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Toluene

DANGER Liquid SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Toluene
Product Code
T1402, Q9138, Q9131, Q9250, Q9300, Q9308, X211H

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Solvent. Raw material for use in the chemical industry. Please refer to Ch16 and/or the annexes for the registered uses under REACH.

Overview

Toluene is a colourless. liquid. substance commonly used solvent. raw material for use in the chemical industry. please refer to ch16 and/or the annexes for the registered uses under reach..

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Organize and access your chemical safety data with ease.

GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 2 H225
Skin Irr. Category 2 H315
Repr. Category 2 H361d
STOT SE Category 3 H336
STOT RE Category 2 H373
Asp. Tox. Category 1 H304

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H225: Highly flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H304: May be fatal if swallowed and enters airways.
  • H361: Suspected of damaging fertility or the unborn child.
  • H336: May cause drowsiness or dizziness.
  • H373: May cause damage to organs or organ systems through prolonged or repeated exposure.

Precautionary Statements

  • P202: Do not handle until all safety precautions have been read and understood.
  • P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
  • P243: Take precautionary measures against static discharge.
  • P260: Do not breathe dust/fume/gas/mist/vapours/spray.
  • P280: Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
  • P331: Do NOT induce vomiting.
  • P303+P361+P353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
  • P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
  • P308+P313: IF exposed or concerned: Get medical advice/attention.
  • P403+P235: Store in a well-ventilated place. Keep cool.
  • P405: Store locked up.
  • P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Shell Trading International Limited

manufacturer

๐Ÿ“

80 Strand London, WC2R 0ZA United Kingdom

๐ŸŒ

GB

๐Ÿ“ž

+44 (0) 20 7546 2364

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

Emergency Contact

๐Ÿ“ž

+44 (0)151 350 4595

๐ŸŒ

GB

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Product Type

substance

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Toluene
EC: 203-625-9
108-88-3 100% โš ๏ธ Hazardous

Additional Information

Refer to chapter 16 for full text of EC R-phrases.

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

๐Ÿซ Inhalation Exposure

DO NOT DELAY. Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.

Symptoms:

If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory symptoms may be delayed for several hours after exposure. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting in dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Auditory system effects may include temporary hearing loss and/or ringing in the ears. Visual system disturbances may be evidenced by decreases in the ability to discriminate between colours.

๐Ÿ–๏ธ Skin Contact

Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.

Symptoms:

Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters.

๐Ÿ‘๏ธ Eye Contact

Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the nearest medical facility for additional treatment.

Symptoms:

Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision.

๐Ÿฝ๏ธ Ingestion/Swallowing

If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101 F (38.3 C), shortness of breath, chest congestion or continued coughing or wheezing. Give nothing by mouth.

Symptoms:

If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101 F (38.3 C), shortness of breath, chest congestion or continued coughing or wheezing.

๐Ÿšจ Immediate Medical Attention Required

Potential for chemical pneumonitis. Potential for cardiac sensitisation, particularly in abuse situations. Hypoxia or negative inotropes may enhance these effects. Consider: oxygen therapy. Call a doctor or poison control center for guidance.

Medical Treatment

Potential for chemical pneumonitis. Potential for cardiac sensitisation, particularly in abuse situations. Hypoxia or negative inotropes may enhance these effects. Consider: oxygen therapy. Call a doctor or poison control center for guidance.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

