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Safety Data Sheet EN

Nitric Acid 38%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitric Acid 38%
Chemical Name
Nitric Acid

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Use as an intermediate

Uses advised against

Refer to Section 15

Manufacturers & Suppliers

H

Horticentre Ltd

national supplier

10 Firth Street, Drury, 2113

+64 9 294 8453

Emergency Contacts

National Poison Centre

0800 764 766

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
STOT RE Cat. 2 H373
Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P234 Keep only in original container.
P260 Do not breathe fumes, vapours or spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective clothing as detailed in Section 8.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of according to Local Regulations or Authorities

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Nitric Acid 7697-37-2 26 - 65% No
Non-hazardous ingredients --- --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air. Remove contaminated clothing and loosen remaining clothing. Allow person to assume most comfortable position and keep warm. Keep at rest until fully recovered. Get medical advice if breathing becomes difficult.

Symptoms: Irritation of the respiratory tract, dry/sore throat, coughing. Following symptoms may appear later: corrosion of the upper respiratory tract, respiratory difficulties. Possible inflammation of the respiratory tract. Risk of lung oedema. Blue/grey discolouration of the skin.

Skin contact

Seek medical advice. Wash immediately with lots of water (15 minutes)/shower. Remove polluted clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Chemical burns must be treated promptly by a physician. Wash contaminated clothing before reuse. Thoroughly clean shoes before re-using.

Symptoms: Causes serious burns. May cause immediate skin irritation and blistering. Slow-healing wounds. Yellow skin. May stain the skin. Caustic burns/corrosion of the skin. Danger of very serious irreversible effects.

Eye contact

Flush with plenty of water or Diphoterine for 15 min. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Symptoms: Causes serious eye damage. Symptoms may include: pain, lacrimation, redness of the eye tissue. Direct contact with the eyes can cause irreversible damage, including blindness. Risk of serious permanent damages to eyes if the product is not rapidly removed. Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes.

Ingestion

Seek medical advice. Rinse mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.

Symptoms: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Possible esophageal perforation. Symptoms may include: Nausea. Vomiting. Abdominal pain. Shock.

Immediate Medical Attention

Immediately call a POISON CENTER or doctor/physician. Chemical burns must be treated promptly by a physician. Get medical advice if breathing becomes difficult.

Medical Treatment

Treat symptomatically. The exposed person may need to be kept under medical surveillance for 48 hours.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

The product itself does not burn. Use fire extinguishing methods suitable to surrounding conditions.

Unsuitable media

When cooling/extinguishing: no water in the substance.

Specific hazards

Non Flammable, Non-combustible material.

Instructions

Exposure to fire/heat: keep upwind, consider evacuation and have neighbourhood close doors. Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Dilute toxic gases with water spray.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. Evacuate the danger area. Keep unnecessary and unprotected personnel from entering. Keep upwind. Seal off low-lying areas. Close doors and windows of adjacent premises.

Environmental

Prevent soil and water pollution. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

Cleanup methods

Collect as much as possible in a suitable clean container, preferably for re-use, otherwise for disposal. Take up rest of liquid spill into absorbent material. Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess of water.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Read label before use. Do not breathe fumes, vapours or spray. Do not get in eyes, on skin, or on clothing. Do not ingest. Avoid wearing contact lenses. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Keep only in original container. Use only outdoors or in a well-ventilated area. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Avoid splashing. Keep container tightly closed. To dilute the substance must be poured in water. Use corrosion proof equipment. Empty containers retain product residue and can be hazardous. Spillages should be cleaned up promptly to avoid damage to surrounding materials. Remove contaminated clothing and protective equipment before entering eating areas. If on skin, take off contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Wear protective clothing as detailed in Section 8.

Storage

Store locked up. Store in corrosive resistant container with a resistant inner liner. Store on an acid resistant underground. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.

Hygiene

Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Remove contaminated clothing and protective equipment before entering eating areas. If on skin, take off contaminated clothing. Contaminated work clothing should not be allowed out of the workplace.

