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Safety Data Sheet EN

Manganese(II) chloride tetrahydrate

CAS 13446-34-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Manganese(II) chloride tetrahydrate
Product Code
203734
Chemical Name
Manganese(II) chloride tetrahydrate

Regulatory Identifiers

CAS Number
13446-34-9 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

Merck Life Science BV logo

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B, B-1560 HOEILAART

+32 (0)3 899-1301

http://www.sigmaaldrich.com

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H301 Toxic if swallowed.
H318 Causes serious eye damage.
H373 May cause damage to organs (Brain) through prolonged or repeated exposure.

Precautionary Statements

P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
P280 Wear eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Manganese dichloride tetrahydrate EC: 231-869-6 13446-34-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Hydrogen chloride gas, Manganese/manganese oxides. Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
flakes
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
No data available
Colour Intensity
---
Form
---
Odor
odourless
Odor Threshold
---
Ph
3,5 - 6 at 50 g/l at 25 °C
Melting Point
Melting point/ range: 58 °C - lit.
Boiling Point
1.190 °C at 1.013 hPa - (anhydrous substance)
Flash Point
does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
2,54 at 21,5 °C - Regulation (EC) No. 440/2008, Annex, A.3
Bulk Density
---
Density
2,01 g/cm3 at 20 °C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
106 - 198 °C Elimination of water of crystallisation
Solubility
---
Partition Coefficient
Not applicable for inorganic substances
Solubility In Water
757 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6- completely soluble1.980 g/l at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Alkali metals, Zinc. Violent reactions possible with: acids

Avoid

no information available

Incompatible

Metals, Light metals

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3288
Shipping Name
TOXIC SOLID, INORGANIC, N.O.S. (Manganese dichloride tetrahydrate)
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Manganese(II) chloride tetrahydrate?

The signal word is danger.

What is the physical form of Manganese(II) chloride tetrahydrate?

Manganese(II) chloride tetrahydrate is a flakes with no data available color. It has odourless odor.

What is Manganese(II) chloride tetrahydrate used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Manganese(II) chloride tetrahydrate?

This substance has 3 hazard statements:

  • H301: Toxic if swallowed.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs (Brain) through prolonged or repeated exposure.

What is the melting point of Manganese(II) chloride tetrahydrate?

The melting point is Melting point/ range: 58 °C - lit. and the boiling point is 1.190 °C at 1.013 hPa - (anhydrous substance).