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Safety Data Sheet EN

TEROSON PU 8594 HMLC

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TEROSON PU 8594 HMLC
Product Code
2156814

Regulatory Identifiers

CAS Number
N/A

Identified Uses

1-component-polyurethane adhesive

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT RE Cat. 1

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P260 Do not breathe dust.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
4,4'-Methylenediphenyl diisocyanate, oligomeric reaction products with a-hydro- w-hydroxypoly[oxy(methyl-1,2- ethanediyl)] and polyeth 64298-75-5 30 - 60% Yes
Carbon black - Nano 1333-86-4 10 - 30% Yes
Oxirane, methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1), polymer with 1,1'-methylenebis[4- isocyanatobenzene] 59675-67-1 1 - 5% Yes
Hexanedioic acid, polymer with 1,6- hexanediol and 1,1'-methylenebis[4- isocyanatobenzene] 31075-20-4 1 - 5% Yes
Methylenebis(phenylisocyanate) 101-68-8 0.1 - 1% Yes

Notes

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. For severe exposures, get under safety shower after removing clothing, then get medical attention. For lesser exposure, seek medical attention if irritation develops or persists after area is washed. Wash clothing before reuse.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Workplace vapors have produced reversible corneal epithelial edema impairing vision.

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Skin: Treat symptomatically as for contact dermatitis or thermal burns. Respiratory: Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, dry chemical or carbon dioxide.

Unsuitable media

Not available.

Specific hazards

Sealed containers at elevated temperatures or contaminated with water may rupture explosively. Water or fog may cause frothing which can be violent especially if sprayed into containers of hot or burning liquid. At temperatures above 204.4°C (400°F), polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers. Explosive rupture is possible.

Instructions

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

isolate the hazard area and deny entry to unnecessary and unprotected personnel

Small spill

absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up.

Materials: sawdust or other absorbent, neutralizing solution

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Exposure to vapors of heated MDI can be extremely dangerous. Use only with adequate ventilation. Protect from moisture. Keep container closed. Employee education and training in the safe use and handling of this compound are required under the OSHA Hazard Communication Standard.

Storage

Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store away from heat, sparks, flames, or other sources of ignition. Do not let moisture contaminate this material.

Hygiene

Wash thoroughly after handling.

Fire prevention

Store away from heat, sparks, flames, or other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Paste
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
Black
Colour Intensity
---
Form
---
Odor
Characteristic
Odor Threshold
Not available.
Ph
Not applicable, Product reacts with water.
Melting Point
Not applicable, Determination technically not possible
Boiling Point
Not applicable, Decomposes > 140°C (284°F).
Flash Point
> 130 °C (> 266°F) ASTM D3278 Setaflash Closed Cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0.1 hPa (20 °C (68°F))
Vapor Density
---
Relative Density
1.24
Bulk Density
---
Density
---
Flammability
The product is not flammable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Insoluble Water
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
0.3 % (calculated)
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

Contact with moisture, other materials which can react with isocyanates, or temperatures above 204.4°C (400°F), may cause polymerization.

Avoid

Keep away from heat, ignition sources and incompatible materials. Contamination with water.

Incompatible

Water. Alcohols. Amines. Ammonia. Strong acids and strong bases.

Decomposition

Irritating organic vapours. Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. MDI vapors and aerosols. Isocyanates.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for TEROSON PU 8594 HMLC?

The signal word is danger.

What is the physical form of TEROSON PU 8594 HMLC?

TEROSON PU 8594 HMLC is a paste with black color. It has characteristic odor.

What is the solubility of TEROSON PU 8594 HMLC?

Insoluble Water

What is TEROSON PU 8594 HMLC used for?

1-component-polyurethane adhesive

What are the hazard statements for TEROSON PU 8594 HMLC?

This substance has 5 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of TEROSON PU 8594 HMLC?

The melting point is Not applicable, Determination technically not possible and the boiling point is Not applicable, Decomposes > 140°C (284°F)..