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Safety Data Sheet EN

4-Bromofluorobenzene

CAS 460-00-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4-Bromofluorobenzene
Product Code
AC107010000; AC107010100; AC107011000; AC107015000
Synonyms
1-Bromo-4-fluorobenzene

Regulatory Identifiers

CAS Number
460-00-4 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor
H312 Harmful in contact with skin
H315 Causes skin irritation
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 Keep container tightly closed
P235 Keep cool
P240 Ground and bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use non-sparking tools
P243 Take action to prevent static discharges
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P312 Call a POISON CENTER or doctor if you feel unwell
P332 + P313 If skin irritation occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P362 + P364 Take off contaminated clothing and wash before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Benzene, 1-bromo-4-fluoro- 460-00-4 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.

Skin contact

Get medical attention. Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire

Specific hazards

Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment. See Section 12 for additional Ecological Information.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Flammables area.

Hygiene

Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use explosion-proof electrical/ventilating/lighting equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas.

Hands

Wear appropriate protective gloves

Eyes

Tight sealing safety goggles. Face protection shield.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter. Type A. Brown. conforming to EN14387.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
175
Flash Point
53 °C / 127.4 °F
Solubility In Water
0.14 g/L (20°C)
Voc Content
---
Dynamic Viscosity
---
Partition Coefficient
3.018
Cloud Point
---
Odor Threshold
No information available
Properties Status
---
Upper Explosive Limit
No data available
Flammability
Flammable
Bulk Density
Not applicable
Freezing Point
---
Physical State Data
liquid
Ph
7
Crystallisation Point
---
Physical State
Liquid
Vapor Pressure
3.7 mmHg @ 20 °C
Relative Evaporation Rate
---
State Under Standard Conditions
---
Lower Explosive Limit
No data available
Solubility In Fat
---
Decomposition Temperature
No data available
Explosive Limits
---
Kinematic Viscosity
---
Evaporation Rate
---
Vapor Density
5.6 (Air = 1.0)
Metal Corrosion
---
Solubility
---
Boiling Point
150 - 153 °C / 302 - 307.4 °F
Softening Point
No data available
Auto Ignition Temperature
> 350 °C / > 662 °F
Colour Intensity
---
Appearance
Colorless
Melting Point
-8 °C / 17.6 °F
Density
1.593
Relative Density
---
Form
---
Odor
aromatic
Solidification Point
---
Colour
Colorless
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids, Strong bases

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂), Hydrogen halides, Gaseous hydrogen fluoride (HF)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1993
Shipping Name
Flammable liquid, n.o.s.
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 4-Bromofluorobenzene known by?

4-Bromofluorobenzene is also known as: 1-Bromo-4-fluorobenzene

What is the hazard signal word for 4-Bromofluorobenzene?

The signal word is warning.

What is the physical form of 4-Bromofluorobenzene?

4-Bromofluorobenzene is a liquid appearing as colorless with colorless color. It has aromatic odor.

What is 4-Bromofluorobenzene used for?

Laboratory chemicals.

What are the hazard statements for 4-Bromofluorobenzene?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapor
  • H312: Harmful in contact with skin
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H332: Harmful if inhaled
  • H335: May cause respiratory irritation

What is the melting point of 4-Bromofluorobenzene?

The melting point is -8 °C / 17.6 °F and the boiling point is 150 - 153 °C / 302 - 307.4 °F.