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Safety Data Sheet EN

Nitric acid

CAS 7697-37-2
EC 231-714-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitric acid
Product Code
A509-P500, A509-P1, A509-P212
Chemical Name
Nitric acid
Synonyms
Azotic acid; Engraver's acid; Aqua fortis

Regulatory Identifiers

CAS Number
7697-37-2 Check regulations →
EC Number
231-714-2 Check regulations →
REACH No.
01-2119487297-23-0081
UFI Code
J71R-86W6-QX0X-MQYF

Identified Uses

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

national supplier

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

national supplier

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Contact

01509 231166

Chemtrec US

(800) 424-9300

Chemtrec EU

001-703-527-3887

National Poisons Information Centre (NPIC)

01 809 2166

8am-10pm, 7 days a week

Malta

+356 2395 2000

Cyprus

+357 2240 5611

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Liq. Cat. 3 H272
Met. Corr. Cat. 1 H290
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H272 May intensify fire; oxidizer
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H331 Toxic if inhaled

Precautionary Statements

P220 Keep away from clothing and other combustible materials
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Nitric acid ...% [C ≤ 70 %] EC: 231-714-2 7697-37-2 65 - 70% Yes
Water EC: 231-791-2 7732-18-5 30 - 35% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove from exposure, lie down. Call a physician immediately.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Call a physician immediately.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Clean mouth with water. Call a physician immediately.

Symptoms: Severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Neoprene gloves (> 480 minutes, 0.45 mm, Level 6, EN374-3); Butyl rubber (> 480 minutes, 0.35 mm, EN 374); Nitrile rubber (< 10 minutes, 0.38 mm).

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143 or Acid gases filter Type E Yellow conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
---
Odor Threshold
No data available
Auto Ignition Temperature
No data available
Solubility
---
Solidification Point
---
Voc Content
---
Cloud Point
---
Vapor Pressure
0.94 kPa (20°C)
Physical State Data
liquid
Relative Evaporation Rate
---
Melting Point
-41 °C / -41.8 °F
Partition Coefficient
-2.3 (Nitric acid ...% [C ≤ 70 %])
Dynamic Viscosity
---
Flammability
No data available
Physical State
Liquid
Properties Status
---
Bulk Density
Not applicable
Kinematic Viscosity
---
Boiling Point
Not applicable
Appearance
Clear Colorless, Light yellow
Vapor Density
No data available
State Under Standard Conditions
---
Density
1.40
Solubility In Fat
---
Metal Corrosion
---
Colour Intensity
---
Crystallisation Point
---
Flash Point
Not applicable
Softening Point
No data available
Upper Explosive Limit
---
Form
---
Odor
Strong Acrid
Relative Density
---
Freezing Point
---
Lower Explosive Limit
---
Ph
< 1.0 (0.1M)
Decomposition Temperature
No data available
Molecular Weight
63.01
Colour
---
Explosive Limits
---
Solubility In Water
Miscible
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2031
Shipping Name
NITRIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Nitric acid known by?

Nitric acid is also known as: Azotic acid; Engraver's acid; Aqua fortis

What is the hazard signal word for Nitric acid?

The signal word is danger.

What is the physical form of Nitric acid?

Nitric acid is a liquid appearing as clear colorless, light yellow . It has strong acrid odor.

What is Nitric acid used for?

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

What are the hazard statements for Nitric acid?

This substance has 4 hazard statements:

  • H272: May intensify fire; oxidizer
  • H290: May be corrosive to metals
  • H314: Causes severe skin burns and eye damage
  • H331: Toxic if inhaled

What is the melting point of Nitric acid?

The melting point is -41 °C / -41.8 °F and the boiling point is Not applicable.