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Safety Data Sheet EN

Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur
Product Code
100317

Regulatory Identifiers

CAS Number
N/A
REACH No.
see section 3

Identified Uses

Reagent for analysis, Chemical production. In compliance with the conditions described in the annex to this safety data sheet.

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Aqueous solution

Chemical Name CAS Number Concentration Hazardous
Hydrochloric Acid --- 25 - 50% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Call in physician.

Symptoms: Cough, Shortness of breath

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Symptoms: Irritation and corrosion

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Symptoms: Risk of blindness!

Ingestion

make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call a physician immediately in all cases of inhalation, skin contact, eye contact, or ingestion.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. splash contact: Glove material: natural latex, Glove thickness: 0,6 mm, Break through time: >120 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 706 Lapren® (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: filter E-(P2). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
liquid
Odor
stinging
Odor Threshold
0,8 - 5 ppm Gaseous hydrogen chloride (HCl).
Ph
< 1 at 20 °C
Melting Point
---
Boiling Point
No information available.
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
-30 °C
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available.
Vapor Pressure
190 hPa at 20 °C
Vapor Density
---
Relative Density
No information available.
Bulk Density
---
Density
ca.1,19 g/cm3 at 20 °C
Flammability
---
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
No information available.
Decomposition Temperature
No information available.
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
at 20 °C soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
May be corrosive to metals.
Dynamic Viscosity
2,3 mPa.s at 15 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Corrosive in contact with metals

Hazardous reactions

Exothermic reaction with: Amines, potassium permanganate, salts of oxyhalogenic acids, semimetallic oxides, semimetallic hydrogen compounds, Aldehydes, vinylmethyl ether. Risk of ignition or formation of inflammable gases or vapours with: carbides, lithium silicide, Fluorine. Generates dangerous gases or fumes in contact with: Aluminium, hydrides, formaldehyde, Metals, strong alkalis, Sulphides. Risk of explosion with: Alkali metals, conc. sulfuric acid.

Avoid

Heating.

Incompatible

Metals, metal alloys

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1789
Shipping Name
HYDROCHLORIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The signal word is danger.

What is the physical form of Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colourless color. It has stinging odor.

What is Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?

Reagent for analysis, Chemical production. In compliance with the conditions described in the annex to this safety data sheet.

What are the hazard statements for Hydrochloric acid fuming 37% for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.