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Safety Data Sheet EN

Sodium hydroxide monohydrate 99.99 Suprapur®

CAS 12200-64-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sodium hydroxide monohydrate 99.99 Suprapur®
Product Code
1.06466
Chemical Name
Sodium hydroxide monohydrate

Regulatory Identifiers

CAS Number
12200-64-5 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Reagent for analysis, Chemical production

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Index-No. : 011-002-00-6 EC-No. : 215-185-5

Chemical Name CAS Number Concentration Hazardous
Caustic soda monohydrate EC: 215-185-5 12200-64-5 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call in physician / ophthalmologist immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Dispose of properly. Clean up affected area.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.

Storage

Tightly closed. Dry.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material : Nitrile rubber, Break through time : 480 min, Glove thickness : 0,11 mm, Protective index : Full contact, Manufacturer : KCL 741 Dermatril® L; Material : Nitrile rubber, Break through time : 480 min, Glove thickness : 0,11 mm, Protective index : Splash contact, Manufacturer : KCL 741 Dermatril® L; Remarks : This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter B-(P3). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
off-white
Colour Intensity
---
Form
---
Odor
odourless
Odor Threshold
Not applicable
Ph
ca. 14 (20 °C)
Melting Point
No data available
Boiling Point
No data available
Flash Point
No data available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
No data available
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
ca. 1.100 g/l (20 °C); ca. 3.400 g/l (100 °C)
Solubility In Fat
---
Molecular Weight
58,01 g/mol
Voc Content
---
Metal Corrosion
May be corrosive to metals.
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

No data available

Hazardous reactions

Risk of explosion/exothermic reaction with: Acetone, Nitriles, Alkaline earth metals, Cyanides, magnesium, organic nitro compounds, oxidisable substances, acids, phosphides, halogens, halogen-halogen compounds, chlorinated solvents, Ethylene oxide, Hydrazine hydrate, hydroxylamine, anhydrides, Peroxides, Acrolein, Acid chlorides, Sulphuric acid, silver, hydrogen peroxide, Water, Metals, Light metals. Possible formation of: Hydrogen. Violent reactions possible with: organic combustible substances, ammonium compounds, phenols. Generates dangerous gases or fumes in contact with: persulfates, Sodium borohydride, Oxides of phosphorus.

Avoid

no information available

Incompatible

Aluminium, brass, Metals, metal alloys, Zinc, Tin

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Caustic soda monohydrate: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 45,4 mg/l Exposure time: 96 h Remarks: (50% solution) (IUCLID) Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 76 mg/l Exposure time: 24 h Method: DIN 38412 Remarks: (50% solution)

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Components: Caustic soda monohydrate: Assessment : PBT/vPvB: Not applicable for inorganic substances

The product contains no PBT or vPvB components at levels of 0.1% or higher. For the component Caustic soda monohydrate, the assessment is not applicable as it is an inorganic substance.

12.6 Endocrine disrupting properties

**Product:** **Assessment** : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

Components: Caustic soda monohydrate: Additional ecological information : Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1823
Shipping Name
SODIUM HYDROXIDE, SOLID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Sodium hydroxide monohydrate 99.99 Suprapur®?

The signal word is danger.

What is the physical form of Sodium hydroxide monohydrate 99.99 Suprapur®?

Sodium hydroxide monohydrate 99.99 Suprapur® is a solid with off-white color. It has odourless odor.

What is Sodium hydroxide monohydrate 99.99 Suprapur® used for?

Reagent for analysis, Chemical production

What are the hazard statements for Sodium hydroxide monohydrate 99.99 Suprapur®?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Sodium hydroxide monohydrate 99.99 Suprapur®?

The melting point is No data available and the boiling point is No data available.