In Water
1,980 g/l at 20 °C (68 °F) 757 g/l at 20 °C (68 °F) - Regulation (EC) No. 440/2008, Annex, A.6 - completely soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Alkali metals, Zinc. Violent reactions possible with: acids

Avoid

no information available

Incompatible

Metals, Light metals

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 61 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Manganese sulphate

12.1 Toxicity

(Manganese dichloride tetrahydrate) semi-static test NOEC - Lemna minor (duckweed) - 30.72 mg/l - 7 d Remarks: (ECHA) The value is given in analogy to the following substances: manganese(II) chloride (Manganese dichloride tetrahydrate) Toxicity to bacteria Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Manganese sulphate (Manganese dichloride tetrahydrate)

12.2 Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

The methods for determining the biological degradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Endocrine disrupting properties

No data available

12.7 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3288
Shipping Name
Toxic solid, inorganic, n.o.s. (Manganese dichloride tetrahydrate)
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Manganese(II) chloride tetrahydrate?

The signal word is danger.

What is the physical form of Manganese(II) chloride tetrahydrate?

Manganese(II) chloride tetrahydrate is a solid appearing as flakes . It has odorless odor.

What is Manganese(II) chloride tetrahydrate used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Manganese(II) chloride tetrahydrate?

This substance has 4 hazard statements:

  • H301: Toxic if swallowed.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs (Brain) through prolonged or repeated exposure.
  • H402: Harmful to aquatic life.

What is the melting point of Manganese(II) chloride tetrahydrate?

The melting point is 58 °C (136 °F) and the boiling point is 1,190 °C 2,174 °F at 1,013 hPa - (anhydrous substance).