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Safety Data Sheet EN

Toluene

CAS 108-88-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Toluene
Product Code
T290-1; T290-1LC; T290-4; T290RS-19; T290RS-28; T290RS-200; T290N2-19; T290SK-1; T290SK-4; T290SS-28; T290SS-50; T290SS-115; T290SS-200; NC0112455; NC1089193; T290RS1350; T290RS50
Chemical Name
Toluene
Synonyms
Tol; Methylbenzene

Regulatory Identifiers

CAS Number
108-88-3 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC®

800-424-9300

CHEMTREC®

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
Repr. Cat. 2
STOT SE Cat. 3
STOT RE Cat. 2
Asp. Tox. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
H361d Suspected of damaging the unborn child
H372 May cause damage to organs through prolonged or repeated exposure

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 Keep container tightly closed
P235 Keep cool
P240 Ground and bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use non-sparking tools
P243 Take action to prevent static discharges
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear eye/face protection
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical attention/advice
P331 Do NOT induce vomiting
P332 + P313 If skin irritation occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P362 + P364 Take off contaminated clothing and wash before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Toluene 108-88-3 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: Risk of serious damage to the lungs (by aspiration). Difficulty in breathing.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician or poison control center immediately. If vomiting occurs naturally, have victim lean forward.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Materials: inert absorbent material, suitable, closed containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area. Keep away from heat, sparks and flame.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
aromatic
Odor Threshold
1.74 ppm
Ph
No information available
Melting Point
-95 °C / -139 °F
Boiling Point
111 °C / 231.8 °F @ 760 mmHg
Flash Point
4 °C / 39.2 °F Method - No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
2.4 (Butyl acetate = 1.0)
Vapor Pressure
29 mbar @ 20 °C
Vapor Density
3.1 (Air = 1.0)
Relative Density
0.866
Bulk Density
Not applicable
Density
---
Flammability
Highly flammable
Upper Explosive Limit
7 vol%
Lower Explosive Limit
1.2 vol%
Explosive Limits
---
Auto Ignition Temperature
535 °C / 995 °F
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
2.73 (Toluene)
Solubility In Water
practically insoluble 0.5 g/L @ 20°C
Solubility In Fat
---
Molecular Weight
92.14
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.6 mPa.s @ 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids, Strong bases, Halogenated compounds

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1294
Shipping Name
TOLUENE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Toluene known by?

Toluene is also known as: Tol; Methylbenzene

What is the hazard signal word for Toluene?

The signal word is danger.

What is the physical form of Toluene?

Toluene is a liquid appearing as colorless with colorless color. It has aromatic odor.

What is Toluene used for?

Laboratory chemicals.

What are the hazard statements for Toluene?

This substance has 7 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H304: May be fatal if swallowed and enters airways
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H336: May cause drowsiness or dizziness
  • H361d: Suspected of damaging the unborn child
  • H372: May cause damage to organs through prolonged or repeated exposure

What is the melting point of Toluene?

The melting point is -95 °C / -139 °F and the boiling point is 111 °C / 231.8 °F @ 760 mmHg.