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Safety Data Sheet EN

Nitric acid

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitric acid
Product Code
A202-212; A202-400; A202-500
Synonyms
Azotic acid; Engraver's acid; Aqua fortis

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

Chemtrec US

(800) 424-9300

Chemtrec EU

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Oxidizing liquids Cat. 3
Met. Corr. Cat. 1
Acute Tox. Cat. 1
Skin Corr. Cat. 1A
Eye Dam. Cat. 1

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H272 May intensify fire; oxidizer
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H330 Fatal if inhaled

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P220 Keep/Store away from clothing/ other combustible materials
P221 Take any precaution to avoid mixing with combustibles
P234 Keep only in original container
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear respiratory protection
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P310 Immediately call a POISON CENTER or doctor/physician
P363 Wash contaminated clothing before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam for extinction
P390 Absorb spillage to prevent material damage
P402 Store in a dry place
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P406 Store in corrosive resistant polypropylene container with a resistant inliner
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Nitric acid ...% 7697-37-2 90% No
Water 7732-18-5 10% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically. Possible perforation of stomach or esophagus should be investigated.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

Dry chemical

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. Keep in properly labeled containers.

Hygiene

Do not get in eyes, on skin, or on clothing. Do not ingest.

Fire prevention

Keep away from clothing and other combustible materials. Do not store near combustible materials.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Tight sealing safety goggles. Face protection shield.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Acid gases filter. Type E. Yellow. conforming to EN14387.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear to light yellow
Colour
---
Colour Intensity
---
Form
---
Odor
Strong Acrid
Odor Threshold
No information available
Ph
< 1.0 (0.1M)
Melting Point
-40 °C / -40 °F
Boiling Point
84 °C / 183.2 °F
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
56 hPa
Vapor Density
No information available
Relative Density
1.511
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No information available
Decomposition Temperature
No information available
Solubility
miscible
Partition Coefficient
No data available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
63.02
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.746 mPa.s (25°C)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Oxidizer: Contact with combustible/organic material may cause fire. Hygroscopic.

Reactivity

Reactive Hazard: Yes

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Combustible material. Excess heat. Exposure to air or moisture over prolonged periods. Exposure to moist air or water.

Incompatible

Strong bases, Reducing Agent, Aldehydes, Alcohols, Cyanides, Metals, Finely powdered metals, Ammonia, Organic materials, Strong reducing agents, Combustible material

Decomposition

Nitrogen oxides (NOx), Thermal decomposition can lead to release of irritating gases and vapors

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2032
Shipping Name
NITRIC ACID, RED FUMING SOLUTION
Transport Class
8
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Nitric acid known by?

Nitric acid is also known as: Azotic acid; Engraver's acid; Aqua fortis

What is the hazard signal word for Nitric acid?

The signal word is danger.

What is the physical form of Nitric acid?

Nitric acid is a liquid appearing as clear to light yellow . It has strong acrid odor.

What is the solubility of Nitric acid?

miscible

What is Nitric acid used for?

Laboratory chemicals.

What are the hazard statements for Nitric acid?

This substance has 4 hazard statements:

  • H272: May intensify fire; oxidizer
  • H290: May be corrosive to metals
  • H314: Causes severe skin burns and eye damage
  • H330: Fatal if inhaled

What is the melting point of Nitric acid?

The melting point is -40 °C / -40 °F and the boiling point is 84 °C / 183.2 °F.