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Safety Data Sheet EN

1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

CAS 140681-55-6
EC 414-380-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
Product Code
L17003

Regulatory Identifiers

CAS Number
140681-55-6 Check regulations →
EC Number
414-380-4 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

A

Avocado Research Chemicals Ltd.

manufacturer

Shore Road, Heysham, Lancashire, LA3 2XY, United Kingdom

+44 (0) 1524 850506

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Self-heat. Cat. 1 H251
Acute Tox. Cat. 4 H302
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H251 Self-heating: may catch fire
H302 Harmful if swallowed
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements

P235 Keep cool
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P420 Store separately

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,4-Diazoniabicyclo[2.2.2]octane, 1-(chloromethyl)-4-fluoro-, bis[tetrafluoroborate(1-)] EC: 414-380-4 140681-55-6 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: Trouble breathing, dizziness, lightheadedness, chest pain.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Symptoms: May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, tingling of the hands and feet, muscle pain or flushing.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Causes severe eye damage.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Immediate Medical Attention

Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO₂). Dry chemical.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment as required.

Environmental

Should not be released into the environment.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Materials: suitable containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage

Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat, sparks and flame. Keep at temperature not exceeding 30°C. Corrosives area. Keep under nitrogen.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from heat, sparks and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. (minimum requirement)

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Powder Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
White
Colour
---
Colour Intensity
---
Form
---
Odor
Irritating
Odor Threshold
No data available
Ph
No information available
Melting Point
175 °C / 347 °F
Boiling Point
No information available
Flash Point
No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable - Solid
Vapor Pressure
No data available
Vapor Density
Not applicable
Relative Density
---
Bulk Density
No data available
Density
---
Flammability
No information available
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
-3.39
Solubility In Water
Very soluble
Solubility In Fat
---
Molecular Weight
354.26
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable if heated. Moisture sensitive.

Reactivity

Yes

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Temperatures above 50°C. Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Exposure to moist air or water. Combustible material.

Incompatible

Incompatible products. Combustible material.

Decomposition

Nitrogen oxides (NOx). Carbon monoxide (CO). Carbon dioxide (CO₂). Gaseous hydrogen fluoride (HF). Oxides of boron.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3088
Shipping Name
Self-heating solid, organic, n.o.s.
Transport Class
4.2
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)?

The signal word is danger.

What is the physical form of 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)?

1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) is a powder solid appearing as white . It has irritating odor.

What is 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) used for?

Laboratory chemicals.

What are the hazard statements for 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)?

This substance has 5 hazard statements:

  • H251: Self-heating: may catch fire
  • H302: Harmful if swallowed
  • H317: May cause an allergic skin reaction
  • H318: Causes serious eye damage
  • H412: Harmful to aquatic life with long lasting effects

What is the melting point of 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)?

The melting point is 175 °C / 347 °F and the boiling point is No information available.