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Safety Data Sheet EN

3,3',5,5'-Tetramethylbenzidine

CAS 54827-17-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
3,3',5,5'-Tetramethylbenzidine
Product Code
87748
Chemical Name
3,3',5,5'-Tetramethylbenzidine

Regulatory Identifiers

CAS Number
54827-17-7 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma

manufacturer

M

Merck Life Science BV/SRL

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Carc. Cat. 2 H351
Aquatic Chronic Cat. 4 H413

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H351 Suspected of causing cancer.
H413 May cause long lasting harmful effects to aquatic life.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
3,3',5,5'-tetramethylbenzidine EC: 259-364-6 54827-17-7 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx). Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Store under nitrogen.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: KCL 741 Dermatril® L. Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: KCL 741 Dermatril® L. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
---
Form
---
Solubility In Fat
---
Voc Content
---
Lower Explosive Limit
No data available
Physical State
solid
Cloud Point
---
Solidification Point
---
Melting Point
Melting point/range: 168 - 171 °C Melting point/range: 166 - 171 °C
Odor Threshold
---
Explosive Limits
---
Kinematic Viscosity
No data available
Vapor Density
---
Odor
No data available
Flash Point
Not applicable
Metal Corrosion
---
Upper Explosive Limit
No data available
Boiling Point
168 - 169 °C
Auto Ignition Temperature
No data available
Properties Status
---
Crystallisation Point
---
Solubility In Water
insoluble
Colour
No data available
Bulk Density
---
Colour Intensity
---
Softening Point
---
Dynamic Viscosity
No data available
Density
---
Molecular Weight
---
Relative Evaporation Rate
---
Partition Coefficient
No data available
Decomposition Temperature
No data available
Freezing Point
---
Appearance
---
Relative Density
No data available
Flammability
No data available
Vapor Pressure
No data available
Solubility
---
Physical State Data
solid
Ph
No data available
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents

Avoid

Exposure to moisture. Light.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

Shipping Name
Not dangerous goods
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 3,3',5,5'-Tetramethylbenzidine?

The signal word is warning.

What is the physical form of 3,3',5,5'-Tetramethylbenzidine?

3,3',5,5'-Tetramethylbenzidine is a solid with no data available color. It has no data available odor.

What is 3,3',5,5'-Tetramethylbenzidine used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for 3,3',5,5'-Tetramethylbenzidine?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed.
  • H351: Suspected of causing cancer.
  • H413: May cause long lasting harmful effects to aquatic life.

What is the melting point of 3,3',5,5'-Tetramethylbenzidine?

The melting point is Melting point/range: 168 - 171 °C Melting point/range: 166 - 171 °C and the boiling point is 168 - 169 °C.