NextSDS Logo
Safety Data Sheet EN

Toluene

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report.

Get Free Audit
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Toluene
Chemical Name
Toluene
Synonyms
Toloul, Methylbenzene

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Solvent

Manufacturers & Suppliers

H

Honeywell

manufacturer

1953 South Harvey Street, Muskegon, MI 49442

1-800-932-5000

V

VWR International

distributor

1310 Goshen Parkway, West Chester, PA 19380

Emergency Contacts

Emergency Contact

1-800-424-9300

CHEMTREC

1-800-424-9300

CANUTEC

1-613-996-6666

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H220 Vapours may form explosive mixtures with air.
H302 Ingestion causes gastrointestinal disturbances.
H304 Harmful: may cause lung damage if swallowed.
H312 May be harmful if absorbed through skin.
H315 The product causes irritation of eyes, skin and mucous membranes.
H315 Irritating to skin.
H319 Vapours irritate the eyes.
H319 Contact with liquid or mist will irritate the eyes.
H336 Causes headache, drowsiness or other effects to the central nervous system.
H336 Vapours may cause drowsiness and dizziness.
H336 Inhalation of high vapour concentrations can cause CNS-depression and narcosis.
H370 Severe exposure may cause respiratory depression, unconsciousness, convulsions and death.
H371 May cause damage to the cornea.
H372 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
This product is a clear, volatile, flammable liquid.
Highly flammable.

Precautionary Statements

Do not allow product to contact skin, eyes and clothing.
Do not breathe vapours.

Get a free compliance audit

Upload your SDS inventory and get a detailed compliance report

Free Audit
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

INGREDIENT NAME Toluene CAS NUMBER WEIGHT % 108-88-3 100

Chemical Name CAS Number Concentration Hazardous
Toluene 108-88-3 100% Yes

This product is considered to be hazardous according to the criteria specified in 29 CFR 1910.1200 (Hazard Communication Standard) and the Canadian Controlled Product Regulations.

Notes

Trace impurities and additional material names not listed above may also appear in Section 15 toward the end of the MSDS. These materials may be listed for local "Right-To-Know" compliance and for other reasons.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air in case of accidental inhalation of vapours. If not breathing, give artificial respiration. If breathing is difficult, give oxygen, provided a qualified operator is available.

Skin contact

Wash off immediately with soap and plenty of water. Take off contaminated clothing and shoes immediately. Wash contaminated clothing before re-use.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

DO NOT induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.

Immediate Medical Attention

Obtain medical attention. Call a physician immediately. Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use alcohol-resistant foam, carbon dioxide (CO2) or dry chemical.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards

Highly flammable. Vapours may form explosive mixtures with air. Vapours are heavier than air and may travel along the ground to some distant source of ignition and flash back. Fire or intense heat may cause violent rupture of packages.

Instructions

In the event of fire, cool tanks with water spray. After fire, flush area with water to prevent re-ignition.

Firefighter Protection

Fire-fighters should wear self-contained, NIOSH-approved breathing apparatus and full protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unnecessary people away. Isolate area. Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Stop flow of material, if this is without risk.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Shovel into suitable container for disposal.

Materials: sand, silica gel, acid binder, universal binder, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Always wear recommended personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapours. Keep away from fire, sparks and heated surfaces.

Storage

Keep in a well-ventilated place. Keep container tightly closed in a dry and well-ventilated place. Store in area designed for storage of flammable liquids. Outside or detached storage is preferable. Protect containers against physical damage.

Hygiene

Always wear recommended personal protective equipment.

Fire prevention

Keep away from fire, sparks and heated surfaces. Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapours or mists generated from the handling of this product. Use product only in closed system. Prevent electrostatic charge build-up by using common bonding and grounding techniques.

Hands

Wear impervious gloves

Eyes

For handling in closed ventilation system, wear safety glasses with side-shields. For leak, spill or other emergency, use chemical goggles and face-shield.

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. For routine operations, wear self-contained breathing apparatus.

Skin/Body

flame retardant antistatic protective clothing. For leak, spills, or other emergency, use full protective equipment.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear, colorless liquid
Colour
---
Colour Intensity
---
Form
---
Odor
Sweet, pungent
Odor Threshold
---
Ph
Not applicable
Melting Point
-125°F (-95°C)
Boiling Point
231.08°F (110.6°C) @ 760 mm Hg
Flash Point
39.2°F (4°C)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
4.5 (Compared to Ether)
Evaporation Rate
4.5
Vapor Pressure
28.5 @ 68°F (20°C)
Vapor Density
3.1
Relative Density
0.867@ 68°F (20°C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
0.074% @ 68°F (20°C)
Solubility In Fat
---
Molecular Weight
92.14
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Hazardous reactions

Hazardous polymerisation does not occur.

Avoid

Heat, flames and sparks. Incompatible products

Incompatible

oxidising agents, strongly alkaline and strongly acid materials

Decomposition

carbon monoxide and carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1294
Shipping Name
Toluene
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Toluene known by?

Toluene is also known as: Toloul, Methylbenzene

What is the hazard signal word for Toluene?

The signal word is danger.

What is the physical form of Toluene?

Toluene is a liquid appearing as clear, colorless liquid . It has sweet, pungent odor.

What is Toluene used for?

Solvent

What are the hazard statements for Toluene?

This substance has 16 hazard statements:

  • H220: Vapours may form explosive mixtures with air.
  • H302: Ingestion causes gastrointestinal disturbances.
  • H304: Harmful: may cause lung damage if swallowed.
  • H312: May be harmful if absorbed through skin.
  • H315: The product causes irritation of eyes, skin and mucous membranes.
  • H315: Irritating to skin.
  • H319: Vapours irritate the eyes.
  • H319: Contact with liquid or mist will irritate the eyes.
  • H336: Causes headache, drowsiness or other effects to the central nervous system.
  • H336: Vapours may cause drowsiness and dizziness.
  • H336: Inhalation of high vapour concentrations can cause CNS-depression and narcosis.
  • H370: Severe exposure may cause respiratory depression, unconsciousness, convulsions and death.
  • H371: May cause damage to the cornea.
  • H372: Harmful: danger of serious damage to health by prolonged exposure through inhalation.
  • This product is a clear, volatile, flammable liquid.
  • Highly flammable.

What is the melting point of Toluene?

The melting point is -125°F (-95°C) and the boiling point is 231.08°F (110.6°C) @ 760 mm Hg.