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Safety Data Sheet EN

D128181

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
D128181
Product Code
73714

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Additive for car engine lubricating oil

Uses advised against

This material should not be used for any other purpose than that recommended without expert advice.

Manufacturers & Suppliers

INFINEUM FRANCE S.N.C. logo

INFINEUM FRANCE S.N.C.

manufacturer

Chemin Départemental 54, 13130 BERRE L'ETANG

+33 4 42 74 57 01

http://www.infineum.com

Emergency Contacts

Emergency Contact

04-4274.4690

Emergency Contact

+33-4.4274.4690

Emergency Contact

0221-7499 3355

Emergency Contact

+49-221-7499 3355

Emergency Contact

019-2150 221

Emergency Contact

+39 019-2150 221

Emergency Contact

01235 549777

Emergency Contact

+44 1235 549777

ORFILA

01 45 42 59 59

ORFILA

+33-1 45 42 59 59

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
bis(nonylphenyl)amine EC: 253-249-4 --- 2.5 - 10% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts EC: 283-392-8 --- 3 - 5% Yes
reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate EC: 406-040-9 --- 1 - 2.5% Yes
C14-16-18 Alkyl phenol --- 0.1 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. If breathing has stopped, assist ventilation with a mechanical device. Do not use mouth-to-mouth resuscitation if exposure to hydrogen sulphide is suspected.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. In case of burns apply cold water until pain subsides then seek medical advice.

Eye contact

Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists: Get medical advice/ attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

Medical Treatment

Show this safety data sheet to the doctor in attendance. The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

Unsuitable media

High volume water jet

Specific hazards

Not classified as flammable or combustible, but will combust if ignited.

Instructions

Fire-fighters should exercise extreme caution in enclosed spaces due to the possible presence of toxic decomposition and combustion products.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Self-contained full-face overpressure breathing apparatus should be used in enclosed spaces. Use standard body protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with spilled material. Do not touch or walk through spilled material.

Small spill

Wipe up with absorbent material (e.g. cloth, fleece).

Large spill

Dyke far ahead of liquid spill for later recovery and disposal.

Environmental

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Recover by pumping or with suitable absorbent. Seek the advice of a specialist before using dispersants. Wipe up with absorbent material (e.g. cloth, fleece).

Materials: absorbent material (e.g. cloth, fleece)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations.

Storage

Product should be stored below the recommended maximum loading / unloading temperature to avoid degradation of product quality and eventually decomposition.

Hygiene

Smoking, eating and drinking should be prohibited in the application area.

Fire prevention

Normal measures for preventive fire protection.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

See attached ES. No special requirements under ordinary conditions of use and with adequate ventilation. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Hands

Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat resistant gloves. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Eyes

The applicable European standard can be found in EN 166. Eye wash bottle with pure water. Tightly fitting safety goggles. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory

The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Skin/Body

Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. The applicable European standard can be found in EN 14605.

Environmental

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
brown
Colour Intensity
---
Form
viscous liquid
Odor
hydrocarbon-like
Odor Threshold
not determined
Ph
Not applicable
Melting Point
not determined
Boiling Point
not determined
Flash Point
176 °C (349 °F) Method: Pensky-Martens Closed Cup (ASTM D93)
Freezing Point
not determined
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
< 0,1 hPa (< 0,1 mmHg) at 20 °C (68 °F) estimated
Vapor Density
not determined
Relative Density
0,946 at 15,6 °C (60,1 °F)
Bulk Density
Not applicable
Density
0,946 g/cm³ at 15 °C (59 °F)
Flammability
not determined
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
not determined
Solubility In Water
< 0,0001 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
162 mm2/s at 100 °C (212 °F) Method: ASTM D 445; 2642 mm2/s at 40 °C (104 °F) Method: ASTM D 445
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

No hazards to be specially mentioned.

Avoid

Excessive heat.

Incompatible

Strong oxidizing agents, water

Decomposition

Hydrogen Sulfide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish : No data is available on the product itself. Toxicity to daphnia and other aquatic invertebrates : No data is available on the product itself. Toxicity to algae : No data is available on the product itself. Components:

No data is available on the product itself.

12.1 Toxicity

bis(nonylphenyl)amine : Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Test Method: static test Test substance: Read-across (Analogy) Method: OECD Test Guideline 203 Based on available data, the classification criteria are not met. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Test Method: static test Test substance: yes Method: OECD Test Guideline 202 Based on available data, the classification criteria are not met. Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l Exposure time: 72 h Test Method: static test

12.1 Toxicity

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4,5 mg/l Exposure time: 96 h Test Method: semi-static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 203 GLP: yes Toxic to aquatic life. Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): 23 mg/l Exposure time: 48 h Test Method: static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 202 GLP: yes Harmful to aquatic life. Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 21 mg/l Exposure time: 72 h Test Method: static test Analytical monitoring: no Test substance: yes Method: OECD Test Guideline 201 GLP: yes Harmful to aquatic life. Toxicity to bacteria : IC50 : 10.000 mg/l Exposure time: 3 h Test Method: Respiration inhibition Test substance: yes GLP: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0,4 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Analytical monitoring: yes Test substance: yes Method: OECD Test Guideline 211 GLP: yes Toxic to aquatic life with long lasting effects.