๐Ÿงช Physical State
Liquid
Critical Property
๐Ÿ“Š Physical State Data
liquid
๐Ÿ“Š State Under Standard Conditions
Not available
๐Ÿ‘๏ธ Appearance
Colourless. Liquid.
๐ŸŽจ Colour
Colourless
๐Ÿ“Š Colour Intensity
Not available
๐Ÿ“Š Form
Liquid
๐Ÿ‘ƒ Odor
Aromatic.
๐Ÿ“Š Odor Threshold
1.74 ppm
๐Ÿงช Ph
Not applicable
๐ŸงŠ Melting Point
Typical -95 C / -139 F
Critical Property
๐Ÿ’จ Boiling Point
Typical 110 - 111 C / 230 - 232 F
Critical Property
๐Ÿ”ฅ Flash Point
4 C / 39 F (Abel)
Critical Property
๐Ÿ“Š Freezing Point
Typical -95 C / -139 F
๐Ÿ“Š Softening Point
Not available
๐Ÿ“Š Solidification Point
Not available
๐Ÿ“Š Cloud Point
Not available
๐Ÿ“Š Crystallisation Point
Not available
๐Ÿ“Š Relative Evaporation Rate
Not available
๐Ÿ’จ Evaporation Rate
6.1 (DIN 53170, di-ethyl ether=1) 2 (ASTM D 3539, nBuAc=1)
๐Ÿ’จ Vapor Pressure
Typical 1 kPa at 0 C / 32 F Typical 3 - 3.5 kPa at 20 C / 68 F Typical 12 kPa at 50 C / 122 F
๐Ÿ“Š Vapor Density
3.1
๐Ÿ“Š Relative Density
Data not available.
๐Ÿ“Š Bulk Density
Not available
โš–๏ธ Density
Typical 871 kg/m3 at 15 C / 59 F
Critical Property
๐Ÿ”ฅ Flammability
Yes, in certain circumstances product can ignite due to static electricity.
๐Ÿ“Š Upper Explosive Limit
7.1 %(V)
๐Ÿ“Š Lower Explosive Limit
1.2 %(V)
๐Ÿ“Š Explosive Limits
Not available
๐Ÿ“Š Auto Ignition Temperature
480 - 536 C / 896 - 997 F (ASTM E-659)
๐Ÿ“Š Decomposition Temperature
Data not available.
๐Ÿ’ง Solubility
Not available
๐Ÿ“Š Partition Coefficient
2.65
๐Ÿ“Š Solubility In Water
0.515 kg/m3
๐Ÿ“Š Solubility In Fat
Not available
๐Ÿ“Š Molecular Weight
92 g/mol
๐Ÿ“Š Voc Content
100 %
๐Ÿ“Š Metal Corrosion
Not available
๐Ÿ“Š Dynamic Viscosity
Data not available.
๐Ÿ“Š Kinematic Viscosity
0.63 mm2/s at 25 C / 77 F
๐Ÿ“Š Properties Status
Not available

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

๐Ÿญ Engineering Controls

Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended.

๐Ÿงค Hand Protection

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739, AS/NZS:2161) made from the following materials may provide suitable chemical protection: Longer term protection: Viton. Incidental contact/Splash protection: Nitrile rubber. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. For continuous contact we recommend gloves with breakthrough time of more 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

๐Ÿ‘๏ธ Eye Protection

Chemical splash goggles (chemical monogoggles). Approved to EU Standard EN166, AS/NZS:1337.

๐Ÿ˜ท Respiratory Protection

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for organic gases and vapours [boiling point >65 C (149 F)] meeting EN14387. Where air-filtering respirators are unsuitable (e.g., airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus.

๐Ÿฆบ Skin/Body Protection

Chemical resistant gloves/gauntlets. Where risk of splashing or in spillage clean up, use chemical resistant one-piece overall with integral hood. Wear antistatic and flame retardant clothing.

๐ŸŒ Environmental Exposure Controls

Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Information on accidental release measures are to be found in section 6.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

๐Ÿท๏ธ UN Number

1294

๐Ÿ“ฆ Proper Shipping Name

Toluene

โš ๏ธ Transport Hazard Class

3

๐Ÿ“‹ Packing Group

II

๐Ÿš› ADR Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

๐Ÿšข IMDG Maritime Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

โœˆ๏ธ IATA Air Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Toluene?

The signal word for this substance is "danger".

What is the physical form of Toluene?

Toluene is a liquid appearing as colourless. liquid. with colourless color. It has aromatic. odor.

What is Toluene used for?

Solvent. Raw material for use in the chemical industry. Please refer to Ch16 and/or the annexes for the registered uses under REACH.

What are the hazard statements for Toluene?

This substance has 6 hazard statements: H225: Highly flammable liquid and vapor. H315: Causes skin irritation. H304: May be fatal if swallowed and enters airways. H361: Suspected of damaging fertility or the unborn child. H336: May cause drowsiness or dizziness. H373: May cause damage to organs or organ systems through prolonged or repeated exposure.

What is the melting point of Toluene?

The melting point is Typical -95 C / -139 F and the boiling point is Typical 110 - 111 C / 230 - 232 F.