Fire prevention

Keep substance away from: heat sources. Keep substance away from: heat, ignition and direct sunlight.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Flash Point
Not available
Dynamic Viscosity
---
Colour
Colourless to yellow. On exposure to light: red-brown.
Odor
Irritating/pungent odour. Asphyxiating odour.
Freezing Point
Not available
State Under Standard Conditions
---
Upper Explosive Limit
Not available
Evaporation Rate
---
Vapor Density
---
Flammability
Non flammable
Physical State
Liquid
Colour Intensity
---
Softening Point
---
Appearance
Colourless to yellow. On exposure to light: red-brown.
Molecular Weight
---
Odor Threshold
0.25 - 0.98 ppm 0.75 - 2.5 mg/m³
Solubility In Fat
---
Solubility In Water
Exothermically soluble in water. Soluble in ether. Complete
Decomposition Temperature
>200°C
Voc Content
---
Explosive Limits
---
Relative Density
1.1 - 1.4 (water = 1) Relative density of saturated gas/air mixture : 1
Density
1,24 (38%) - 1,33 (53%) - 1,36 (60%) - 1,38 (65%)
Partition Coefficient
-0.21
Solubility
---
Bulk Density
---
Properties Status
---
Solidification Point
---
Kinematic Viscosity
Not available
Boiling Point
104 - 122 °C; 117°C (53%), 120°C (60%)
Lower Explosive Limit
Not available
Melting Point
-38 - -18 °C
Vapor Pressure
9.4-20 hPa, 55%-70% (@20°C)
Auto Ignition Temperature
Not available
Metal Corrosion
---
Relative Evaporation Rate
---
Cloud Point
---
Ph
<1
Form
---
Physical State Data
liquid
Crystallisation Point
< -20 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable on exposure to light. Stable under recommended storage and treatment circumstances (heading 7). Reactive material.

Reactivity

Reacts violently with many compounds e.g.: with (strong) reducers, with (some) bases, with organic material and with combustible materials. Reacts with (some) metals. Violent to explosive reaction with (some) metal powders: release of highly flammable gases/vapours (hydrogen).

Hazardous reactions

Not combustible but enhances combustion of other substances. Very flammable gas (hydrogen) may be formed on contact with metals. Reacts exothermically with water (moisture). Risk of explosion in confined areas and in contact with incompatible materials.

Avoid

Avoid high temperatures. Avoid ignition sources.

Incompatible

Attacks many metals releasing highly flammable gas (hydrogen) which generates fire or explosion hazards. Reactive or incompatible with the following materials: alkalis, metals. Violent reactions possible with: combustible materials, organic solvents, oxidizable substances, alcohols, ketones, aldehydes, acid anhydrides, amines, anilines, nitriles, organic nitro compounds, hydrazine, acetylidenes, metal alloys, metal oxides, alkali metals, ammonia, acids, halogens, nonmetallic oxides, polypropylene, nitrides, sulfites. carbon steel, hydrogen peroxide and many other substances. Attacks materials such as: some synthetic materials and rubber.

Decomposition

Decomposes on exposure to temperature rise: release of toxic and corrosive gases/vapours (nitrous vapours). Decomposes slowly on exposure to light: release of toxic and corrosive gases/vapours (nitrous vapours). On contact with ordinary metals (steel, galvanized, aluminium) corrosion may occur and generate highly flammable hydrogen gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2031
Shipping Name
NITRIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Nitric Acid 38%?

The signal word is danger.

What is the physical form of Nitric Acid 38%?

Nitric Acid 38% is a liquid appearing as colourless to yellow. on exposure to light: red-brown. with colourless to yellow. on exposure to light: red-brown. color. It has irritating/pungent odour. asphyxiating odour. odor.

What is Nitric Acid 38% used for?

Use as an intermediate

What are the hazard statements for Nitric Acid 38%?

This substance has 5 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H318: Causes serious eye damage.
  • H332: Harmful if inhaled.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of Nitric Acid 38%?

The melting point is -38 - -18 °C and the boiling point is 104 - 122 °C; 117°C (53%), 120°C (60%).