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Safety Data Sheet EN

TEROSON PU 8630 HMLC

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TEROSON PU 8630 HMLC
Product Code
779091

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
Carc. Cat. 1A
STOT RE Cat. 1

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H350 MAY CAUSE CANCER.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, clothing, eye and face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
4,4'-Methylenediphenyl diisocyanate, oligomeric reaction products with a-hydro- w-hydroxypoly[oxy(methyl-1,2- ethanediyl)] and polyeth 64298-75-5 30 - 60% No
Carbon black - Nano 1333-86-4 10 - 30% No
Calcitic limestone 1317-65-3 1 - 5% No
Methylenebis(phenylisocyanate) 101-68-8 0.1 - 1% No
Quartz (SiO2) respirable particulates (RCS) >=10% 14808-60-7 0.1 - 1% No

Notes

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. For severe exposures, get under safety shower after removing clothing. Wash clothing before reuse.

Symptoms: This compound is a known skin sensitizer.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Symptoms: Workplace vapors have produced reversible corneal epithelial edema impairing vision.

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

Get medical attention. For severe exposures, get under safety shower after removing clothing, then get medical attention. For lesser exposure, seek medical attention if irritation develops or persists after area is washed.

Medical Treatment

Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Treat symptomatically as for contact dermatitis or thermal burns. Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, dry chemical or carbon dioxide.

Specific hazards

Sealed containers at elevated temperatures or contaminated with water may rupture explosively. Water or fog may cause frothing which can be violent especially if sprayed into containers of hot or burning liquid. During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion. At temperatures above 204.4°C (400°F), polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers. Explosive rupture is possible.

Instructions

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Small spill

For minor spills, absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution: mixture of 80% water and 20% non-ionic surfactant Tergitol TMN-10; or 90% water, 3-8% concentrated ammonia and 2% detergent. Add about ten parts of neutralizer per part of isocyanate, with mixing. Allow to stand uncovered for 48 hours to let carbon dioxide escape.

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up.

Materials: sawdust or other absorbent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Exposure to vapors of heated MDI can be extremely dangerous. Use only with adequate ventilation. Protect from moisture. Keep container closed. Employee education and training in the safe use and handling of this compound are required under the OSHA Hazard Communication Standard.

Storage

Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials.

Hygiene

Wash thoroughly after handling.

Fire prevention

Store away from heat, sparks, flames, or other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Voc Content
0.00 %
Colour
Black
Density
1.2 at 20.00 °C (68°F)
Relative Evaporation Rate
---
Vapor Density
---
Solubility In Water
---
Appearance
---
Dynamic Viscosity
3,500 Pa*s
Relative Density
---
Evaporation Rate
Not applicable
Bulk Density
---
Upper Explosive Limit
Not available.
Flash Point
Not applicable
Kinematic Viscosity
Not available.
Boiling Point
Not applicable, Decomposes > 140°C (284°F).
Colour Intensity
---
Partition Coefficient
Not available.
Auto Ignition Temperature
Not applicable
Freezing Point
---
Vapor Pressure
< 0.1 hPa (20 °C (68°F))
Physical State Data
liquid
Solubility
Insoluble Water
Cloud Point
---
Physical State
Solid
State Under Standard Conditions
---
Crystallisation Point
---
Metal Corrosion
---
Solubility In Fat
---
Odor
Characteristic
Decomposition Temperature
Not available.
Solidification Point
---
Melting Point
Not applicable, Determination technically not possible
Odor Threshold
Not available.
Ph
Product reacts with water., Not applicable
Softening Point
---
Explosive Limits
---
Lower Explosive Limit
Not available.
Properties Status
---
Molecular Weight
---
Form
---
Flammability
The product is not flammable.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

None under normal processing.

Avoid

Keep away from heat, ignition sources and incompatible materials. Contamination with water.

Incompatible

Reacts with alcohols and amines. Reaction with water, formation of CO2 Amines.

Decomposition

Irritating organic vapours. Oxides of carbon. Hydrogen cyanide. MDI vapors and aerosols. Isocyanates.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for TEROSON PU 8630 HMLC?

The signal word is danger.

What is the physical form of TEROSON PU 8630 HMLC?

TEROSON PU 8630 HMLC is a solid with black color. It has characteristic odor.

What is the solubility of TEROSON PU 8630 HMLC?

Insoluble Water

What are the hazard statements for TEROSON PU 8630 HMLC?

This substance has 6 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H350: MAY CAUSE CANCER.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of TEROSON PU 8630 HMLC?

The melting point is Not applicable, Determination technically not possible and the boiling point is Not applicable, Decomposes > 140°C (284°F)..