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Safety Data Sheet EN

N,N'-Methylenebis(acrylamide)

CAS 110-26-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
N,N'-Methylenebis(acrylamide)
Product Code
146072
Chemical Name
N,N'-Methylenebis(acrylamide)

Regulatory Identifiers

CAS Number
110-26-9 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B, B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 4 H312
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Repr. Cat. 2 H361fd
STOT RE Cat. 1 H372

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H340 May cause genetic defects.
H350 May cause cancer.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H372 Causes damage to organs (Peripheral nervous system) through prolonged or repeated exposure if swallowed.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
N,N'-methylenediacrylamide EC: 203-750-9 110-26-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

Immediate Medical Attention

Seek medical advice immediately. Call in physician. Call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Flammability
---
Explosive Limits
---
Odor
characteristic odour
Colour Intensity
---
Appearance
---
Solidification Point
---
Ph
---
Relative Evaporation Rate
---
Cloud Point
---
Bulk Density
---
Decomposition Temperature
---
Melting Point
Melting point/ range: > 300 °C
Auto Ignition Temperature
---
Flash Point
Not applicable
Vapor Density
---
Odor Threshold
---
Physical State
powder
Density
1,216 g/cm3 at 20 °C - OECD Test Guideline 109
Physical State Data
solid
Freezing Point
---
Vapor Pressure
< 0,01 hPa - OECD Test Guideline 104
Upper Explosive Limit
---
Evaporation Rate
---
Partition Coefficient
log Pow: -0,08 at 25 °C - OECD Test Guideline 107 -
Solubility
---
Colour
white
Solubility In Water
34,1 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6
Kinematic Viscosity
No data available
Softening Point
---
State Under Standard Conditions
---
Solubility In Fat
---
Boiling Point
333,8 °C at 1.013 hPa - Regulation (EC) No. 440/2008, Annex, A.2
Properties Status
---
Voc Content
---
Crystallisation Point
---
Relative Density
---
Form
---
Molecular Weight
---
Metal Corrosion
---
Lower Explosive Limit
---
Dynamic Viscosity
No data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents, Bases, Strong acids

Avoid

Exposure to air.

Incompatible

no information available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2811
Shipping Name
TOXIC SOLID, ORGANIC, N.O.S. (N,N'-methylenediacrylamide)
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for N,N'-Methylenebis(acrylamide)?

The signal word is danger.

What is the physical form of N,N'-Methylenebis(acrylamide)?

N,N'-Methylenebis(acrylamide) is a powder with white color. It has characteristic odour odor.

What is N,N'-Methylenebis(acrylamide) used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for N,N'-Methylenebis(acrylamide)?

This substance has 6 hazard statements:

  • H301: Toxic if swallowed.
  • H312: Harmful in contact with skin.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
  • H372: Causes damage to organs (Peripheral nervous system) through prolonged or repeated exposure if swallowed.

What is the melting point of N,N'-Methylenebis(acrylamide)?

The melting point is Melting point/ range: > 300 °C and the boiling point is 333,8 °C at 1.013 hPa - Regulation (EC) No. 440/2008, Annex, A.2.