12.1 Toxicity

reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate : Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 74 mg/l Exposure time: 96 h Test Method: semi-static test Test substance: yes Method: OECD Test Guideline 203 Based on available data, the classification criteria are not met. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 24 h Test substance: yes Method: OECD Test Guideline 202 Based on available data, the classification criteria are not met. Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 3 mg/l Exposure time: 72 h Test substance: yes Method: OECD Test Guideline 201 Based on available data, the classification criteria are not met. Ecotoxicology Assessment Chronic aquatic toxicity : May cause long lasting harmful effects to aquatic life.

Acute toxicity tests on fish, daphnia, and algae indicate that classification criteria for acute aquatic toxicity are not met. However, the substance is assessed as having chronic aquatic toxicity, potentially causing long-lasting harmful effects to aquatic life.

12.2 Persistence and degradability

Product: Biodegradability : No data is available on the product itself. Components:

No data is available on the product itself regarding biodegradability.

12.2 Persistence and degradability

bis(nonylphenyl)amine : Biodegradability : aerobic activated sludge Result: Not biodegradable Biodegradation: 1 % Exposure time: 28 d Test substance: Read-across (Analogy) According to the results of tests of biodegradability this product is not readily biodegradable.

According to the results of tests of biodegradability this product is not readily biodegradable.

12.2 Persistence and degradability

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Biodegradability : aerobic activated sludge Concentration: 10 mg/l Result: Not readily biodegradable. Biodegradation: 1,5 % Exposure time: 28 d Method: OECD Test Guideline 301B Test substance: yes GLP: yes According to the results of tests of biodegradability this product is not readily biodegradable. Stability in water : Hydrolysis: 6,6 % at50 °C(120 h) pH: 7 Test substance: yes Method: OECD Test Guideline 111 Hydrolysis: 0 % at50 °C(120 h) pH: 4 Test substance: yes Method: OECD Test Guideline 111 Hydrolysis: 0 % at50 °C(120 h) pH: 9 Test substance: yes Method: OECD Test Guideline 111

The substance is not readily biodegradable based on OECD 301B test results. Hydrolysis tests indicate low degradation at pH 4, 7, and 9 at 50 °C.

12.2 Persistence and degradability

reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate : Biodegradability : Result: Not biodegradable Method: OECD Test Guideline 301B Test substance: yes According to the results of tests of biodegradability this product is not readily biodegradable.

The substance is not readily biodegradable.

12.3 Bioaccumulative potential

Product: Bioaccumulation : No data is available on the product itself. Partition coefficient: n-octanol/water : not determined Components:

No data is available on the product itself regarding bioaccumulation, and the partition coefficient is not determined.

12.3 Bioaccumulative potential

bis(nonylphenyl)amine : Bioaccumulation : Accumulation in aquatic organisms is expected. Partition coefficient: n-octanol/water : log Pow: > 7,6

12.3 Bioaccumulative potential

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Bioaccumulation : Test substance: Read-across (Analogy) Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected. Partition coefficient: n-octanol/water : log Pow: 0,56

12.3 Bioaccumulative potential

reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate : Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout) Exposure time: 35 d Bioconcentration factor (BCF): 260 Test substance: yes Method: OECD Test Guideline 305 Due to the distribution coefficient n-octanol/water, accumulation in organisms is possible. Partition coefficient: n-octanol/water : log Pow: 9,2

12.4 Mobility in soil

Product: Mobility : No data is available on the product itself. Components: bis(nonylphenyl)amine : Mobility : After release, adsorbs onto soil. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Mobility : After release, adsorbs onto soil. reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate : Mobility : After release, adsorbs onto soil.

12.5 Results of PBT and vPvB assessment

Product: Assessment : No data is available on the product itself. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Components: bis(nonylphenyl)amine : Assessment : This substance is not considered to be persistent, bioaccumulating and toxic (PBT)., This substance is not considered to be very persistent and very bioaccumulating (vPvB). Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts : Assessment : This substance is not considered to be persistent, bioaccumulating and toxic (PBT)., This substance is not considered to be very persistent and very bioaccumulating (vPvB). reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate : Assessment : This substance is not considered to be persistent, bioaccumulating and toxic (PBT)., This substance is not considered to be very persistent and very bioaccumulating (vPvB).

The product and its components are not considered to be persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/ container to an approved waste disposal plant.

Disposal

The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Disposal recommendations based on material as supplied, Disposal must be in accordance with applicable laws and regulations, and material characteristics at time of disposal.

Waste Codes

13 02 XX waste engine, gear and lubricating oils EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Regulation (EC) No. 1907/2006

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for D128181?

The signal word is no signal word.

What is the physical form of D128181?

D128181 is a liquid with brown color. It has hydrocarbon-like odor.

What is D128181 used for?

Additive for car engine lubricating oil

What are the hazard statements for D128181?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of D128181?

The melting point is not determined and the boiling point is not determined.